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Bis(trimethylphosphan)-η5-cyclopentadienyl- tert- butylimidovanadium( III): Reaktionen mit Schwefel, Selen, Tellur und Iod
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Martin Billen
Veröffentlicht/Copyright:
2. Juni 2014
The reaction of [tBuN=VCp(PMe3)2] (1) with S8, Se, Te or I2 have been studied. Via this pathway dinuclear diamagnetic tert-butylimidovanadium(IV) complexes are formed: [(μ-E)(μ- NtBu)2V2Cp2] (E=S, Se, Te), [(μ-η1−E2)(μ-NtBu)2V2Cp2] {E=Se (3), Te}, [(μ-NtBu)2V2Cp2I2]. In addition the vanadium(V) complexes [tBuN=VCp (S5)] (9a) and tBuN=VCpI2 could be isolated. The synthesis of tBuN=VCpF2 is also described. All compounds obtained have been characterized by spectroscopic methods (MS; 1H, 13C, 51V NMR), 3 and 9b by single crystal X-ray diffraction analysis.
Received: 2002-11-28
Published Online: 2014-6-2
Published in Print: 2003-4-1
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Artikel in diesem Heft
- Bis(trimethylphosphan)-η5-cyclopentadienyl- tert- butylimidovanadium( III): Reaktionen mit Schwefel, Selen, Tellur und Iod
- Von Fluorsilylamiden zu Element-Silylamiden und Iminosilanen
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- New Dinuclear Mn(II) Phenanthroline Adipato Complex: Synthesis and Structural and Thermal Characterization of Mn2(phen)2(H2O)2(C6H8O4)2
- Crystal Structure and Magnetic Properties of a New Hetero-Dinuclear CuIIMnII Schiff Base Complex
- High-Pressure Preparation, Crystal Structure, and Properties of RE4B6O15 (RE = Dy, Ho) with an Extension of the “Fundamental Building Block”-Descriptors
- Novel Asymmetrical Dianionic Polyimido-Sulfur(IV)-Ylides
- Decarbonylation of Pentamethylcyclopentadienyl Tetracarbonylvanadium, Cp*V(CO)4, in the Presence of Oxygen. The X-Ray Crystal Structure Analyses of Cp*V(CO)4 and [Cp*V(O)(μ-O)]4
- Formation of a Doubly C,N-Bridged Six-Membered Metallacyclic Bis[(2-imidazolyl)zirconocene] Dication
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- Metallkomplexe mit biologisch wichtigen Liganden, CLI [1]. Metallorganische Komplexe mit R-3-(3-Pyridyl)alaninat
- Methoxyabietane Diterpenoid from the Root of Salvia phlomoides and Structural Correction of Another Diterpene from Cryptomeria japonica
- Access to Orthogonal Protected Phenols – Synthesis of a Silylated Quinol
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- Simple Synthesis, Characterization and Structure of Diorganotin(IV) Complexes Containing the N-(2-Salicylidene)-N'-benzoylhydrazone Ligand
- Synthese monofluorierter cyclopropanoider Nucleosidanaloga
- Crystal Structure of a New Dimethyl Carbonate/2,4,6-Tris(trifluoromethyl)- 1,3,5-triazine 1:1 Adduct
- Synthesis and Molecular Structure of [Fe2Cl2(μ-S-tBu)2(η1-η1-μ-dppe)] (dppe = Ph2P(CH2)2PPh2)
Schlagwörter für diesen Artikel
Sulfido;
Selenido;
Tellurido;
Iodo Complexes of Vanadium(IV);
51V NMR Spectra
Artikel in diesem Heft
- Bis(trimethylphosphan)-η5-cyclopentadienyl- tert- butylimidovanadium( III): Reaktionen mit Schwefel, Selen, Tellur und Iod
- Von Fluorsilylamiden zu Element-Silylamiden und Iminosilanen
- β-CaB4O7: A New Polymorph Synthesized under High-Pressure/High-Temperature Conditions
- New Dinuclear Mn(II) Phenanthroline Adipato Complex: Synthesis and Structural and Thermal Characterization of Mn2(phen)2(H2O)2(C6H8O4)2
- Crystal Structure and Magnetic Properties of a New Hetero-Dinuclear CuIIMnII Schiff Base Complex
- High-Pressure Preparation, Crystal Structure, and Properties of RE4B6O15 (RE = Dy, Ho) with an Extension of the “Fundamental Building Block”-Descriptors
- Novel Asymmetrical Dianionic Polyimido-Sulfur(IV)-Ylides
- Decarbonylation of Pentamethylcyclopentadienyl Tetracarbonylvanadium, Cp*V(CO)4, in the Presence of Oxygen. The X-Ray Crystal Structure Analyses of Cp*V(CO)4 and [Cp*V(O)(μ-O)]4
- Formation of a Doubly C,N-Bridged Six-Membered Metallacyclic Bis[(2-imidazolyl)zirconocene] Dication
- Metallkomplexe mit biologisch wichtigen Liganden, CL [1]. 1,1-Dithiolato-Komplex von Palladium(II), Platin(II) und Gold(I) aus Diphenylmethylenglycinester sowie N,N-Dimethylglycinester und Schwefelkohlenstoff
- Metallkomplexe mit biologisch wichtigen Liganden, CLI [1]. Metallorganische Komplexe mit R-3-(3-Pyridyl)alaninat
- Methoxyabietane Diterpenoid from the Root of Salvia phlomoides and Structural Correction of Another Diterpene from Cryptomeria japonica
- Access to Orthogonal Protected Phenols – Synthesis of a Silylated Quinol
- A New Prenylated Hydroquinone from the Roots of Garcinia atroviridis Griff ex T. Anders (Guttiferae)
- Simple Synthesis, Characterization and Structure of Diorganotin(IV) Complexes Containing the N-(2-Salicylidene)-N'-benzoylhydrazone Ligand
- Synthese monofluorierter cyclopropanoider Nucleosidanaloga
- Crystal Structure of a New Dimethyl Carbonate/2,4,6-Tris(trifluoromethyl)- 1,3,5-triazine 1:1 Adduct
- Synthesis and Molecular Structure of [Fe2Cl2(μ-S-tBu)2(η1-η1-μ-dppe)] (dppe = Ph2P(CH2)2PPh2)
