Startseite Ubergangsmetall-substituierte Phosphane, Arsane und Stibane, LIX [1], Ein Addukt des Me3P-substituierten Ferrio-diphenylphosphans Cp(OC)(Me3P)Fe-PPh2 mit Methylisothiocyanat: Darstellung, Protonierung und Methylierung / Transition Metal Substituted Phosphanes, Arsanes and Stibanes, LIX [1]. An Adduct of the Me3P-Substituted Ferrio-diphenylphosphane Cp(OC)(Me3P)Fe-PPh2 and Methylisothiocyanate: Synthesis, Protonation, and Methylation
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Ubergangsmetall-substituierte Phosphane, Arsane und Stibane, LIX [1], Ein Addukt des Me3P-substituierten Ferrio-diphenylphosphans Cp(OC)(Me3P)Fe-PPh2 mit Methylisothiocyanat: Darstellung, Protonierung und Methylierung / Transition Metal Substituted Phosphanes, Arsanes and Stibanes, LIX [1]. An Adduct of the Me3P-Substituted Ferrio-diphenylphosphane Cp(OC)(Me3P)Fe-PPh2 and Methylisothiocyanate: Synthesis, Protonation, and Methylation

  • Wolfgang Malisch , Andre Spörl , Katharina Thirase und Oliver Fey
Veröffentlicht/Copyright: 2. Juni 2014
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Zeitschrift für Naturforschung B
Aus der Zeitschrift Zeitschrift für Naturforschung B Band 53 Heft 10

Abstract

Treatment of the ferrio-phosphane Cp(OC)2Fe-PPh2 (1) with Me3P (2) yields Cp(OC)(Me3P)Fe-PPh2 (3) via CO-substitution. Reaction of 3 with methylisothiocyanate (4) leads to the formation of the adduct Cp(OC)(Me3P)Fe-PPh2 -C(S)NMe (5), which is regioselectively methylated at the sulfur atom with Mel (6a) or MeSO3CF3 (6b), respectively, to give the cationic complexes [Cp(OC)(Me3P)Fe-PPh2 -C(SMe)=NMe]I/CF3 SO3(7a,b). In contrast, protonation with CF3SO3H (8 ) occurs at the nitrogen atom, yielding [Cp(OC)(Me3P)Fe-PPh2- C(S)-N(H)Me]CF3SO3 (9). The structures of 7b and 9 have been determined by X-ray diffraction analysis

Keywords: Ferrio-phosphanes; Organoisothiocyanates; Adduct Formation; Cationic Phosphane Iron Complexes
Received: 1998-5-12
Published Online: 2014-6-2
Published in Print: 1998-10-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Artikel in diesem Heft

