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A quantitative description of fission-track etching in apatite

  • Carolin Aslanian , Raymond Jonckheere ORCID logo EMAIL logo , Bastian Wauschkuhn und Lothar Ratschbacher
Veröffentlicht/Copyright: 24. April 2021
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American Mineralogist
Aus der Zeitschrift American Mineralogist Band 106 Heft 4

Abstract

We measured the apatite etch rate vR in 5.5 M HNO3 at 21 °C as a function of orientation. Results for Durango apatite evidence that vR varies by a factor >5 with angle to the c-axis. Our measurements also provided track etch rates vT and surface etch rates vS. However, these cannot be combined for calculating track etching or counting efficiencies. By inserting the measured etch rates in a recent model, we calculate the geometries and dimensions of surface tracks in different apatite faces. The proposed model must be recalibrated for different etching protocols and adapted for other minerals. We submit that the new model justifies reviewing track counting efficiencies based on the existing (vB-vT) etch model. We anticipate that this will have an effect on practical aspects of fission track dating. Single-track step-etch data show that the confined track lengths increase with etch time at a decreasing average rate vL that differs from the track etch rate vT and the apatite etch rate vR. Both vT and vL exhibit large track-to-track differences that produce irreducible length variation related to the latent-track structure resulting from formation and annealing. Step etching and track width measurements are effective for reducing or eliminating procedure-related artifacts from track length data, and so for accessing more fundamental track properties.

Keywords: Apatite; fission track; etching; apatite etch rate; track etch rate; Experimental Halogens in Honor of Jim Webster

† Special collection papers can be found online at http://www.minsocam.org/MSA/AmMin/special-collections.html.

Acknowledgments and funding

Research funded by the German Research Council (DFG project Jo 358/4-1). We are much indebted to R. Ketcham and A.J.W. Gleadow for their professional reviews, which greatly improved our manuscript.

References cited

Barbarand, J., Hurford, T., and Carter, A. (2003) Variation in apatite fission-track length measurement: Implications for thermal history modelling. Chemical Geology, 19, 77–106.10.1016/S0009-2541(02)00423-0Suche in Google Scholar

Batterman, B.W. (1957) Hillocks, pits and etch rate in Germanium crystals. Journal of Applied Physics, 28, 1236–1241.10.1063/1.1722624Suche in Google Scholar

Burton, W.K., Cabrera, N., and Frank, F.C. (1951) The growth of crystals and the equilibrium structures of their faces. Philosophical Transactions of the Royal Society of London A, 243, 299–358.10.1098/rsta.1951.0006Suche in Google Scholar

Carlson, W.D., Donelick, R.A., and Ketcham, R.A. (1999) Variability of apatite fission-track annealing kinetics: I. Experimental results. American Mineralogist, 84, 1213–1223.10.2138/am-1999-0901Suche in Google Scholar

Chernov, A.A. (2004) Notes on interface growth kinetics 50 years after Burton, Cabrera and Frank. Journal of Crystal Growth, 264, 499–518.10.1016/j.jcrysgro.2003.12.076Suche in Google Scholar

Donelick, R.A., Ketcham, R.A., and Carlson, W.D. (1999) Variability of apatite fission-track annealing kinetics: II. Crystallographic orientation effects. American Mineralogist, 84, 1224–1234.10.2138/am-1999-0902Suche in Google Scholar

Donelick, R.A., O’Sullivan, P.B., and Ketcham, R.A. (2005) Apatite fission-track analysis. In P. Reiners, and T. Ehlers, Eds., Low-temperature Thermochronol-ogy. Reviews in Mineralogy and Geochemistry, 58, 49–94.10.1515/9781501509575-005Suche in Google Scholar

Enkelmann, E., Jonckheere, R., and Wauschkuhn, B. (2005) Independent fission-track ages (ϕ-ages) of proposed and accepted apatite age standards and a comparison of ϕ-, Z-, ζ- and ζ0-ages: Implications for method calibration. Chemical Geology, 222, 232–248.10.1016/j.chemgeo.2005.07.009Suche in Google Scholar

Fleischer, R.L., Price, P.B., and Walker, R.M. (1975) Nuclear tracks in solids. Principles and Applications. University of California Press, Berkeley, pp. 604.10.1525/9780520320239Suche in Google Scholar

Frank, F.C. (1958) On the kinematic theory of crystal growth and dissolution processes. In T.H. Doremus, B.W. Roberts, and D. Turnbull, Eds., Growth and Perfection of Crystals, p. 411–419. Wiley.Suche in Google Scholar

Frank, F.C., and Ives, M.B. (1960) Orientation-dependent dissolution of Germanium. Journal of Applied Physics, 31, 1996–1999.10.1063/1.1735485Suche in Google Scholar

