Synthesis and characterization of graphene quantum dots

References

[1] Demming A. King of the elements? Nanotechnology. 2010;21:300201.10.1088/0957-4484/21/30/300201Suche in Google Scholar PubMed

[2] Mcdonough W. Carbon is not the enemy. Nature. 2016;539:349–51.10.1038/539349aSuche in Google Scholar PubMed

[3] Ajayan PM, Ebbesen TW. Nanometre-size tubes of carbon. Rep Prog Phys. 1997;1025:1025–62.10.1088/0034-4885/60/10/001Suche in Google Scholar

[4] Wallace PR. The band theory of graphite. Phys Rev. 1947;71:622–634.10.1103/PhysRev.71.622Suche in Google Scholar

[5] Bacon M, Bradley SJ, Nann T. Graphene quantum dots. Part Part Syst Charact. 2014;31:415–28.10.1002/ppsc.201300252Suche in Google Scholar

[6] Geim AK, Novoselov KS. The Rise of Graphene. Nat Mater. 2007;6:183–91.10.1142/9789814287005_0002Suche in Google Scholar

[7] Cao Y, Fatemi V, Fang S, Watanabe K, Taniguchi T, Kaxiras E, et al. Unconventional superconductivity in magic-angle graphene superlattices. Nature. 2018;556:43–50.10.1038/nature26160Suche in Google Scholar PubMed

[8] Sk MA, Ananthanarayanan A, Huang L, Lim KH, Chen P. Revealing the tunable photoluminescence properties of graphene quantum dots. J Mater Chem C. 2014;2:6954–60.10.1039/C4TC01191KSuche in Google Scholar

[9] Yan Y, Chen J, Li N, Tian J, Li K, Jiang J, et al. Systematic bandgap engineering of graphene quantum dots and applications for photocatalytic water splitting and CO2 reduction. ACS Nano. 2018;12:3523–32.10.1021/acsnano.8b00498Suche in Google Scholar PubMed

[10] Shinde DB, Pillai VK. Electrochemical resolution of multiple redox events for graphene quantum dots. Angew Chem Int Ed Engl. 2013;52:2482–5.10.1002/anie.201208904Suche in Google Scholar PubMed

[11] Ponomarenko LA, Schedin F, Katsnelson MI, Yang R, Hill EW, Novoselov KS, et al. Chaotic dirac billiard in graphene quantum dots. Science (80-.). 2008;320:356–8.10.1126/science.1154663Suche in Google Scholar PubMed

[12] Velasco J, Lee J, Wong D, Kahn S, Tsai HZ, Costello J, et al. Visualization and control of single-electron charging in bilayer graphene quantum dots. Nano Lett. 2018;18:5104–10.10.1021/acs.nanolett.8b01972Suche in Google Scholar PubMed

[13] Kundu S, Yadav RM, Shelke MV, Narayanan TN, Vajtai R, Ajayan PM, et al. Synthesis of N, F and S co-doped graphene quantum dots. Nanoscale. 2015;7:11515–9.10.1039/C5NR02427GSuche in Google Scholar

[14] Kundu S, Sarojinijeeva P, Karthick R, Anantharaj G, Saritha G, Bera R, et al. Enhancing the efficiency of DSSCs by the modification of TiO2 photoanodes using N, F and S, co-doped graphene quantum dots. Electrochim Acta. 2017;242:337–43.10.1016/j.electacta.2017.05.024Suche in Google Scholar

[15] Ye R, Xiang C, Lin J, Peng Z, Huang K, Yan Z, et al. Coal as an abundant source of graphene quantum dots. Nat Commun. 2013;4:1–6.10.1038/ncomms3943Suche in Google Scholar PubMed

[16] Ju J, Chen W. Graphene quantum dots as fluorescence probes for sensing metal ions: synthesis and applications. Curr Org Chem. 2015;19:1150–62.10.2174/1385272819666150318222547Suche in Google Scholar

[17] Du Y, Gao S. Chemically doped fluorescent carbon and graphene quantum dots for bioimaging, sensor, catalytic and photoelectronic applications. Nanoscale. 2016;8:2532–43.10.1039/C5NR07579CSuche in Google Scholar PubMed

[18] Zhu S, Song Y, Zhao X, Shao J, Zhang J, Yang B. The photoluminescence mechanism in carbon dots ( Graphene Quantum Dots, Carbon Nanodots, and Polymer Dots): current state and future perspective. Nano Res. 2015;8:355–81.10.1007/s12274-014-0644-3Suche in Google Scholar

[19] Gao X, Du C, Zhuang Z, Chen W. Carbon quantum dots-based nanoprobes for metal ions detection. J Mater Chem C. 2016;4:6927–45.10.1039/C6TC02055KSuche in Google Scholar

[20] Musselman KP, Ibrahim KH, Yavuz M, Musselman KP, Ibrahim KH, Yavuz M. Research update: beyond graphene — synthesis of functionalized quantum dots of 2D materials and their applications research update: beyond graphene — synthesis of functionalized quantum dots of 2D materials and their applications. APL Mater. 2018;6:120701.10.1063/1.5067250Suche in Google Scholar

[21] Xu Y, Wang X, Zhang L, Lv F. Chem soc rev recent progress in two-dimensional inorganic. Chem Soc Rev. 2018;47:586–625.10.1039/C7CS00500HSuche in Google Scholar