  1. Ubergangsmetall-substituierte Phosphane, Arsane und Stibane, LIX [1], Ein Addukt des Me3P-substituierten Ferrio-diphenylphosphans Cp(OC)(Me3P)Fe-PPh2 mit Methylisothiocyanat: Darstellung, Protonierung und Methylierung / Transition Metal Substituted Phosphanes, Arsanes and Stibanes, LIX [1]. An Adduct of the Me3P-Substituted Ferrio-diphenylphosphane Cp(OC)(Me3P)Fe-PPh2 and Methylisothiocyanate: Synthesis, Protonation, and Methylation
  2. Ubergangsmetall-substituierte Phosphane, Arsane und Stibane, LX [1]. Ferrio-(thiocarbamoyl)phosphane Cp(OC)2 Fe-P(Mes)[C(=S)-N(R)H] (R = Me, Et, f-Bu): Aufbau aus dem Ferrio-mesitylphosphan Cp(OC)2 Fe-P(Mes)H und Organoisothiocyanaten sowie Quaternisierung mit Alkylhalogeniden und Oxidation mit Schwefel / Transition Metal Substituted Phosphanes, Arsanes and Stibanes, LX [1]. Ferrio-(thiocarbamoyl)phosphanes Cp(OC)2Fe-P(Mes)[C(=S)-N(R)H] (R= Me, Et, r-Bu): Build-up from the Ferrio-mesitylphosphane Cp(OC)2Fe-P(Mes)H and Organoisothiocyanates, Quatemization with Alkyl Halides and Oxidation with Sulfur
  3. Phosphenium-Komplexe, 43 [1]. Ringöffnungsreaktionen der dreigliedrigen Phosphametallacyclen {PR2 = P(o-Tol)2, P(Ph)(o-Tol), P(Mes)[C(S)N(H)Et], P(/-Bu)[C(O)N(H)Et} / Phosphenium Complexes, 43 [1]. Ring-Opening Reactions of the Three-Membered Phosphametallacycles {PR1 = P(o-Tol)2, P(Ph)(oTol), P(Mes)[C(S)N(H)Et], P(r-Bu)[C(0)N(H)Et}
  4. Magnesium Bis[D(-)-Mandelate] Dihydrate and Other Alkaline Earth, Alkali, and Zinc Salts of Mandelic Acid
  5. The Basicity of Silylamines and Alkylamines: An Equilibrium Study of the Competitive Borane Adduct Formation
  6. Kristallchemische Beziehungen von CO6O2 [TeO4 (CoAsO5)2] zur Steinsalzstruktur von CoO mit einem Beitrag über magnetische Messungen an CO6O2[TeO4(CoAsO5)2] / Crystal Chemical Relations of Co6O2[TeO4(CoAsO5)2] to the Rocksalt Structure of CoO and a Contribution on Magnetic Measurements of Co6O2[TeO4(CoAsO5)2]
  7. Synthese, Kristallstruktur und Eigenschaften von Triguanidinium-tri--imidocyclotriphosphat-Monohydrat und Tetraguanidinium-tetra-/i-imidocyclotetraphosphat-Tetrahydrat, [C(NH2)3]3(PO2NH)3 · H2O und [C(NH2)3]4(PO2NH)4 · 4 H2O / Synthesis, Crystal Structure, and Properties of Triguanidinium Tri-/i-imidocyclotriphosphate Monohydrate and Tetraguanidinium Tetra-/i-imidocyclotetraphosphate Tetrahydrate, [C(NH2)3]3(PO2NH)3 · H2O and [C(NH2)3]4(PO*NH)4 · 4 H2O
  8. Untersuchungen an Polyhalogeniden, XXXVII [1]. Heptaiodide(3-) von Amminkomplexen des Chroms und Cobalts: Hexamminchrom(III)heptaiodid [Cr(NH3)6](I3)(I4) und die Tri-μ-hydroxo-bis[metall(III)-triammin]heptaiodide [(NH3)3 M(OH)3M(NH3)3](I3)2I mit M = Co, Cr / Studies o f Polyhalides, XXXVII [1]. Heptaiodides(3-) of Ammine Complexes of Chromium and Cobalt: Hexamminechromium(III) heptaiodide [Cr(NH3)6](I3)(I4) and the Tri-μ-hydroxo-bis[metal(III)-triammine] heptaiodides [(NH3)3M(OH)3M(NH3)3](I3)2I with M = Co, Cr
