Effects of Metal Ions and N-Donor Ligands with Different Coordination Characters on the Construction of d10 Metal-organic Complexes with Selective Photocatalytic Activities
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Guo-Cheng Liu
,
Yun Qu
Four new d10 metal-organic coordination polymers, [Zn(L)(phen)(H2O)] (1), [Cd(L)(phen)] (2), [Zn(L)(bppdc)]·3H2O (3), and [Cd(L)(bppdc)]·3H2O (4) [L=2-carboxymethylsulfanyl nicotinic acid, phen=1,10-phenanthroline, bppdc=N;N`-bis(pyridin-3-yl)pyridine-2,6-dicarboxamide], have been obtained from hydrothermal reactions of zinc(II)=cadmium(II) nitrates with the semi-rigid N-= S-containing dicarboxylate L, and the two structurally disparate neutral N-donor ligands phen and bppdc. Single-crystal X-ray diffraction analysis has revealed that compound 1 is a one-dimensional (1- D) helical coordination polymer linked by ZnII atoms and L spacers. Compound 2 features a doublechain structure connected via binuclear CdII units and pairs of L linkers. Adjacent chains of 1 and 2 are packed into 3-D supramolecular networks by hydrogen bonds and p-p stacking interactions. Compounds 3 and 4 exhibit similar 2-D (4,4)-connected wave-like networks based on linear [M-L]n and zigzag [M-bppdc]n metal-organic chains (M=ZnII for 3 and CdII for 4). The effects of metal ions and N-donor ligands with different coordination characters are discussed. Moreover, the photoluminescence properties and photocatalytic activities of compounds 1 - 4 were investigated.
Graphical Abstract
Effects of Metal Ions and N-Donor Ligands with Different Coordination Characters on the Construction of d10 Metal-organic Complexes with Selective Photocatalytic Activities
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Articles in the same Issue
- Synthesis and Crystal Structure of a “High-temperature” Phase of Li[H2NC(O)NH], the Missing Alkali-Metal Ureate
- Strukturen von polaren Magnesiumorganylen: Synthese und Struktur von Basen-Addukten des Bis(pentamethylcyclopentadienyl)magnesiums
- The Mixed-valent Mercury(I/II) Compounds Hg3(HAsO4)2 and Hg6As2O10
- New Intermetallic Zinc Compounds with Ordering Variants of the KHg2 and LT-SrZn5 Type
- Effects of Metal Ions and N-Donor Ligands with Different Coordination Characters on the Construction of d10 Metal-organic Complexes with Selective Photocatalytic Activities
- Synthesis and Characterization of Novel Re(BIAN)(CO)3Cl Derivatives Including the First Example of a Water-soluble Tricarbonyl Rhenium(I) Complex with Bis(imino)acenaphthene Ligands
- Hydrothermal Synthesis and Crystal Structure of a One-dimensional Cobalt (II) Coordination Polymer with Two Organic Ligands
- Vinylsilylferrocenes and Ethynyl(vinyl)silylferrocenes. Synthesis, Multinuclear Magnetic Resonance Study and DFT Calculations
- One-pot Multi-component Synthesis of Mono- and Bis-indolylimidazole Derivatives Using Zn2+@KSF and Their Antibacterial Activity
- Catalyst-free, Solvent-promoted and Scalable Multicomponent Synthesis of 3-Aminoalkylated Indoles via a Mannich-type Reaction
- Synthesis and Reactions of New Chiral Linear Dipeptide Candidates Using Nalidixic Acid as Starting Material
- Synthesis and Characterization of Ammonium Acesulfamate
- Two Rare Hydroazulene-type Sesquiterpenes from the Roots of Aristolochia yunnanensis
- Spiroalkaloids and Coumarins from the Stem Bark of Pauridiantha callicarpoides