[22] Slonczewski JC, Weiss PR. Band structure of graphite. Phys Rev. 1958;330:272–9.10.1103/PhysRev.109.272Suche in Google Scholar

[23] Li Y, Shu H, Niu X, Wang J. Electronic and optical properties of edge-functionalized graphene quantum dots and the underlying mechanism. J Phys Chem. 2015;119:24950–7.10.1021/acs.jpcc.5b05935Suche in Google Scholar

[24] Li Y, Shu H, Wang S, Wang J. Electronic and optical properties of graphene quantum dots: the role of many-body effects. J Phys Chem C. 2015;119:4983–9.10.1021/jp506969rSuche in Google Scholar

[25] Morgenstern M, Freitag N, Vaid A, Pratzer M, Liebmann M. Graphene quantum dots probed by scanning tunneling spectroscopy and transport spectroscopy after local anodic oxidation. arXiv preprint arXiv:1505.04092. 2015;1–14.10.1002/pssr.201510164Suche in Google Scholar

[26] Wurm J, Rycerz A, Adagideli I, Wimmer M, Richter K, Baranger HU. Symmetry classes in graphene quantum dots: universal spectral statistics, weak localization, and conductance fluctuations. Phys Rev Lett. 2009;102:6–9.10.1103/PhysRevLett.102.056806Suche in Google Scholar PubMed

[27] Okamoto T, Sasagawa A, Harada Y, Nakano S, Norimatsu W, Kusunoki M, et al. Visualization of zero-dimensional plasmons in graphene quantum dots with near-field infrared microscopy. Int. Conf. Infrared, Millimeter, Terahertz Waves, IRMMW-THz. 2018–Septe. 2018:1–2.10.1109/IRMMW-THz.2018.8510367Suche in Google Scholar

[28] Tian W, Li W, Yu W, Liu X. A review on lattice defects in graphene: types, generation, effects and regulation. Micromachines. 2017;8:1–15.10.3390/mi8050163Suche in Google Scholar

[29] Terrones M, Botello-Méndez AR, Campos-Delgado J, López-Urías F, Vega-Cantú YI, Rodríguez-Macías FJ, et al. Graphene and graphite nanoribbons: morphology, properties, synthesis, defects and applications. Nano Today. 2010;5:351–72.10.1016/j.nantod.2010.06.010Suche in Google Scholar

[30] Libisch F, Stampfer C, Burgdörfer J. Graphene quantum dots: beyond a dirac billiard. Phy Rev B. 2009;79:1–6.10.1103/PhysRevB.79.115423Suche in Google Scholar

[31] Ziatdinov M, Lim H, Fujii S, Kusakabe K, Kiguchi M, Enoki T, et al. Chemically induced topological zero mode at graphene armchair Edges †. Phys Chem Chem Phys. 2017;19:5145–54.10.1039/C6CP08352HSuche in Google Scholar

[32] Ziatdinov M, Fujii S, Kusakabe K, Kiguchi M, Mori T, Enoki T. Visualization of electronic states on atomically smooth graphitic edges with different types of hydrogen termination. Phys Rev B Phys. 2013;87:115427.10.1103/PhysRevB.87.115427Suche in Google Scholar

[33] Yeh TF, Huang WL, Chung CJ, Chiang IT, Chen LC, Chang HY, et al. Elucidating quantum confinement in graphene oxide dots based on excitation-wavelength-independent photoluminescence. J Phys Chem Lett. 2016;7:2087–92.10.1021/acs.jpclett.6b00752Suche in Google Scholar PubMed

[34] Li L, Peng J, Zhao J, Zhu J. Focusing on luminescent graphene quantum dots: current status and future perspectives. Nanoscale 2013;5:4015–39.10.1039/c3nr33849eSuche in Google Scholar PubMed

[35] Shen J, Zhu Y, Chen C, Yang X, Li C. Facile preparation and upconversion luminescence of graphene quantum dots. Chem Commun. 2011;47:2580–2.10.1039/C0CC04812GSuche in Google Scholar

[36] Zhuo S, Shao M, Lee S-T. Upconversion and downconversion fluorescent graphene quantum dots: ultrasonic preparation and photocatalysis. ACS Nano. 2012;6:1059–64.10.1021/nn2040395Suche in Google Scholar PubMed

[37] Wang Z, Zeng H, Sun L. Graphene quantum dots: versatile photoluminescence for energy, biomedical, and environmental applications. J Mater Chem C Mater Opt Elec Dev. 2015;3:1157–65.10.1039/C4TC02536ASuche in Google Scholar

[38] Kundu S, Malik B, Pattanayak DK, Pitchai R, Pillai VK. Role of specific N-containing active sites in interconnected graphene quantum dots for the enhanced electrocatalytic activity towards oxygen evolution reaction. Chem Sel. 2017;2:9943–6.10.1002/slct.201701952Suche in Google Scholar

[39] Kundu S, Malik B, Pattanayak DK, Pitchai R, Pillai VK. Unraveling the hydrogen evolution reaction active sites in N-functionalized interconnected graphene quantum dots. Chem Sel. 2017;2:4511–5.10.1002/slct.201700631Suche in Google Scholar

[40] kundu S, Malik B, Pattanayak DK, Pillai VK. Effect of dimensionality and doping in quasi “one dimensional (1-D)” N – doped graphene nanoribbons on the oxygen reduction reaction. ACS Appl Mater Interfaces. 2017;9:38409–18.10.1021/acsami.7b09601Suche in Google Scholar PubMed