Gleadow, A.J.W. (1978) Anisotropic and variable track etching characteristics in natural sphenes. Nuclear Track Detection, 2, 105–111.10.1016/0145-224X(78)90008-XSuche in Google Scholar

Gleadow, A.J.W. (1981) Fission track dating methods: what are the real alternatives? Nuclear Tracks, 5, 3–14.10.1016/0191-278X(81)90021-4Suche in Google Scholar

Gleadow, A.J.W., and Seiler, C. (2015) Fission-track dating and thermochronology. In J.W. Rink and J.W. Thompson, Eds., Encyclopedia of Scientific Dating Methods, p. 285–296. Springer.10.1007/978-94-007-6304-3_5Suche in Google Scholar

Gleadow, A.J.W., Kohn, B., and Seiler, C. (2019) The future of fission track thermochronology. In M.G. Malusà and P.G. Fitzgerald, Eds., Fission-Track Thermochronology and its Application to Geology, Geography and Environment, p. 77–92. Springer.10.1007/978-3-319-89421-8_4Suche in Google Scholar

Gleadow, A.J.W., Belton, D.X., Kohn, B.P., and Brown, R.W. (2002) Fission track dating of phosphate minerals and the thermochronology of apatite. In M.J. Kohn, J. Rakovan, and J.M. Hughes, Eds., Phosphates, Geochemical, Geobiological, and Materials Importance. Reviews of Mineralogy and Geochemistry, 48, 579–630.10.2138/rmg.2002.48.16Suche in Google Scholar

Green, P.F., Duddy, I.R., Gleadow, A.J.W., Tingate, P.R., and Laslett, G.M. (1986) Thermal annealing of fission tracks in apatite 1. A qualitative description. Chemical Geology (Isotope Geoscience Section), 59, 237–253.10.1016/0168-9622(86)90074-6Suche in Google Scholar

Guo, S.-L., Chen, B.-L., and Durrani, S.A. (2020) Solid-state nuclear track detectors. In Handbook of Radioactivity Analysis, Radiation Physics and Detectors, 4th ed., vol. 1, p. 307–407. Academic Press.10.1016/B978-0-12-814397-1.00003-0Suche in Google Scholar

Hasebe, N., Barbarand, J., Jarvis, K., Carter, A., and Hurford, A.J. (2004) Apatite fission-track chronometry using laser ablation ICP-MS. Chemical Geology, 207, 135–145.10.1016/j.chemgeo.2004.01.007Suche in Google Scholar

Heimann, R., Franke, W., and Lacmann, R. (1971) Dissolution forms of single crystal spheres of rutile. Journal of Crystal Growth, 13/14, 202–206.10.1016/0022-0248(72)90155-8Suche in Google Scholar

Heimann, R., Franke, W., and Lacmann, R. (1975) The dissolution forms of single crystal spheres. IV. Dissolution of MgO. Journal of Crystal Growth, 28, 151–156.10.1016/0022-0248(75)90037-8Suche in Google Scholar

Holmes, P.J. (1962) Practical applications of chemical etching. In P.J. Holmes, Ed., The Electro-chemistry of Semiconductors, p. 329–377. Academic Press.Suche in Google Scholar

Hurford, A.J. (2019) An historical perspective on fission-track thermochronology. In M.G. Malusà and P.G. Fitzgerald, Eds., Fission-Track Thermochronology and its Application to Geology, Geography and Environment, p. 3–23. Springer.10.1007/978-3-319-89421-8_1Suche in Google Scholar

Irving, B.A. (1959) Shapes of etch hillocks and pits and their correlation with measured etch rates. Journal of Applied Physics, 31, 109–111.10.1063/1.1735382Suche in Google Scholar

Irving, B.A. (1962) Chemical etching of semiconductors. In P.J. Holmes, Ed., The Electro-chemistry of Semiconductors, p. 256–289. Academic Press.Suche in Google Scholar

Jaccodine, R.J. (1962) Use of modified free energy theorems to predict equilibrium growing and etching shapes. Journal of Applied Physics, 33, 2643–2647.10.1063/1.1729036Suche in Google Scholar

Jonckheere, R. (2003) On the densities of etchable fission tracks in a mineral and co-irradiated external detector with reference to fission-track dating of minerals. Chemical Geology, 200, 41–58.10.1016/S0009-2541(03)00116-5Suche in Google Scholar

Jonckheere, R., and Van den haute, P. (1996) Observations on the geometry of etched fission tracks in apatite: Implications for models of track revelation. American Mineralogist, 81, 1476–1493.10.2138/am-1996-11-1219Suche in Google Scholar