  9. Functionalized 1,1-Ethene Dithiolates as Ligands, V [1]. Synthesis and Crystal Structure of Palladium(II) and Platinum(II) Complexes with Dithioylidene Barbituric Acid Ligands. Molecular Structure of a 2,6-Diaminopyridine-Platinum(II) Barbiturate Complex
  10. Solvothermal Synthesis and Crystal Structure Determination of Tris- (ethyleneamine-ammonium) Tetraselenoantimonat: Non-Centrosymmetry Mediated by an Extended Unusual N-H···N Hydrogen Bonded Network?
  11. Thermische Zersetzung und Lösungskalorimetrie von Ammoniumeuropiumchloriden / Thermal Decomposition and Solution Calorimetry of Ammonium Europium Chlorides
  12. Photochemical Reductive Elimination of Nitrogen from Triazidogallium(III). Generation of Luminescent Gallium(I)
  13. Zur Existenz von [ReNCl4-nFn]- (n = 1-3) Nitridorhenat(VI)-Gemischt- ligandkomplexen -Eine EPR-Untersuchung / EPR Evidence of [ReNCl4-n FnJ– (n = 1-3) Nitridorhenate(VI) Mixed-Ligand Complexes
  14. Synthesis and Crystal Structure of N-[(15,4R)-2-Oxo-pinanyl]-β-alanine Methylester
  15. Synthesis and Conformation of Nucleoside 5'-S-Thiosulfates
  16. Niedere Hydrate aliphatischer primärer Amine. Neue Untersuchungen zu Bildung und Struktur [1] / Lower Hydrates of Aliphatic Primary Amines. New Studies of Formation and Structure [1]
  17. Synthesis and Dimroth Rearrangement of 6-Cyano-l,2,4-triazolo- [4,3-a]pyrimidin-5- and 7-ones. A Novel Alkylation with Orthoesters and a New Participation of the Cyano Group in the Rearrangement
  18. Synthesis and Thermal Properties of Twin Compounds, Alkanediacids 4-(4'-Cyano)-biphenyl Diesters
  19. Synthesis of Pyrrolo-, Thienopyrrolo-, Benzothienopyrroloquinolines as well as Triazoloindole Derivatives
  20. Ab initio MO Optimizations of Osmiumtetracarbonyldihydride and Metallacyclophanes with two Osmium Atoms and their Molecular Complexes with Different Guests
  21. Preparation and Crystal Structure of Cs4Nb2S11
  22. On the Metalation of 2,6-Dimethyl-4-tert-butyl-thiophenol
  23. Kristallstruktur des Oxo-Acetatkomplexes [Co7(μ4- O)2(O2CCH3)10(OPEt3)2] / Crystal Structure of the Oxo-Acetate Complex [Co7(μ4 -O)2(O2CCH3)10(OPEt3)2]
  24. Penol Catalyzed Claisen ortho Ester Rearrangment of Allylic Alcohols with Trimethyl-β-hoxy) ortho Propionate
https://doi.org/10.1515/znb-1998-1001
Schlagwörter für diesen Artikel
Ferrio-phosphanes; Organoisothiocyanates; Adduct Formation; Cationic Phosphane Iron Complexes