[41] Shinde DB, Dhavale VM, Kurungot S, Pillai VK. Electrochemical preparation of nitrogen-doped graphene quantum dots and their size-dependent electrocatalytic activity for oxygen reduction. Bull Mater Sci. 2015;38:435–42.10.1007/s12034-014-0834-3Suche in Google Scholar

[42] Zhang R, Adsetts JR, Nie Y, Sun X, Ding Z. Electrochemiluminescence of nitrogen- and sulfur-doped graphene quantum dots. Carbon N Y. 2018;129:45–53.10.1016/j.carbon.2017.11.091Suche in Google Scholar

[43] Li LL, Ji J, Fei R, Wang CZ, Lu Q, Zhang JR, et al. A facile microwave avenue to electrochemiluminescent two-color graphene quantum dots. Adv Funct Mater. 2012;22:2971–9.10.1002/adfm.201200166Suche in Google Scholar

[44] Zhang D, Zhang Z, Wu Y, Fu K, Chen Y, Li W, et al. Biomaterials systematic evaluation of graphene quantum dot toxicity to male mouse sexual behaviors, reproductive and o Ff spring health. Biomaterials. 2019;194:215–32.10.1016/j.biomaterials.2018.12.001Suche in Google Scholar PubMed

[45] Wang M, Sun Y, Cao X, Peng G, Javed I, Kakinen A, et al. Graphene quantum dots against human IAPP aggregation and toxicity: in vivo. Nanoscale. 2018;10:19995–20006.10.1039/C8NR07180BSuche in Google Scholar PubMed PubMed Central

[46] Jin K, Gao H, Lai L, Pang Y, Zheng S, Niu Y, et al. Preparation of highly fluorescent sulfur doped graphene quantum dots for live cell imaging. J Lumin. 2018;197:147–52.10.1016/j.jlumin.2018.01.028Suche in Google Scholar

[47] Xie Y, Wan B, Yang Y, Cui X, Xin Y, Guo LH. Cytotoxicity and autophagy induction by graphene quantum dots with different functional groups. J Environ Sci (China). 2018;77:198–209.10.1016/j.jes.2018.07.014Suche in Google Scholar PubMed

[48] Chandra A, Deshpande S, Shinde DB, Pillai VK, Singh N. Mitigating the cytotoxicity of graphene quantum dots and enhancing their applications in bioimaging and drug delivery. ACS Macro Lett. 2014;3:1064–8.10.1021/mz500479kSuche in Google Scholar PubMed

[49] Shen J, Zhu Y, Yang X, Li C. Graphene quantum dots: emergent nanolights for bioimaging, sensors, catalysis and photovoltaic devices. Chem Commun (Camb). 2012;48:3686–99.10.1039/c2cc00110aSuche in Google Scholar PubMed

[50] Shen J, Zhu Y, Yang X, Zong J, Zhang J, Li C. One-pot hydrothermal synthesis of graphene quantum dots surface-passivated by polyethylene glycol and their photoelectric conversion under near-infrared light. New J Chem. 2012;36:97–101.10.1039/C1NJ20658CSuche in Google Scholar

[51] Eda G, Lin YY, Mattevi C, Yamaguchi H, Chen HA, Chen IS, et al. Blue photoluminescence from chemically derived graphene oxide. Adv Mater. 2010;22:505–9.10.1002/adma.200901996Suche in Google Scholar PubMed

[52] Fan L, Hu Y, Wang X, Zhang L, Li F, Han D, et al. Fluorescence resonance energy transfer quenching at the surface of graphene quantum dots for ultrasensitive detection of TNT. Talanta. 2012;101:192–7.10.1016/j.talanta.2012.08.048Suche in Google Scholar PubMed

[53] Li H, He X, Liu Y, Huang H, Lian S, Lee ST, et al. One-step ultrasonic synthesis of water-soluble carbon nanoparticles with excellent photoluminescent properties. Carbon N Y. 2011;49:605–9.10.1016/j.carbon.2010.10.004Suche in Google Scholar

[54] Zhu Y, Murali S, Stoller MD, Velamakanni A, Piner RD, Ruoff RS. Microwave assisted exfoliation and reduction of graphite oxide for ultracapacitors. Carbon N Y. 2010;48:2118–22.10.1016/j.carbon.2010.02.001Suche in Google Scholar

[55] Massabeau S, Riccardi E, Rosticher M, Valmorra F, Huang P, Tignon J, et al. THz band gap in encapsulated graphene quantum dots. IEEE. 2018. DOI:10.1109/IRMMW-THz.2018.8509964.Suche in Google Scholar

[56] Zhou J, Booker C, Li R, Zhou X, Sham T. An electrochemical avenue to blue luminescent nanocrystals from multiwalled carbon nanotubes ( MWCNTs). J Am Chem Soc. 2007;8:744–5.10.1021/ja0669070Suche in Google Scholar PubMed

[57] Baker SN, Baker GA. Luminescent carbon nanodots: emergent nanolights. Angew Chemie Int Ed. 2010;49:6726–44.10.1002/anie.200906623Suche in Google Scholar PubMed

[58] Zhao Q-L, Zhang Z-L, Huang B-H, Peng J, Zhang M, Pang D-W. Facile preparation of low cytotoxicity fluorescent carbon nanocrystals by electrooxidation of graphite. Chem Commun. 2008;281:5116–8.10.1039/b812420eSuche in Google Scholar PubMed

