Startseite Influence of process parameters on property of PP/EPDM blends prepared by a novel vane extruder
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Influence of process parameters on property of PP/EPDM blends prepared by a novel vane extruder

  • Wei Zou , Rong-yuan Chen , Chengran Wu und Jin-ping Qu EMAIL logo
Veröffentlicht/Copyright: 16. März 2016
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Abstract

In this study, thermoplastic elastomers based on polypropylene (PP) and ethylene-propylene-diene terpolymer (EPDM) were prepared via direct melt blending in a novel vane extruder. The influence of processing temperature and rotor speed on the degree of cross-linking of the EPDM phase, the tensile properties, the melting behavior and the crystallization morphology of PP/EPDM blends was investigated. It was observed that the volume fraction (Vr) of the vulcanizate arriving swelling equilibrium reached the maximum value when the processing temperature was 190°C. The tensile properties showed better performance at 195°C, at which the PP/EPDM blend obtained good dispersive mixing performance. Moreover, the Vr of the vulcanizate arriving swelling equilibrium reached the maximum value when the rotor speed was 60 rpm, at which the dispersive mixing performance and tensile properties of the PP/EPDM blend were better.


Corresponding author: Jin-ping Qu, National Engineering Research Center of Novel Equipment for Polymer Processing, The Key Laboratory of Polymer Processing Engineering of Ministry of Education South China University of Technology, Guangzhou 510640, China, e-mail:

Acknowledgments:

The authors wish to acknowledge the National Natural Science Foundation of China-Guangdong Joint Foundation Project (U1201242), 973 Program (2012CB025902), the Major Scientific Research Projects of Guangdong Province (2014B010132002), the National Research Foundation for the Doctoral Program of Higher Education of China (20120172130004), the Special-funded Program on National Key Scientific Instruments and Equipment Development of China (Grant no. 2012YQ230043), the National Nature Science Foundation of China (Grant no. 51435005) and Young Scientists Fund of the National Natural Science Foundation of China (Grant no. 51403068) for financial support.

References

[1] Goharpey F, Nazockdast H, Katbab AA. Polym. Eng. Sci. 2005, 45, 84–94.10.1002/pen.20232Suche in Google Scholar

[2] Winters R, Lugtenburg J, Litvinov VM, Van Duin M, De Groot HJM. Polymer 200, 42, 9745–9752.10.1016/S0032-3861(01)00504-3Suche in Google Scholar

[3] Sker M, Philippe C, Mosto B, Philippe C. Macromol. Mat. Eng. 2011, 296, 909–920.10.1002/mame.201000406Suche in Google Scholar

[4] Wu H, Tian M, Zhang L, Tian H, Wu Y, Ning N, Chan TW. ACS Sustainable Chem. Eng. 2014, 3, 26–32.10.1021/sc500391gSuche in Google Scholar

[5] Xiao HW, Huang SQ, Jiang T. J. Appl. Polym. Sci. 2004, 92, 357–362.10.1002/app.20026Suche in Google Scholar

[6] Hamzah MS, Hidayah IN, Mariatti M, Kamarol M. J. Reinf. Plast. Comp. 2014, 33, 193–1940.10.1177/0731684413504325Suche in Google Scholar

[7] Chen Y, Xu C, Cao L, Wang Y, Cao X. Polym. Test. 2012, 31, 728–736.10.1016/j.polymertesting.2012.05.010Suche in Google Scholar

[8] Chen Y, Xu C, Cao, L, Wang, Y, Fang, L. J. Phys. Chem. B 2013, 117, 7819–7825.10.1021/jp403293bSuche in Google Scholar PubMed

[9] Lima P, Oliveira J, Costa V. J. Appl. Polym. Sci. 2014, 13, 631–644.Suche in Google Scholar

[10] Mirzadeh A, Lafleur PG, Kamal MR, Dubois C. Polym. Eng. Sci. 2012, 52, 1099–1110.10.1002/pen.22178Suche in Google Scholar

