Volume 39, Issue 7

In the chemical industry, a typical problem is the appropriate treatment of the process wastewaters. The biological treatment cannot be usually applied because of the high content of organochemical compounds. However, phsycicochemical methods can significantly contribute to the proper treatment of the process wastewater and usually also allows the recovery of the polluting materials. This phenomenon opens the application area of physicochemical methods for the treatment of process wastewater and can contribute not only to the aims of the circular economy but also to the zero liquid discharge. Besides literature studies, authors’ own results and innovations have been also presented. The treatment strategy for pharmaceutical process wastewater is reviewed in detail, which also serves to point out that hybrid methods can be usually efficient to solve the primary goal–maximum recovery and reuse of polluting materials.

In recent years, TiO 2 /ZnO hybrid nanostructures have been attracting the interest of the scientific community due to their excellent photoelectrochemical properties. The main advantage of TiO 2 /ZnO hybrid nanostructures over other photocatalysts based on semiconductor materials lies in their ability to form heterojunctions in which the valence and conduction bands of both semiconductors are intercalated. This factor produces a decrease in the band gap and the recombination rate and an increase in the light absorption range. The aim of this review is to perform a revision of the main methods to synthesise TiO 2 /ZnO hybrid nanostructures by ZnO deposition on TiO 2 nanotubes using electrochemical processes. Electrochemical synthesis methods provide an easy, fast, and highly efficient route to carry out the synthesis of nanostructures such as nanowires, nanorods, nanotubes, etc. They allow us to control the stoichiometry, thickness and structure mainly by controlling the voltage, time, temperature, composition of the electrolyte, and concentration of monomers. In addition, a study of the most promising applications for TiO 2 /ZnO hybrid nanostructures has been carried out. In this review, the applications of dye-sensitised solar cell, photoelectrocatalytic degradation of organic compounds, photoelectrochemical water splitting, gas sensors, and lithium-ion batteries have been highlighted.

The increase in biodiesel production has resulted in the oversupply of glycerol into the market. Purified and processed glycerol has found many direct applications in pharmaceuticals, food, etc. However, the cost of processing and market value of processed glycerol has driven the research of direct utilization of crude glycerol to industrially essential chemicals. Various methods and research have been devoted to using glycerol to produce value-added products separately. Glycerol can undergo several transformation reactions like hydrogenation, oxidation, alcoholysis, and etherification. Etherification of glycerol can be divided into three main reactions: self-etherification, using alcohol, and olefins and these products have vast applications such as fuel additives, plasticizer, etc. The current review presents a comprehensive summary of glycerol etherification to value-added products and their applications. The catalytic system developed along with reaction conditions and the factors responsible for the better activity is also discussed. Overall, the review presents a detailed discussion on the catalytic system developed, the utilization of different alcohols and olefins, and the application of products. Moreover, the environmental and economic aspects of the etherification of glycerol via various conversion routes while assessing the process parameters needs to be tackled to attain wider adoption of the process.

Heavy metal ions (HMIs) are known to cause severe damages to the human body and ecological environment. And considering the current alarming situation, it is crucial to develop a rapid, sensitive, robust, economical and convenient method for their detection. Screen printed electrochemical technology contributes greatly to this task, and has achieved global attention. It enabled the mass transmission rate and demonstrated ability to control the chemical nature of the measure media. Besides, the technique offers advantages like linear output, quick response, high selectivity, sensitivity and stability along with low power requirement and high signal-to-noise ratio. Recently, the performance of SPEs has been improved employing the most effective and promising method of the incorporation of different nanomaterials into SPEs. Especially, in electrochemical sensors, the incorporation of nanomaterials has gained extensive attention for HMIs detection as it exhibits outstanding features like broad electrochemical window, large surface area, high conductivity, selectivity and stability. The present review focuses on the recent progress in the field of screen-printed electrochemical sensors for HMIs detection using nanomaterials. Different fabrication methods of SPEs and their utilization for real sample analysis of HMIs using various nanomaterials have been extensively discussed. Additionally, advancement made in this field is also discussed taking help of the recent literature.