The analysis of EXAFS data aimed at extracting information on the local atomic structure of materials is discussed. To identify the structure of interest, one has to solve a system of Fredholm integral equations of the first kind. The situation is considered in which three functions, that characterize the structure under study, are to be determined from one equation. In practice, in this case a nonuniqueness arises in the reconstruction of the unknown functions within a prescribed accuracy, so that additional information has to be used. For a broad range of materials, the functions that are reconstructed possess a rather specific form; namely, these functions appear to be a sum of several narrow peaks that can be approximated by δ functions. This qualitative information about the functions is non-classical. The proposed new analysis procedure is based on the classical theory of ill-posed problems and on using the available non-classical information. The efficiency of the algorithms proposed is illustrated by applying them to model and experimental data of a test compound consisting of uranium, silicon and oxygen, whose structure was previously identified by other authors.
Contents
-
Requires Authentication UnlicensedRegularization methods for the analysis of EXAFS spectra of chemical complexesLicensedJanuary 24, 2008
-
Requires Authentication UnlicensedAn inverse problem for the non-selfadjoint matrix Sturm–Liouville equation on the half-lineLicensedJanuary 24, 2008
-
Requires Authentication UnlicensedIdentification of stress corrosion cracking of SUS samples arising in electromagnetic nondestructive testingLicensedJanuary 24, 2008
-
Requires Authentication UnlicensedTikhonov regularization of nonlinear ill-posed equations under general source conditionLicensedJanuary 24, 2008
-
Requires Authentication UnlicensedOn approximation of inverse problem for abstract parabolic differential equations in Banach spacesLicensedJanuary 24, 2008
-
Requires Authentication UnlicensedTikhonov regularization with nondifferentiable stabilizing functionalsLicensedJanuary 24, 2008