Photodegradation of Malachite Green Using Immobilized TiO2 and Factorial Design
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Patricio Palacios
Abstract
The effect of the variables: initial pH (4-10), concentration of the dye (3-17 ppm), irradiation wavelength (254-360 nm) and sustrate: H2O2 molar ratio (1:1-1:9) on the photocatalytic degradation of malachite green using TiO2 immobilized on glass Raschig rings was studied. The analysis was planned as a fractional factorial design in order to determine the best affordable experimental conditions to diminish the concentration of this highly toxic and persistent dye, and to use the data as a starting point for the removal of this compound from polluted industrial waters present in industrial salmon cultures found in southern lakes of Chile. Interestingly, the best conditions were achieved when the solution was irradiated with 360 nm wavelength under alkaline conditions arising from the results a negligible effect of the H2O2, making possible to consider the use of solar light to carry on this process.
© 2016 by Walter de Gruyter Berlin/Boston
Artikel in diesem Heft
- Preface (TiO2-11 Section)
- Preface (AOTs-12 Section)
- Photocatalytic Decomposition of Formaldehyde Using Titania Coated Lime Tile
- TiO2-Nitrogen Modified for Water Decolourisation under VIS Radiation
- FTIR Studies of the Surface of TiO2, Fe-TiO2 and Fe-C-TiO2 Photocatalysts in Phenol Oxidation Via the Photo-Fenton Process
- Using Titania Photocatalysts to Degrade Toluene in a Combined Adsorption and Photocatalysis Process
- Photoelectrochemical Decomposition of VOCs on an Anodized TiO2 Plate
- Enhancement and Modeling of the Photocatalytic Degradation of Benzoic Acid
- Reactivity Indices for ortho/para Monosubstituted Phenols
- Modeling of the Photocatalytic Degradation Reactions of Aromatic Pollutants: A Solvent Effect Model
- Photodegradation of Malachite Green Using Immobilized TiO2 and Factorial Design
- Adsorption and Photodegradation of Humic Acids by Nano-Structured TiO2 for Water Treatment
- Photocatalytic Reductive Destruction of Azo Dyes by Polyoxometalates
- Effect of the Sintering Temperature on the Photocatalytic Activity of CdO + CdTiO3 Thin Films
- Photocatalytic Activity in Zn2TiO4 + ZnO Thin Films Obtained by the Sol-gel Process
- TiO2-Based Materials for Toluene Photocalytic Oxidation: Water Vapor Influence
- Influence of Aqueous Solubility of Various VOCs on Their Photocatalytic Degradation
- Photocatalysis: A Powerful Technology for Cold Storage Applications
- Some Remarks on So-Called Heterogeneous Photocatalysis and on the Mechanical Application of the Langmuir-Hinshelwood Kinetic Model
Artikel in diesem Heft
- Preface (TiO2-11 Section)
- Preface (AOTs-12 Section)
- Photocatalytic Decomposition of Formaldehyde Using Titania Coated Lime Tile
- TiO2-Nitrogen Modified for Water Decolourisation under VIS Radiation
- FTIR Studies of the Surface of TiO2, Fe-TiO2 and Fe-C-TiO2 Photocatalysts in Phenol Oxidation Via the Photo-Fenton Process
- Using Titania Photocatalysts to Degrade Toluene in a Combined Adsorption and Photocatalysis Process
- Photoelectrochemical Decomposition of VOCs on an Anodized TiO2 Plate
- Enhancement and Modeling of the Photocatalytic Degradation of Benzoic Acid
- Reactivity Indices for ortho/para Monosubstituted Phenols
- Modeling of the Photocatalytic Degradation Reactions of Aromatic Pollutants: A Solvent Effect Model
- Photodegradation of Malachite Green Using Immobilized TiO2 and Factorial Design
- Adsorption and Photodegradation of Humic Acids by Nano-Structured TiO2 for Water Treatment
- Photocatalytic Reductive Destruction of Azo Dyes by Polyoxometalates
- Effect of the Sintering Temperature on the Photocatalytic Activity of CdO + CdTiO3 Thin Films
- Photocatalytic Activity in Zn2TiO4 + ZnO Thin Films Obtained by the Sol-gel Process
- TiO2-Based Materials for Toluene Photocalytic Oxidation: Water Vapor Influence
- Influence of Aqueous Solubility of Various VOCs on Their Photocatalytic Degradation
- Photocatalysis: A Powerful Technology for Cold Storage Applications
- Some Remarks on So-Called Heterogeneous Photocatalysis and on the Mechanical Application of the Langmuir-Hinshelwood Kinetic Model