Jonckheere, R., and Van den haute, P. (1998) On the frequency distributions per unit area of the dimensions of fission tracks revealed in an internal and external mineral surface and in the surface of an external detector. Radiation Measurements, 29, 135–143.10.1016/S1350-4487(98)00039-0Suche in Google Scholar

Jonckheere, R., and Van den haute, P. (1999) On the frequency distributions per unit area of the projected and etchable lengths of surface-intersecting fission tracks: Influences of track revelation, observation and measurement. Radiation Measurements, 30, 155–179.10.1016/S1350-4487(99)00038-4Suche in Google Scholar

Jonckheere, R., and Van den haute, P. (2002) On the efficiency of fission-track counts in an internal and external apatite surface and in a muscovite external detector. Radiation Measurements, 35, 29–40.10.1016/S1350-4487(01)00262-1Suche in Google Scholar

Jonckheere, R., Van den haute, P., and Ratschbacher, L. (2015) Standardless fission-track dating of the Durango apatite age standard. Chemical Geology, 417, 44–57.10.1016/j.chemgeo.2015.09.014Suche in Google Scholar

Jonckheere, R., Tamer, M.T., Wauschkuhn, B., Wauschkuhn, F., and Ratschbacher, L. (2017) Single-track length measurements of step-etched fission tracks in Durango apatite: “Vorsprung durch Technik”. American Mineralogist, 102, 987–996.Suche in Google Scholar

Jonckheere, R., Wauschkuhn, B., and Ratschbacher, L. (2019) On growth and form of etched fission tracks in apatite: A kinetic approach. American Mineralogist, 104, 569–579.10.2138/am-2019-6762Suche in Google Scholar

Jonckheere, R., Aslanian, C., Wauschkuhn, B., and Ratschbacher, L. (2020) Some geometrical properties of fission-track-surface intersections in apatite. American Mineralogist, 105, 1355–1364.10.2138/am-2020-7271Suche in Google Scholar

Ketcham, R.A. (2003) Observations on the relationship between crystallographic orientation and biasing in apatite fission-track measurements. American Mineralogist, 88, 817–829.10.2138/am-2003-5-610Suche in Google Scholar

Ketcham, R.A., Carter, A.C., Donelick, R.A., Barbarand, J., and Hurford, A.J. (2007) Improved measurement of fission-track annealing in apatite using c-axis projection. American Mineralogist, 92, 789–798.10.2138/am.2007.2280Suche in Google Scholar

Ketcham, R.A., Carter, A., and Hurford, A.J. (2015) Inter-laboratory comparison of fission track confined length and etch figure measurements in apatite. American Mineralogist, 100, 1452–1468.10.2138/am-2015-5167Suche in Google Scholar

Kohn, B., Chung, L., and Gleadow, A., (2019) Fission-track analysis: Field collection, sample preparation and data acquisition. In M.G. Malusà and P.G. Fitzgerald, Eds., Fission-Track Thermochronology and its Application to Geology, Geography and Environment, p. 25–48. Springer.10.1007/978-3-319-89421-8_2Suche in Google Scholar

Laslett, G.M., Gleadow, A.J.W., and Duddy, I. (1984) The relationship between fission track length and track density in apatite. Nuclear Tracks, 9, 29–38.10.1016/0735-245X(84)90019-XSuche in Google Scholar

Li, W., Wang, L., Lang, M., Trautmann, C., and Ewing, R.C. (2011) Thermal annealing mechanisms of latent fission tracks: Apatite vs. zircon. Earth and Planetary Science Letters, 302, 227–235.10.1016/j.epsl.2010.12.016Suche in Google Scholar

Li, W., Lang, M., Gleadow, A.J.W., Zdorovets, M.V., and Ewing, R.C. (2012) Thermal annealing of unetched fission tracks in apatite. Earth and Planetary Science Letters, 321-322, 121–127.10.1016/j.epsl.2012.01.008Suche in Google Scholar

Li, W., Kluth, P., Schauries, D., Rodriguez, M.D., Lang, M., Zhang, F., Zdorovets, M., Trautmann, C., and Ewing, R.C. (2014) Effect of orientation on ion track formation in apatite and zircon. American Mineralogist, 99, 1127–1132.10.2138/am.2014.4669Suche in Google Scholar

Nováková, L., Jonckheere, R., Wauschkuhn, B., and Ratschbacher, L. (2020) Thermal history modelling of the western margin of the Bohemian Massif using high-resolution apatite fission-track thermochronology. Abstracts of the EGU General Assembly, May 4–7, 2020. Tectonics and Structural Geology Session (TS2.3).10.5194/egusphere-egu2020-15152Suche in Google Scholar