[59] Li Y, Hu Y, Zhao Y, Shi G, Deng L, Hou Y, et al. An electrochemical avenue to green-luminescent graphene quantum dots as potential electron-acceptors for photovoltaics. Adv Mater. 2011;23:776–80.10.1002/adma.201003819Suche in Google Scholar PubMed

[60] Shinde DB, Pillai VK. Electrochemical preparation of luminescent graphene quantum dots from multiwalled carbon nanotubes. Chem A Eur J. 2012;18:12522–8.10.1002/chem.201201043Suche in Google Scholar PubMed

[61] Gokus T, Nair RR, Bonetti A, Böhmler M, Lombardo A, Novoselov KS, et al. Making graphene luminescent by oxygen plasma treatment. ACS Nano. 2009;3:3963–8.10.1021/nn9012753Suche in Google Scholar PubMed

[62] Casiraghi C, Hartschuh A, Lidorikis E, Qian H. Rayleigh imaging of graphene and graphene layers. Nano Nano Lett. 2007;7:2711–7.10.1021/nl071168mSuche in Google Scholar PubMed

[63] Ferrari AC, Meyer JC, Scardaci V, Casiraghi C, Lazzeri M, Mauri F, et al. Raman spectrum of graphene and graphene layers. Phys Rev Lett. 2006;97:1–4.10.1103/PhysRevLett.97.187401Suche in Google Scholar PubMed

[64] Chen J-L, Yan X-P. Ionic strength and ph reversible response of visible and near-infrared fluorescence of graphene oxide nanosheets for monitoring the extracellular PH. Chem Commun (Camb). 2011;47:3135–7.10.1039/c0cc03999cSuche in Google Scholar PubMed

[65] Tang D, Liu J, Yan X, Kang L. The graphene oxide derived graphene quantum dots with different photoluminescence properties and peroxidase-like catalytic activity duosi. RSC Adv. 2016;6:50609–17.10.1039/C5RA26279HSuche in Google Scholar

[66] Zhou X, Zhang Y, Wang C, Wu X, Yang Y, Zheng B, et al. Photo-fenton reaction of graphene oxide: a new strategy to prepare graphene quantum dots for DNA cleavage. ACS Nano. 2012;6:6592–9.10.1021/nn301629vSuche in Google Scholar PubMed

[67] Lin L, Zhang S. Creating high yield water soluble luminescent graphene quantum dots via exfoliating and disintegrating carbon nanotubes and graphite flakes. Chem Commun (Camb). 2012;48:10177–9.10.1039/c2cc35559kSuche in Google Scholar PubMed

[68] Tang L, Ji R, Cao X, Lin J, Jiang H, Li X, et al. Deep ultraviolet photoluminescence graphene quantum dots. ACS Nano. 2012;6:5102–10.10.1021/nn300760gSuche in Google Scholar PubMed

[69] Kim J, Suh JS. Size-controllable and low-cost fabrication of graphene quantum dots using thermal plasma jet. ACS Nano. 2014;8:4190–6.10.1021/nn404180wSuche in Google Scholar PubMed

[70] Li Q, Zhang S, Dai L, Li L. Nitrogen-doped colloidal graphene quantum dots and their size-dependent electrocatalytic activity for the oxygen reduction reaction. J Am Chem Soc. 2012;134:18932–5.10.1021/ja309270hSuche in Google Scholar PubMed

[71] Lu J, Yeo PSE, Gan CK, Wu P, Loh KP. Transforming C60 molecules into graphene quantum dots. Nat Nanotechnol. 2011;6:247–52.10.1038/nnano.2011.30Suche in Google Scholar PubMed

[72] Yan X, Cui X, Li B, Li L. Large, solution-processable graphene quantum dots as light absorbers for photovoltaics. Nano Lett. 2010;10:1869–73.10.1021/nl101060hSuche in Google Scholar PubMed

[73] Yan X, Cui X, Li L. Synthesis of large, stable colloidal graphene quantum dots with tunable size. J Am Chem Soc. 2010;132:5944–5.10.1021/ja1009376Suche in Google Scholar PubMed

[74] Liu R, Wu D, Feng X. Dots with uniform morphology. J Am Chem Soc. 2011;133:15221–3.10.1021/ja204953kSuche in Google Scholar PubMed

[75] Dong Y, Guo CX, Chi Y, Li CM. Reply to comment on “one-step and high yield simultaneous preparation of single- and multi-layer graphene quantum dots from CX-72 carbon black”. J Mater Chem. 2012;22:21777–8.10.1039/c2jm34130aSuche in Google Scholar

[76] Peng J, Gao W, Gupta BK, Liu Z, Romero-Aburto R, Ge L, et al. Graphene quantum dots derived from carbon fibers. Nano Lett. 2012;12:844–9.10.1021/nl2038979Suche in Google Scholar PubMed

[77] Dong Y, Chen C, Zheng X, Gao L, Cui Z, Yang H, et al. One-step and high yield simultaneous preparation of single- and multi-layer. J Mater Chem. 2012;22:8764–6.10.1039/c2jm30658aSuche in Google Scholar

[78] Ding Z, Li F, Wen J, Wang X, Sun R. Gram-scale synthesis of single-crystalline graphene quantum dots derived from lignin biomass. Green Chem. 2018;20:1383–90.10.1039/C7GC03218HSuche in Google Scholar

