Application of polyurethane membrane with surface modified ZSM-5 for pervaporation of phenol/water mixture
-
Hong Ye
,
Xiang Zhang
Abstract
In the present work, β-cyclodextrin was grafted to the surface of ZSM-5 via 2,3-epoxypropyl trimethylammonium chloride (ETMAC) and epichlorohydrin (EPI) as the bridging agent by ion exchange and sequential grafting. The mixed matrix membranes were prepared using polyurethane (PU) and ZSM-5 before and after modification. Modified ZSM-5 and corresponding MMM were characterized by Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA), and scanning electron microscope (SEM). These membranes were applied for the removal of phenol from aqueous solution in pervaporation process. The results showed that modified ZSM-5 dispersed homogeneously in polymer. The flux and pervaporation separation index of PU increased greatly with a limited decrease in selectivity by the addition of modified ZSM-5. The increased feed temperature enhanced both the flux and separation factor of PU and modified PU membranes.
Acknowledgments
The authors gratefully acknowledge the financial support provided by Beijing Natural Science Foundation (L140009), The Importation and Development of High-Caliber Talents Project of Beijing Municipal Institutions (CIT&TCD201404032), and National Science Foundation of China (20906001).
References
[1] Li C, Zhang X, Hao X, Feng X, Pang X, Zhang H. Chem. Eng. Sci. 2015, 127, 106–114.10.1016/j.ces.2015.01.039Suche in Google Scholar
[2] Younis SA, El-Gendy NS, El-Azab WI, Moustafa YM, Hashem AI. Energ. Source. Part A 2014, 36, 2566–2578.10.1080/15567036.2013.855845Suche in Google Scholar
[3] Hararah MA, Ibrahim KA, Al-Muhtaseb AH, Yousef RI, Abu-Surrah A, Qatatsheh A. J. Appl. Polym. Sci. 2010, 117, 1908–1913.10.1002/app.32107Suche in Google Scholar
[4] Kujawski W, Warszawski A, Ratajczak WO, Porbski T, Capa AWA, Ostrowska I. Sep. Purif. Technol. 2004, 40, 123–132.10.1016/j.seppur.2004.01.013Suche in Google Scholar
[5] Hao X, Pritzker M, Feng X. J. Membr. Sci. 2009, 335, 96–102.10.1016/j.memsci.2009.02.036Suche in Google Scholar
[6] Gupta T, Pradhan NC, Adhikari B. J. Membr. Sci. 2003, 217, 43–53.10.1016/S0376-7388(03)00069-3Suche in Google Scholar
[7] Gupta T, Pradhan NC, Adhikari B. B. Mater. Sci. 2002, 25, 533–536.10.1007/BF02710544Suche in Google Scholar
[8] Das S, Banthia AK, Adhikari B. Chem. Eng. J. 2008, 138, 215–223.10.1016/j.cej.2007.06.030Suche in Google Scholar
[9] Ye H, Wang J, Chen X, Shi S. J. Macromol. Sci. A 2013, 50, 661–669.10.1080/10601325.2013.784582Suche in Google Scholar
[10] Zhuang X, Chen X, Su Y, Luo J, Cao W, Wan Y. J. Membr. Sci. 2015, 493, 37–45.10.1016/j.memsci.2015.06.043Suche in Google Scholar
[11] Zhou H, Su Y, Chen X, Yi S, Wan Y. Sep. Purif. Technol. 2010, 75, 286–294.10.1016/j.seppur.2010.08.017Suche in Google Scholar
[12] Liu G, Xiangli F, Wang W, Liu S, Jin W. Chem. Eng. J. 2011, 174, 495–503.10.1016/j.cej.2011.06.004Suche in Google Scholar
[13] Gao J, Liu M, Wang X, Guo X. Ind. Eng. Chem. Res. 2010, 49, 2194–2199.10.1021/ie901360ySuche in Google Scholar
[14] Sun H, Feng X, Wang S, Ang HM, Tadé MO. Chem. Eng. J. 2011, 170, 270–277.10.1016/j.cej.2011.03.059Suche in Google Scholar
[15] Lv Z, Zhang L, Yang Y, Bi X. Mater. Design 2011, 32, 3624–3628.10.1016/j.matdes.2011.02.016Suche in Google Scholar
[16] Ebadi Amooghin A, Omidkhah M, Kargari A. J. Membr. Sci. 2015, 490, 364–379.10.1016/j.memsci.2015.04.070Suche in Google Scholar
[17] Zhuang X, Chen X, Su Y, Luo J, Feng S, Zhou H, Wan Y. J. Membr. Sci. 2016, 499, 386–395.10.1016/j.memsci.2015.10.018Suche in Google Scholar
[18] Li X, Zhu K, Hao X. Water Sci. Technol. 2009, 60, 329–337.10.2166/wst.2009.315Suche in Google Scholar
[19] Jiraratananon R, Sampranpiboon P, Uttapap D, Huang RYM. J. Membr. Sci. 2002, 210, 389–409.10.1016/S0376-7388(02)00420-9Suche in Google Scholar
