Synthesis of spherical porous cross-linked glutaraldehyde/poly(vinyl alcohol) hydrogels
-
Sadao Araki
,
Yuko Shirakura
Abstract
Spherical glutaraldehyde cross-linked poly(vinyl alcohol) (PVA) hydrogels (G-PVA) were prepared in three steps: gelatification, cross-linking, and removal of alginate. Gelatification was carried out by dropping a solution of alginate, PVA, and glutaraldehyde into a calcium chloride solution to form calcium alginate. Calcium alginate gels were prepared at 20°C, 40°C, 60°C, and 80°C to study the effect of gelatification temperature on the formation of pores on the surface of G-PVA. The effect of the alginate content was studied. PVA and glutaraldehyde were cross-linked by immersion of the gels in a solution of H2SO4 and Na2SO4. The effect of sodium alginate and inorganic salts, such as MgSO4 and K2SO4, on the formation of pores on the surface of G-PVA was confirmed.
Acknowledgments
This work was partially supported by the MEXT-Supported Program for the Strategic Research Foundation at Private Universities, 2012-2016 (S1201026). We appreciate the valuable cooperation of Kuraray Co., Ltd. for this research.
References
[1] Hezaveh H, Muhamad II. Chem. Eng. Res. Des. 2013, 9, 508–519.10.1016/j.cherd.2012.08.014Suche in Google Scholar
[2] Killion JA, Geever LM, Cloonan M, Grehan L, Waldron C, Quinn K, Lyons J, Devine DM, Higginbotham CL. J. Polym. Res. 2014, 21, 538.10.1007/s10965-014-0538-9Suche in Google Scholar
[3] Kumar M, Tripathi BP, Shahi VK. J. Hazardous Mater. 2009, 172, 1041–1048.10.1016/j.jhazmat.2009.07.108Suche in Google Scholar
[4] Zain NAM, Suhaimi MS, Idris A. Process. Biochem. 2011, 46, 2122–2129.10.1016/j.procbio.2011.08.010Suche in Google Scholar
[5] Sahmetliogle E, Yuruk H, Toppare L, Cianga I, Yacci Y. Polym. Int. 2006, 53, 2138–2144.10.1002/pi.1644Suche in Google Scholar
[6] Khoo K-M, Ting Y-P. Biochem. Eng. J. 2001, 8, 51–59.10.1016/S1369-703X(00)00134-0Suche in Google Scholar
[7] Takei T, Ikeda K, Ijima H, Kawakami K, Yoshida M, Hatate Y. Polym. Bull. 2010, 65, 283–291.10.1007/s00289-010-0253-6Suche in Google Scholar
[8] Uemura Y, Hamakawa N, Yoshizawa H, Ando H, Ijichi K, Hatate Y. Chem. Eng. Commun. 2000, 177, 1–14.10.1080/00986440008912157Suche in Google Scholar
[9] Park JK, Chang HN. Biotechnol. Adv. 2000, 18, 303–319.10.1016/S0734-9750(00)00040-9Suche in Google Scholar
[10] Idris A, Zain NAM, Suhaimi MS. Process. Biochem. 2008, 43, 331–338.10.1016/j.procbio.2007.12.008Suche in Google Scholar
[11] De Queiroz AAA, Passos ED, Alves SD, Silva GS, Higa OZ, Vitolo M. J. Appl. Polym. Sci. 2006, 102, 1553–1560.10.1002/app.23444Suche in Google Scholar
[12] Takei T, Ikeda K, Ijima H, Kawakami K. Process. Biochem. 2011, 46, 566–571.10.1016/j.procbio.2010.10.011Suche in Google Scholar
[13] Yamamoto H, Heyamoto N, Yatsuhashi T, Matsui T, Takami Y, Shibata J. Kagaku Kogaku Ronbunshu 2003, 29, 395–399.10.1252/kakoronbunshu.29.395Suche in Google Scholar
[14] Yamamoto H, Kushida A, Heyamoto N, Takami Y, Murayama N, Shibata J. Mater. Trans. 2003, 44, 2436–2440.10.2320/matertrans.44.2436Suche in Google Scholar
[15] Gotoh T, Nakatani Y, Sakohara S. J. Appl. Polym. Sci. 1998, 69, 895–906.10.1002/(SICI)1097-4628(19980801)69:5<895::AID-APP8>3.0.CO;2-HSuche in Google Scholar