[79] Xu Y, Wang S, Hou X, Sun Z, Jiang Y, Dong Z, et al. Coal-derived nitrogen, phosphorus and sulfur co-doped graphene quantum dots: a promising ion fluorescent probe. Appl Surf Sci. 2018;445:519–26.10.1016/j.apsusc.2018.03.156Suche in Google Scholar

[80] Kundu S, Ragupathy P, Pillai VK. Effect of reversible lithium ion intercalation on the size-dependent optical properties of graphene quantum dots. J Electrochem Soc. 2016;163:A1112–A1119.10.1149/2.0041607jesSuche in Google Scholar

[81] Pan D, Guo L, Zhang J, Xi C, Xue Q, Huang H, et al. Cutting Sp2 clusters in graphene sheets into colloidal graphene quantum dots with strong green fluorescence. J Mater Chem. 2012;22:3314–8.10.1039/c2jm16005fSuche in Google Scholar

[82] Tetsuka H, Asahi R, Nagoya A, Okamoto K, Tajima I, Ohta R, et al. Optically tunable amino-functionalized graphene quantum dots. Adv Mater. 2012;24:5333–8.10.1002/adma.201201930Suche in Google Scholar PubMed

[83] Zhu S, Zhang J, Qiao C, Tang S, Li Y, Yuan W, et al. Strongly green-photoluminescent graphene quantum dots for bioimaging applications. Chem Commun (Camb). 2011;47:6858–60.10.1039/c1cc11122aSuche in Google Scholar PubMed

[84] Shin Y, Lee J, Yang J, Park J, Lee K, Kim S, et al. Mass production of graphene quantum dots by one-pot synthesis directly from graphite in high yield. Small. 2014;10:866–70.10.1002/smll.201302286Suche in Google Scholar PubMed

[85] Li W, Li M, Liu Y, Pan D, Li Z, Wang L, et al. Three minute ultrarapid microwave-assisted synthesis of bright fluorescent graphene quantum dots for live cell staining and white LEDs. ACS Appl Nano Mater. 2018;1:1623–30.10.1021/acsanm.8b00114Suche in Google Scholar

[86] Zhu Y, Wang G, Jiang H, Chen L, Zhang X. One-step ultrasonic synthesis of graphene quantum dots with high quantum yield and their application in sensing alkaline phosphatase. Chem Commun (Camb). 2014;51:948–51.10.1039/C4CC07449ASuche in Google Scholar

[87] Zhang M, Bai L, Shang W, Xie W, Ma H, Fu Y, et al. Facile synthesis of water-soluble, highly fluorescent graphene quantum dots as a robust biological label for stem cells. J Mater Chem. 2012;22:7461–7.10.1039/c2jm16835aSuche in Google Scholar

[88] Dong Y, Shao J, Chen C, Li H, Wang R, Chi Y, et al. Blue luminescent graphene quantum dots and graphene oxide prepared by tuning the carbonization degree of citric acid. Carbon N Y. 2012;50:4738–43.10.1016/j.carbon.2012.06.002Suche in Google Scholar

[89] Zhang L, Zhang Z-Y, Liang R-P, Li Y-H, Qiu J-D. Boron-doped graphene quantum dots for selective glucose sensing based on the “abnormal” aggregation-induced photoluminescence enhancement. Anal Chem. 2014;86:4423–30.10.1021/ac500289cSuche in Google Scholar PubMed

[90] Li S, Li Y, Cao J, Zhu J, Fan L, Li X. Sulfur-doped graphene quantum dots as a novel fluorescent probe for highly selective and sensitive detection of Fe 3+. Anal Chem. 2014;86:10201–7.10.1021/ac503183ySuche in Google Scholar PubMed

[91] Li Y, Zhao Y, Cheng H, Hu Y, Shi G, Dai L, et al. Nitrogen-doped graphene quantum dots with oxygen-rich functional groups. J Am Chem Soc. 2012;134:15–18.10.1021/ja206030cSuche in Google Scholar PubMed

[92] Qu D, Zheng M, Zhang L, Zhao H, Xie Z, Jing X, et al. Formation mechanism and optimization of highly luminescent N-doped graphene quantum dots. Sci Rep. 2014;4. DOI:10.1038/srep05294.Suche in Google Scholar PubMed PubMed Central

[93] Qu D, Zheng M, Du P, Zhou Y, Zhang L, Li D, et al. Highly luminescent S, N Co-doped graphene quantum dots with broad visible absorption bands for visible light photocatalyst. Nanoscale. 2013;5:12272–7.10.1039/c3nr04402eSuche in Google Scholar PubMed

[94] Zhang B-X, Gao H, Li X-L. Synthesis and optical properties of nitrogen and sulfur co-doped graphene quantum dots. New J Chem. 2014;38:4615–21.10.1039/C4NJ00965GSuche in Google Scholar

[95] Wang L, Wang Y, Xu T, Liao H, Yao C, Liu Y, et al. Quantum dots with superior optical properties. Nat Commun. 2014;5:1–9.10.1038/ncomms6357Suche in Google Scholar PubMed

[96] Kumar GS, Roy R, Sen D, Ghorai UK, Thapa R, Mazumder N, et al. Amino-functionalized graphene quantum dots: origin of tunable heterogeneous Photoluminescence. Nanoscale. 2014;6:3384–91.10.1039/c3nr05376hSuche in Google Scholar PubMed