[11] Naderi G, Lafleur PG, Dubois C. Polym. Compos. 2008, 29, 1301–1309.10.1002/pc.20495Suche in Google Scholar

[12] Silva ALN, Rocha MC, Coutinho, FM. Polym. Test. 2002, 21, 289–293.10.1016/S0142-9418(01)00084-8Suche in Google Scholar

[13] Dai YQ, Wang B, Wang, SJ, Jiang T, Cheng SY. Radiat. Phys. Chem. 2003, 68, 493–496.10.1016/S0969-806X(03)00216-0Suche in Google Scholar

[14] Mousa A. Int. J. Polym. Mater. 2005, 54, 619–631.10.1080/00914030490499099Suche in Google Scholar

[15] Ao YH, Sun SL, Tan ZY, Zhou C, Zhang HX. J. Appl. Polym. Sci. 2006, 102, 3949–3954.10.1002/app.24257Suche in Google Scholar

[16] Antunes CF, Van Duin M, Machado AV. Polym. Test. 2011, 30, 907–915.10.1016/j.polymertesting.2011.08.013Suche in Google Scholar

[17] Wu H, Ning N, Zhang L, Tian H, Wu Y, Tian M. J. Polym. Res. 2013, 20, 1–8.10.1007/s10965-013-0321-3Suche in Google Scholar

[18] Qiao Z, Tai Q, Song L, Hu Y, Lv P, Jie G, Zhang D. Polym. Adv. Technol. 2011, 22, 2602–2608.10.1002/pat.1808Suche in Google Scholar

[19] Wu H, Tian M, Zhang L, Tian H, Wu Y, Ning N. Soft Matter 2014, 10, 1816–1822.10.1039/c3sm52375fSuche in Google Scholar PubMed

[20] Yetkin SH, Unal H, Mimaroglu A, Findik F. Polym.-Plast. Technol. 2013, 52, 433–439.10.1080/03602559.2012.748802Suche in Google Scholar

[21] Khosrokhavar R, Naderi G, Bakhshandeh GR, Ghoreishy MHR. Iran Polym. J. 2011, 20, 41–53.Suche in Google Scholar

[22] Qu JP. U.S. Patent 8, 573, 828. (2013).10.1093/jiplp/jpt160Suche in Google Scholar

[23] QU JP, Liu LM, Tan B, Liu SR, Chen HX, Feng YH. Polym. Compos. 2012, 33, 185–191.10.1002/pc.21261Suche in Google Scholar

[24] Qu JP, Zhang GZ, Chen HZ, Yin XC, He HZ. Polym. Eng. Sci. 2012, 52, 2147–2156.10.1002/pen.23176Suche in Google Scholar

[25] Qu JP, Yang ZT, Yin XC, He HZ, Feng, YH. Polym.-Plast. Technol. 2009, 48, 1269–1274.10.1080/03602550903204121Suche in Google Scholar

[26] Qu JP, Zhao XQ, Li JB, Cai SQ. J. Appl. Polym. Sci. 2013, 127, 3923–3932.10.1002/app.36806Suche in Google Scholar

[27] Wu ZH, Zhao YQ, Zhang GZ, Yang ZT, Qu JP. J. Appl. Polym. Sci. 2013, 130, 2328–2335.10.1002/app.39434Suche in Google Scholar

[28] Qu JP, Chen HZ, Liu SR, Tan B, Liu LM, Yin XC, Guo RB. J. Appl. Polym. Sci. 2013, 128, 3576–3585.10.1002/app.38573Suche in Google Scholar

[29] Jia S, Qu JP, Wu C, Liu W, Chen R, Zhai S, Chen, F. Langmuir 2013, 29, 13509–13517.10.1021/la4023079Suche in Google Scholar PubMed

Received: 2015-9-6
Accepted: 2015-12-29
Published Online: 2016-3-16
Published in Print: 2016-11-1

©2016 Walter de Gruyter GmbH, Berlin/Boston

Heruntergeladen am 3.12.2025 von https://www.degruyterbrill.com/document/doi/10.1515/polyeng-2015-0386/pdf
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