Paul, T.A., and Fitzgerald, P.G. (1992) Transmission electron microscopic investigation of fission tracks in fluorapatite. American Mineralogist, 77, 336–344.Suche in Google Scholar

Price, P.B., and Fleischer, R.M. (1971) Identification of energetic heavy nuclei with solid dielectric track detectors: Applications to astrophysical and planetary studies. Annual Review of Nuclear Science, 21, 95–334.10.1146/annurev.ns.21.120171.001455Suche in Google Scholar

Price, P.B., and Walker, R.M. (1962) Chemical etching of charged-particle tracks in solids. Journal of Applied Physics, 33, 3407–3412.10.1063/1.1702421Suche in Google Scholar

Rakovan, J. (2002) Growth and surface properties of apatite. In M.J. Kohn, J. Ra-kovan, and J.M. Hughes, Eds., Phosphates, Geochemical, Geobiological, and Materials Importance. Reviews of Mineralogy and Geochemistry, 48, 51–86.10.1515/9781501509636-006Suche in Google Scholar

Tagami, T., and O’Sullivan, P.B. (2005) Fundamentals of fission-track thermochro-nology. Reviews in Mineralogy and Geochemistry, 58, 19–47.10.2138/rmg.2005.58.2Suche in Google Scholar

Tamer, M.T., Chung, L., Ketcham, R.A., and Gleadow, A.J.W. (2019) Analyst and etching protocol effects on the reproducibility of apatite confined fission-track length measurement, and ambient-temperature annealing at decadal timescales. American Mineralogist, 104, 1421–1435.10.2138/am-2019-7046Suche in Google Scholar

Woensdregt, C.F. (1993) Hartman-Perdok theory: Influence of crystal structure and crystalline interface on crystal growth. Faraday Discussions, 95, 97–107.10.1039/FD9939500097Suche in Google Scholar

Woodruff, D.P. (2015) How does your crystal grow? A commentary on Burton, Cabrera and Frank (1951) “The growth of crystals and the equilibrium structure of their surfaces”. Philosophical transactions of the Royal Society A, 373, 1–11.10.1098/rsta.2014.0230Suche in Google Scholar PubMed PubMed Central

Received: 2020-05-17
Accepted: 2020-08-19
Published Online: 2021-04-24
Published in Print: 2021-04-27

© 2021 Walter de Gruyter GmbH, Berlin/Boston

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https://doi.org/10.2138/am-2021-7614
Schlagwörter für diesen Artikel
Apatite; fission track; etching; apatite etch rate; track etch rate; Experimental Halogens in Honor of Jim Webster

Artikel in diesem Heft

  1. Gamma-enhancement of reflected light images: A rapid, effective tool for assessment of compositional heterogeneity in pyrite
  2. Thermal metamorphic history of Antarctic CV3 and CO3 chondrites inferred from the first- and second-order Raman peaks of polyaromatic organic carbon
  3. A quantitative description of fission-track etching in apatite
  4. Spectroscopic analysis of allophane and imogolite samples with variable Fe abundance for characterizing the poorly crystalline components on Mars
  5. Relationship between 207Pb NMR chemical shift and the morphology and crystal structure for the apatites Pb5(AO4)3Cl, vanadinite (A = V), pyromorphite (A = P), and mimetite (A = As)
  6. Effect of cationic substitution on the pressure-induced phase transitions in calcium carbonate
  7. Immiscible-melt inclusions in corundum megacrysts: Microanalyses and geological implications
  8. Water quantification in olivine and wadsleyite by Raman spectroscopy and study of errors and uncertainties
  9. High-pressure and high-temperature vibrational properties and anharmonicity of carbonate minerals up to 6 GPa and 500 °C by Raman spectroscopy
  10. Vanadium-induced coloration in grossite (CaAl4O7) and hibonite (CaAl12O19)
  11. Incorporation mechanism of tungsten in W-Fe-Cr-V-bearing rutile
  12. Titanium diffusion profiles and melt inclusion chemistry and morphology in quartz from the Tshirege Member of the Bandelier Tuf
  13. Vasilseverginite, Cu9O4(AsO4)2(SO4)2, a new fumarolic mineral with a hybrid structure containing novel anion-centered tetrahedral structural units
  14. Priscillagrewite-(Y), (Ca2Y)Zr2Al3O12: A new garnet of the bitikleite group from the Daba-Siwaqa area, the Hatrurim Complex, Jordan
  15. Stöfflerite, (Ca,Na)(Si,Al)4O8 in the hollandite structure: A new high-pressure polymorph of anorthite from martian meteorite NWA 856
  16. Recycled volatiles determine fertility of porphyry deposits in collisional settings
  17. Letter
  18. Nitrogen diffusion in silicate melts under reducing conditions
  19. Book Review
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