[97] Kosynkin DV, Higginbotham AL, Sinitskii A, Lomeda JR, Dimiev A, Price BK, et al. Longitudinal unzipping of carbon nanotubes to form graphene nanoribbons. Nature. 2009;458:872–6.10.1038/nature07872Suche in Google Scholar PubMed

[98] Li Z, Zhang W, Luo Y, Yang J, Hou JG. How graphene is cut upon oxidation. J Am Chem Soc. 2009;131:6320–1.10.1021/ja8094729Suche in Google Scholar PubMed

[99] Li JL, Kudin KN, McAllister MJ, Prud’homme RK, Aksay IA, Car R. Oxygen-driven unzipping of graphitic materials. Phys Rev Lett. 2006;96:5–8.10.1103/PhysRevLett.96.176101Suche in Google Scholar PubMed

[100] Achadu OJ, Nyokong T. Application of graphene quantum dots functionalized with thymine and thymine-appended zinc phthalocyanine as novel photoluminescent nanoprobes. New J Chem. 2016;40:8727–36.10.1039/C6NJ03285KSuche in Google Scholar

[101] Cui P. Effect of boron and nitrogen doping on carrier relaxation dynamics of graphene quantum dots. Mater Res Express. 2018;5:1–13.10.1088/2053-1591/aacadbSuche in Google Scholar

[102] Basak T, Basak T. Effect of carrier doping and external electric field on the optical properties of graphene quantum dots. IOP Conf Ser Mater Sci Eng. 2018;310:1–8.10.1088/1757-899X/310/1/012014Suche in Google Scholar

[103] Kundu S, Ghosh S, Fralaide M, Narayanan TN, Pillai VK, Talapatra S. Fractional photo-current dependence of graphene quantum dots prepared from carbon nanotubes. Phys Chem Chem Phys. 2015;17:24566–9.10.1039/C5CP03306CSuche in Google Scholar PubMed

[104] Kundu S, Ragupathy P, Pillai VK. Effect of reversible lithium ion intercalation on the size-dependent optical properties of graphene quantum dots. J Electrochem Soc. 2016;163:1112–9.10.1149/2.0041607jesSuche in Google Scholar

[105] Kim S, Shin DH, Kim CO, Kang SS, Sin S. Size-dependence of raman scattering from graphene quantum dots: interplay between shape and thickness size-dependence of raman scattering from graphene quantum dots: interplay between shape and thickness. Appl Phys Lett. 2013;102:053108–1–053108–3.10.1063/1.4790641Suche in Google Scholar

[106] Liu Q, Zhang J, He H, Huang G, Xing B, Jia J. Green preparation of high yield fluorescent graphene quantum dots from coal-tar-pitch by mild oxidation. Nanomaterials. 2018;8:844–54.10.3390/nano8100844Suche in Google Scholar PubMed PubMed Central

[107] Feng J, Dong H, Pang B, Chen Y, Yu L, Dong L. Tuning electronic and optical properties of graphene quantum dots by selective boronization. J Mater Chem C. 2019;7:237–48.10.1039/C8TC03863ESuche in Google Scholar

[108] Kundu S, Yadav RM, Narayanan TN, Shelke MV, Vajtai R, Ajayan PM, et al. Synthesis of N, F and S co-doped graphene quantum dots. Nanoscale. 2015;7:11515–9.10.1039/C5NR02427GSuche in Google Scholar

[109] Zhang Z, Zhang J, Chen N, Qu L. Graphene quantum dots: an emerging material for energy-related applications and beyond. Energy Environ Sci. 2012;5:8869–90.10.1039/c2ee22982jSuche in Google Scholar

[110] Zhou J, Li C, Yin L, Wang L, Zhang J. Facile way to fabricate high quality white led with yellow graphene quantum dots. Proc. - 2018 19th Int Conf Electron Packag Technol ICEPT. 2018;2018:1598–1601.10.1109/ICEPT.2018.8480513Suche in Google Scholar

[111] Li X, Rui M, Song J, Shen Z, Zeng H. Carbon and graphene quantum dots for optoelectronic and energy devices: a review. Adv Funct Mater. 2015;25:4929–47.10.1002/adfm.201501250Suche in Google Scholar

[112] Dinari M, Mohsen M, Meysam M. Dye-sensitized solar cells based on nanocomposite of polyaniline/graphene quantum dots. J Mater Sci. 2016;51:2964–71.10.1007/s10853-015-9605-9Suche in Google Scholar

[113] Kim J, Lee B, Kim YJ, Hwang SW. Enhancement of dye-sensitized solar cells Ef Fi ciency using graphene quantum dots as photoanode. Bull Korean Chem Soc. 2018;40:56–61.10.1002/bkcs.11664Suche in Google Scholar

[114] Song SH, Jang M-H, Chung J, Jin SH, Kim BH, Hur S-H, et al. Highly efficient light-emitting diode of graphene quantum dots fabricated from graphite intercalation compounds. Adv Opt Mater. 2014;2:1016–23.10.1002/adom.201400184Suche in Google Scholar

[115] Wang S, Li Z, Xu X, Zhang G, Li Y, Peng Q. Amino-functionalized graphene quantum dots as cathode interlayer for efficient organic solar cells: quantum dot size on interfacial modification ability and photovoltaic performance. Adv Mater Interf. 2018;1801480:1–9.10.1002/admi.201801480Suche in Google Scholar