[16] Kishi R, Miura T, Kihara H, Asano T, Shibata M, Yosomiya R. J. Appl. Polym. Sci. 2003, 89, 75–84.10.1002/app.11996Suche in Google Scholar
[17] Ichimura K. Die Markromol. Chem. 1987, 188, 763–768.10.1002/macp.1987.021880410Suche in Google Scholar
[18] Ichijo H, Suehiro T, Yamauchi A, Ogawa S. J. Appl. Polym. Sci. 1982, 27, 1665–1674.10.1002/app.1982.070270523Suche in Google Scholar
[19] Caykara T, Kucuktepe S, Turan E. Polym. Int. 2007, 53, 532–537.10.1002/pi.2166Suche in Google Scholar
[20] Kanaya T. Sen’i Gakkaishi 2002, 58, 240–244.10.2115/fiber.58.P_240Suche in Google Scholar
[21] Kanaya T, Takeshita H, Nishikoji Y, Ohkura M, Nishida K, Kaji K. Supramol. Sci. 1998, 5, 215–221.10.1016/S0968-5677(98)00009-1Suche in Google Scholar
[22] Takeshita H, Kanaya T, Nishida K, Kaji K. Macromolecules 2001, 34, 7894–7898.10.1021/ma010539xSuche in Google Scholar
[23] Pae BJ, Moon TJ, Lee CH, Ko MB, Park M, Lim S, Kim J, Choe CR. Kor. Polym. J. 1997, 5, 126–130.Suche in Google Scholar
[24] Gopishetty V, Tokarev I, Minko S. J. Mater. Chem. 2012, 22, 19482–19487.10.1039/c2jm31778hSuche in Google Scholar
©2016 Walter de Gruyter GmbH, Berlin/Boston
Artikel in diesem Heft
- Frontmatter
- Original articles
- Preparation and characterization of graphene oxide/PMMA nanocomposites with amino-terminated vinyl polydimethylsiloxane phase interfaces
- Effect of exfoliated graphite nanoplatelets on thermal and heat deflection properties of kenaf polypropylene hybrid nanocomposites
- Synthesis of spherical porous cross-linked glutaraldehyde/poly(vinyl alcohol) hydrogels
- Influence of process parameters on property of PP/EPDM blends prepared by a novel vane extruder
- Influence of processing conditions on heat sealing behavior and resultant heat seal strength for peelable heat sealing of multilayered polyethylene films
- Thermal degradation kinetics and lifetime of HDPE/PLLA/pro-oxidant blends
- Effect of notch sensitivity on the mechanical properties of HA/PEEK functional gradient biocomposites
- The influence of melt mixing on the stability of cellulose acetate and its carbon nanotube composites
- Experimental analysis of resin infusion in air cushion method
- 3D-MID manufacturing via laser direct structuring with nanosecond laser pulses
Artikel in diesem Heft
- Frontmatter
- Original articles
- Preparation and characterization of graphene oxide/PMMA nanocomposites with amino-terminated vinyl polydimethylsiloxane phase interfaces
- Effect of exfoliated graphite nanoplatelets on thermal and heat deflection properties of kenaf polypropylene hybrid nanocomposites
- Synthesis of spherical porous cross-linked glutaraldehyde/poly(vinyl alcohol) hydrogels
- Influence of process parameters on property of PP/EPDM blends prepared by a novel vane extruder
- Influence of processing conditions on heat sealing behavior and resultant heat seal strength for peelable heat sealing of multilayered polyethylene films
- Thermal degradation kinetics and lifetime of HDPE/PLLA/pro-oxidant blends
- Effect of notch sensitivity on the mechanical properties of HA/PEEK functional gradient biocomposites
- The influence of melt mixing on the stability of cellulose acetate and its carbon nanotube composites
- Experimental analysis of resin infusion in air cushion method
- 3D-MID manufacturing via laser direct structuring with nanosecond laser pulses