Artikel in diesem Heft

  1. Ubergangsmetall-substituierte Phosphane, Arsane und Stibane, LIX [1], Ein Addukt des Me3P-substituierten Ferrio-diphenylphosphans Cp(OC)(Me3P)Fe-PPh2 mit Methylisothiocyanat: Darstellung, Protonierung und Methylierung / Transition Metal Substituted Phosphanes, Arsanes and Stibanes, LIX [1]. An Adduct of the Me3P-Substituted Ferrio-diphenylphosphane Cp(OC)(Me3P)Fe-PPh2 and Methylisothiocyanate: Synthesis, Protonation, and Methylation
  2. Ubergangsmetall-substituierte Phosphane, Arsane und Stibane, LX [1]. Ferrio-(thiocarbamoyl)phosphane Cp(OC)2 Fe-P(Mes)[C(=S)-N(R)H] (R = Me, Et, f-Bu): Aufbau aus dem Ferrio-mesitylphosphan Cp(OC)2 Fe-P(Mes)H und Organoisothiocyanaten sowie Quaternisierung mit Alkylhalogeniden und Oxidation mit Schwefel / Transition Metal Substituted Phosphanes, Arsanes and Stibanes, LX [1]. Ferrio-(thiocarbamoyl)phosphanes Cp(OC)2Fe-P(Mes)[C(=S)-N(R)H] (R= Me, Et, r-Bu): Build-up from the Ferrio-mesitylphosphane Cp(OC)2Fe-P(Mes)H and Organoisothiocyanates, Quatemization with Alkyl Halides and Oxidation with Sulfur
  3. Phosphenium-Komplexe, 43 [1]. Ringöffnungsreaktionen der dreigliedrigen Phosphametallacyclen {PR2 = P(o-Tol)2, P(Ph)(o-Tol), P(Mes)[C(S)N(H)Et], P(/-Bu)[C(O)N(H)Et} / Phosphenium Complexes, 43 [1]. Ring-Opening Reactions of the Three-Membered Phosphametallacycles {PR1 = P(o-Tol)2, P(Ph)(oTol), P(Mes)[C(S)N(H)Et], P(r-Bu)[C(0)N(H)Et}
  4. Magnesium Bis[D(-)-Mandelate] Dihydrate and Other Alkaline Earth, Alkali, and Zinc Salts of Mandelic Acid
  5. The Basicity of Silylamines and Alkylamines: An Equilibrium Study of the Competitive Borane Adduct Formation
  6. Kristallchemische Beziehungen von CO6O2 [TeO4 (CoAsO5)2] zur Steinsalzstruktur von CoO mit einem Beitrag über magnetische Messungen an CO6O2[TeO4(CoAsO5)2] / Crystal Chemical Relations of Co6O2[TeO4(CoAsO5)2] to the Rocksalt Structure of CoO and a Contribution on Magnetic Measurements of Co6O2[TeO4(CoAsO5)2]
  7. Synthese, Kristallstruktur und Eigenschaften von Triguanidinium-tri--imidocyclotriphosphat-Monohydrat und Tetraguanidinium-tetra-/i-imidocyclotetraphosphat-Tetrahydrat, [C(NH2)3]3(PO2NH)3 · H2O und [C(NH2)3]4(PO2NH)4 · 4 H2O / Synthesis, Crystal Structure, and Properties of Triguanidinium Tri-/i-imidocyclotriphosphate Monohydrate and Tetraguanidinium Tetra-/i-imidocyclotetraphosphate Tetrahydrate, [C(NH2)3]3(PO2NH)3 · H2O and [C(NH2)3]4(PO*NH)4 · 4 H2O
  8. Untersuchungen an Polyhalogeniden, XXXVII [1]. Heptaiodide(3-) von Amminkomplexen des Chroms und Cobalts: Hexamminchrom(III)heptaiodid [Cr(NH3)6](I3)(I4) und die Tri-μ-hydroxo-bis[metall(III)-triammin]heptaiodide [(NH3)3 M(OH)3M(NH3)3](I3)2I mit M = Co, Cr / Studies o f Polyhalides, XXXVII [1]. Heptaiodides(3-) of Ammine Complexes of Chromium and Cobalt: Hexamminechromium(III) heptaiodide [Cr(NH3)6](I3)(I4) and the Tri-μ-hydroxo-bis[metal(III)-triammine] heptaiodides [(NH3)3M(OH)3M(NH3)3](I3)2I with M = Co, Cr
  9. Functionalized 1,1-Ethene Dithiolates as Ligands, V [1]. Synthesis and Crystal Structure of Palladium(II) and Platinum(II) Complexes with Dithioylidene Barbituric Acid Ligands. Molecular Structure of a 2,6-Diaminopyridine-Platinum(II) Barbiturate Complex
  10. Solvothermal Synthesis and Crystal Structure Determination of Tris- (ethyleneamine-ammonium) Tetraselenoantimonat: Non-Centrosymmetry Mediated by an Extended Unusual N-H···N Hydrogen Bonded Network?
  11. Thermische Zersetzung und Lösungskalorimetrie von Ammoniumeuropiumchloriden / Thermal Decomposition and Solution Calorimetry of Ammonium Europium Chlorides
  12. Photochemical Reductive Elimination of Nitrogen from Triazidogallium(III). Generation of Luminescent Gallium(I)
  13. Zur Existenz von [ReNCl4-nFn]- (n = 1-3) Nitridorhenat(VI)-Gemischt- ligandkomplexen -Eine EPR-Untersuchung / EPR Evidence of [ReNCl4-n FnJ– (n = 1-3) Nitridorhenate(VI) Mixed-Ligand Complexes
  14. Synthesis and Crystal Structure of N-[(15,4R)-2-Oxo-pinanyl]-β-alanine Methylester
  15. Synthesis and Conformation of Nucleoside 5'-S-Thiosulfates
  16. Niedere Hydrate aliphatischer primärer Amine. Neue Untersuchungen zu Bildung und Struktur [1] / Lower Hydrates of Aliphatic Primary Amines. New Studies of Formation and Structure [1]
  17. Synthesis and Dimroth Rearrangement of 6-Cyano-l,2,4-triazolo- [4,3-a]pyrimidin-5- and 7-ones. A Novel Alkylation with Orthoesters and a New Participation of the Cyano Group in the Rearrangement
  18. Synthesis and Thermal Properties of Twin Compounds, Alkanediacids 4-(4'-Cyano)-biphenyl Diesters
  19. Synthesis of Pyrrolo-, Thienopyrrolo-, Benzothienopyrroloquinolines as well as Triazoloindole Derivatives
  20. Ab initio MO Optimizations of Osmiumtetracarbonyldihydride and Metallacyclophanes with two Osmium Atoms and their Molecular Complexes with Different Guests
  21. Preparation and Crystal Structure of Cs4Nb2S11
  22. On the Metalation of 2,6-Dimethyl-4-tert-butyl-thiophenol
  23. Kristallstruktur des Oxo-Acetatkomplexes [Co7(μ4- O)2(O2CCH3)10(OPEt3)2] / Crystal Structure of the Oxo-Acetate Complex [Co7(μ4 -O)2(O2CCH3)10(OPEt3)2]
  24. Penol Catalyzed Claisen ortho Ester Rearrangment of Allylic Alcohols with Trimethyl-β-hoxy) ortho Propionate
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