[20] Lin J, Chen H, Yao L. Appl. Surf. Sci. 2010, 256, 5978–5984.10.1016/j.apsusc.2010.03.105Suche in Google Scholar
[21] Mueller R, Kammler HK, Wegner K, Pratsinis SE. Langmuir 2003, 19, 160–165.10.1021/la025785wSuche in Google Scholar
[22] Das P, Ray SK. J. Ind. Eng. Chem. 2016, 34, 321–336.10.1016/j.jiec.2015.12.007Suche in Google Scholar
[23] Xue C, Yang D, Du G, Chen L, Ren J, Bai F. Biotechnol. Biofuels 2015, 8, 105–113.10.1186/s13068-015-0288-xSuche in Google Scholar
[24] Qureshi N, Meagher MM, Hutkins RW. J. Membr. Sci. 1999, 158, 115–125.10.1016/S0376-7388(99)00010-1Suche in Google Scholar
[25] Ferreira Marques MF, Lopes Gil C, Gordo PM, Kajcsos Z, de Lima AP, Queiroz DP, de Pinho MN. Radiat. Phys. Chem. 2003, 68, 573–576.10.1016/S0969-806X(03)00234-2Suche in Google Scholar
[26] Wu P, Field RW, England R, Brisdon BJ. J. Membr. Sci. 2001, 190, 147–157.10.1016/S0376-7388(01)00408-2Suche in Google Scholar
[27] Pithan F, Staudt-Bickel C. ChemPhysChem 2003, 4, 967–973.10.1002/cphc.200300707Suche in Google Scholar PubMed
[28] Budd PM, Elabas ES, Ghanem BS, Makhseed S, McKeown NB, Msayib KJ, Tattershall CE, Wang D. Adv. Mater. 2004, 16, 456–459.10.1002/adma.200306053Suche in Google Scholar
©2017 Walter de Gruyter GmbH, Berlin/Boston
Artikel in diesem Heft
- Frontmatter
- Original articles
- 3D printing of hydroxyapatite polymer-based composites for bone tissue engineering
- Studies on the effects of 4,4′-dihydroxyphenyl on crystallization and melting behavior of poly (butylene terephthalate)
- Effect of the particulate morphology of resin on the gelation process of PVC plastisols
- Effect of aluminum nitride concentration on different physical properties of low density polyethylene based nanocomposites
- Application of polyurethane membrane with surface modified ZSM-5 for pervaporation of phenol/water mixture
- Synergistic effects of hybridization of carbon black and carbon nanotubes on the mechanical properties and thermal conductivity of a rubber blend system
- Electrical conductivity of carbon nanotube/polypropylene composites prepared through microlayer extrusion technology
- Mechanical performance and electromagnetic shielding effectiveness of composites based on Ag-plating cellulose micro-nano fibers and epoxy
- Effect of screw configuration on the dispersion of nanofillers in thermoset polymers
- Study of a novel co-rotating non-twin screw extruder in processing flame retardant polymer materials
- Thermal influences in the star-pre-distributor of a spiral mandrel die
Artikel in diesem Heft
- Frontmatter
- Original articles
- 3D printing of hydroxyapatite polymer-based composites for bone tissue engineering
- Studies on the effects of 4,4′-dihydroxyphenyl on crystallization and melting behavior of poly (butylene terephthalate)
- Effect of the particulate morphology of resin on the gelation process of PVC plastisols
- Effect of aluminum nitride concentration on different physical properties of low density polyethylene based nanocomposites
- Application of polyurethane membrane with surface modified ZSM-5 for pervaporation of phenol/water mixture
- Synergistic effects of hybridization of carbon black and carbon nanotubes on the mechanical properties and thermal conductivity of a rubber blend system
- Electrical conductivity of carbon nanotube/polypropylene composites prepared through microlayer extrusion technology
- Mechanical performance and electromagnetic shielding effectiveness of composites based on Ag-plating cellulose micro-nano fibers and epoxy
- Effect of screw configuration on the dispersion of nanofillers in thermoset polymers
- Study of a novel co-rotating non-twin screw extruder in processing flame retardant polymer materials
- Thermal influences in the star-pre-distributor of a spiral mandrel die
