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A New 2D Zinc(II)-Organic Framework with Dinuclear Units Based on Iodinated Terephthalate: Synthesis, Crystal Structure and Luminescence Behavior
-
Kai Cui
,
Xian-Kuan Huo
Veröffentlicht/Copyright:
2. Juni 2014
A new coordination polymer [Zn(BDC-I2)(DMF)]n (1) has been prepared by solvothermal reaction of Zn(II) nitrate with 2,5-diiodo-1,4-benzenedicarboxylic acid (H2BDC-I2) in ethanol-DMF, and characterized by elemental analysis, IR spectroscopy and single-crystal and powder X-ray diffraction techniques. Complex 1 shows a two-dimensional network possessing dinuclear Zn2(CO2)4 secondary building units, which are further assembled into a three-dimensional supramolecular structure through intermolecular C-H···I interactions. Solid-state properties such as photoluminescence and thermal stability of 1 have also been investigated.
Graphical Abstract
A New 2D Zinc(II)-Organic Framework with Dinuclear Units Based on Iodinated Terephthalate: Synthesis, Crystal Structure and Luminescence Behavior
Keywords: Iodinated Terephthalate; Zn(II)-Organic Framework; Solvothermal Synthesis; Crystal Structure; Luminescence
Received: 2014-5-1
Published Online: 2014-6-2
Published in Print: 2014-8-1
© 1946 – 2014: Verlag der Zeitschrift für Naturforschung
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Schlagwörter für diesen Artikel
Iodinated Terephthalate;
Zn(II)-Organic Framework;
Solvothermal Synthesis;
Crystal Structure;
Luminescence
Artikel in diesem Heft
- Synthesis and Characterization of the New Lead Strontium Germanate PbSrGeO4
- A Structural Comparison of Two Thallium Copper Erbium Sulfides: TlCu3Er2S5 and Tl2Cu5Er3S8
- A New 2D Zinc(II)-Organic Framework with Dinuclear Units Based on Iodinated Terephthalate: Synthesis, Crystal Structure and Luminescence Behavior
- Ionothermal Synthesis and Crystal Structure of a Neutral 2D Metal- Organic Framework Based on Cobalt(II) 1,2,3-Benzenetricarboxylate
- A New Wells-Dawson-based Organic-Inorganic Honeycomb Hybrid Compound with Cadmium Bis(2,2´-biimidazole) Spacers
- Anion Effect on the Structural Diversity of 1-D and 2-D Zinc(II) Coordination Polymers with a Flexible Fluorinated Bis(imidazole) Ligand
- Synthesis of Raspberry and Ginger Ketones by Nickel Boride-catalyzed Hydrogenation of 4-Arylbut-3-en-2-ones
- Synthesis of Diazepine-fused Porphyrinoids and Annulated Porphyrin Arrays
- Arylation of 1,2,4-Triazines in the Presence of AlCl3
- Synthesis and Crystal Structures of the P,N-Substituted Ferrocenes [Fe{η5-C5H4–P(S)Ph2}(η5-C5H4–NHCH2tBu)] and [Fe(η5-C5H4– PPh2)(η5-C5H4–NHCH2tBu)]
- Synthesis and Modeling Study of Some Potential Pyrimidine Derivatives as HIV Inhibitors
- Synthesis of Functionalized Diaryldiazenes by Formal [3+3] Cyclizations of 1,3-Bis(silyloxy)-1,3-butadienes with 2-Aryldiazenyl-3-silyloxy-2-en-1- ones