[116] Chao D, Zhu C, Xia X, Liu J, Zhang X, Wang J, et al. Graphene quantum dots coated VO 2 arrays for highly durable electrodes for Li and Na Ion batteries. Nano Lett. 2015;15:565–73.10.1021/nl504038sSuche in Google Scholar PubMed

[117] Zhang Y, Zhang K, Jia K, Liu G, Ren S, Li K, et al. Preparation of coal-based graphene quantum dots/α -Fe 2 O 3 nanocomposites and their lithium-ion storage properties. Fuel. 2019;241:646–52.10.1016/j.fuel.2018.12.030Suche in Google Scholar

[118] Guo J, Zhu H, Sunb Y, Tanga L, Zhanga X. Boosting the lithium storage performance of MoS2 with graphene quantum dots. J Mater Chem A. 2016;4:4783–9.10.1039/C6TA00592FSuche in Google Scholar

[119] Liu W, Feng Y, Yan X, Chen J, Xue Q. Superior micro-supercapacitors based on graphene quantum dots. Mater Views. 2013;23:4111–22.10.1002/adfm.201203771Suche in Google Scholar

[120] Li Z, Cao L, Qin P, Liu X, Chen Z, Wang L, et al. Nitrogen and oxygen co-doped graphene quantum dots with high capacitance performance for micro-supercapacitors. Carbon N Y. 2018;139:67–75.10.1016/j.carbon.2018.06.042Suche in Google Scholar

[121] Jin H, Huang H, He Y, Feng X, Wang S, Dai L, et al. Graphene quantum dots supported by graphene nanoribbons with ultrahigh electrocatalytic performance for oxygen reduction. J Am Chem Soc. 2015;137:7588–91.10.1021/jacs.5b03799Suche in Google Scholar PubMed

[122] Fei H, Ye R, Ye G, Gong Y, Peng Z, Fan X, et al. Boron- and nitrogen-doped graphene quantum dots/graphene hybrid nanoplatelets as E Ffi cient electrocatalysts for oxygen reduction. ACS Nano. 2014;8:10837–43.10.1021/nn504637ySuche in Google Scholar PubMed

[123] Guo J, Zhu H, Sun Y, Tang L, Zhang X. Doping MoS2 with graphene quantum dots: structural and electrical engineering towards enhanced electrochemical hydrogen evolution. Electrochim Acta. 2016;211:603–10.10.1016/j.electacta.2016.05.148Suche in Google Scholar

[124] Li Y, Shu H, Niu X, Wang J. Electronic and optical properties of edge-functionalized graphene quantum dots and the underlying mechanism. J Phys Chem C. 2015;119:24950–7.10.1021/acs.jpcc.5b05935Suche in Google Scholar

[125] Yan Y, Liang Q-F, Zhao H, Wu C-Q. Thermoelectric properties of hexagonal graphene quantum dots. Phys Lett A. 2012;376:1154–8.10.1016/j.physleta.2012.02.013Suche in Google Scholar

[126] Guo X, Lu GL, Chen J. Graphene-based materials for photoanodes in dye-sensitized solar cells. Front Energy Res. 2015;3:1–15.10.3389/fenrg.2015.00050Suche in Google Scholar

[127] Gupta V, Chaudhary N, Srivastava R, Sharma GD, Bhardwaj R, Chand S. Luminscent graphene quantum dots for organic photovoltaic devices. J Am Chem Soc. 2011;133:9960–3.10.1021/ja2036749Suche in Google Scholar PubMed

[128] Lim SP, Pandikumar A, Lim HN, Ramaraj R, Huang NM. Boosting photovoltaic performance of dye-sensitized solar cells using silver nanoparticle-decorated N,S-Co-Doped-TiO2 photoanode. Sci Rep. 2015;5:1–14.10.1038/srep11922Suche in Google Scholar PubMed PubMed Central

[129] Khan F, Kim JH. N-functionalized graphene quantum dots with ultrahigh quantum yield and large stokes shift: efficient downconverters for CIGS solar cells. ACS Photonics. 2018;5:4637–743.10.1021/acsphotonics.8b01125Suche in Google Scholar

[130] Kuila T, Bose S, Mishra AK, Khanra P, Kim NH, Lee JH. Chemical functionalization of graphene and its applications. Prog Mater Sci. 2012;57:1061–105.10.1016/j.pmatsci.2012.03.002Suche in Google Scholar

[131] Hai X, Feng J, Chen X, Wang J. Tuning the optical properties of graphene quantum dots for biosensing and bioimaging. J Mater Chem B. 2018;6:3219–34.10.1039/C8TB00428ESuche in Google Scholar PubMed

[132] Tang W. Fluorescent graphene quantum dots as traceable, PH-sensitive drug delivery systems. Int J Nanomed. 2015;10:6709–24.10.2147/IJN.S91864Suche in Google Scholar PubMed PubMed Central

[133] Cai Z, Li F, Wu P, Ji L, Zhang H, Cai C, et al. Synthesis of nitrogen-doped graphene quantum dots at low temperature for electrochemical sensing trinitrotoluene. Anal Chem. 2015;87:11803–11.10.1021/acs.analchem.5b03201Suche in Google Scholar PubMed

[134] Liu Q, Wang K, Huan J, Zhu G, Qian J, Mao H, et al. Graphene quantum dots enhanced electrochemiluminescence of cadmium sulfide nanocrystals for ultrasensitive determination of pentachlorophenol. Analyst. 2014;139:2912–8.10.1039/c4an00307aSuche in Google Scholar PubMed

[135] Markovic ZM, Ristic BZ, Arsikin KM, Klisic DG, Harhaji-Trajkovic LM, Todorovic-Markovic BM, et al. Graphene quantum dots as autophagy-inducing photodynamic agents. Biomaterials. 2012;33:7084–92.10.1016/j.biomaterials.2012.06.060Suche in Google Scholar PubMed

[136] Shiddiky MJA, Rauf S, Kithva PH, Trau M. Graphene/quantum dot bionanoconjugates as signal amplifiers in stripping voltammetric detection of EpCAM biomarkers. Biosens Bioelectron. 2012;35:251–7.10.1016/j.bios.2012.02.057Suche in Google Scholar PubMed

[137] Tang J, Ma X, Liu J, Zheng S, Wang J. Simultaneous determination of hydroquinone and catechol using carbon glass electrode modified with graphene quantum dots. Int J Electrochem Sci Int. 2018;13:11250–62.10.20964/2018.11.52Suche in Google Scholar

[138] Ju J, Zhang R, He S, Chen W. Nitrogen-doped graphene quantum dots-based fluorescent probe for the sensitive turn-on detection of glutathione and its cellular imaging. RSC Adv. 2014;4:52583–9.10.1039/C4RA10601FSuche in Google Scholar

[139] Akbarnia A, Zare HR. A voltammetric assay for microRNA-25 based on the use of amino-functionalized graphene quantum dots and Ss- and Ds-DNAs as gene probes. Microchim Acta. 2018;185. DOI:10.1007/s00604-018-3037-6.Suche in Google Scholar PubMed

[140] Bharathi S, John SA. Highly selective naked eye detection of Vitamin B1 in the presence of other vitamins using graphene quantum dots capped gold nanoparticles. New J Chem. 2019;43:2111–7.10.1039/C8NJ05734FSuche in Google Scholar

[141] Ben Aoun S. Nanostructured carbon electrode modified with n-doped graphene quantum dots – Chitosan nanocomposite: a sensitive electrochemical dopamine sensor. R Soc Open Sci. 2017;4:1–12.10.1098/rsos.171199Suche in Google Scholar PubMed PubMed Central

[142] Wang W, Wang Z, Liu J, Peng Y, Yu X, Wang W, et al. Materials and interfaces one-pot facile synthesis of graphene quantum dots from rice husks for Fe3 + sensing one-pot facile synthesis of graphene quantum dots from rice husks for Fe 3 + sensing. Ind Eng Chem Res. 2018;57:9144–50.10.1021/acs.iecr.8b00913Suche in Google Scholar

[143] Tang Y, Li J, Guo Q, Nie G. Sensors and actuators B: chemical an ultrasensitive electrochemiluminescence assay for Hg 2 + through graphene quantum dots and poly ( 5-Formylindole) nanocomposite. Sens Actuat B Chem. 2019;282:824–30.10.1016/j.snb.2018.11.151Suche in Google Scholar

[144] Ju J, Chen W. In situ growth of surfactant-free gold nanoparticles on nitrogen- doped graphene quantum dots for electrochemical detection of hydrogen peroxide in biological environments. Anal Chem. 2015;87:1903−10.10.1021/ac5041555Suche in Google Scholar PubMed

[145] Zhang R, Chen W. Nitrogen-doped carbon quantum dots: facile synthesis and application as a “turn-off” fluorescent probe for detection of Hg2+ Ions. Biosens Bioelectron. 2014;55:83–90.10.1016/j.bios.2013.11.074Suche in Google Scholar PubMed

[146] Gao X, Lu Y, Zhang R, He S, Ju J, Liu M. One-pot synthesis of carbon nanodots for Fl uorescence turn-on detection of Ag + based on the Ag + -induced enhancement of Fl Uorescence †. J Mater Chem C. 2015;3:2302–9.10.1039/C4TC02582BSuche in Google Scholar

[147] Ju J, Chen W. Synthesis of highly fluorescent nitrogen-doped graphene quantum dots for sensitive, label-free detection of Fe (III) in aqueous media. Biosens Bioelectron. 2014;58:219–25.10.1016/j.bios.2014.02.061Suche in Google Scholar PubMed

[148] Ju J, Zhang R, Chen W. Photochemical deposition of surface-clean silver nanoparticles on nitrogen-doped graphene quantum dots for sensitive colorimetric detection of glutathione. Sens Actuat B. 2016;228:66–73.10.1016/j.snb.2016.01.007Suche in Google Scholar

[149] Barreiro A, Van Der Zant HSJ, Vandersypen LMK. Quantum dots at room temperature carved out from few-layer graphene. Nano Lett. 2012;12:6096–100.10.1021/nl3036977Suche in Google Scholar PubMed

[150] Kubatkin S, Danilov A, Hjort M, Cornil J, Brédas J-L, Stuhr-Hansen N, et al. Single-electron transistor of a single organic molecule with access to several redox states. Nature. 2003;425:698–701.10.1038/nature02010Suche in Google Scholar PubMed

[151] Osorio EA, O’Neill K, Stuhr-Hansen N, Nielsen OF, Bjørnholm T, Van Der Zant HSJ. Addition energies and vibrational fine structure measured in electromigrated single-molecule junctions based on an oligophenylenevinylene derivative. Adv Mater. 2007;19:281–5.10.1002/adma.200601876Suche in Google Scholar