Synthesis and Characterization of Novel Re(BIAN)(CO)3Cl Derivatives Including the First Example of a Water-soluble Tricarbonyl Rhenium(I) Complex with Bis(imino)acenaphthene Ligands
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Elham Kianfar
A series of rhenium(I) carbonyl chloride complexes carrying bis(imino)acenaphthene (BIAN) molecules as p-acceptor ligands was prepared and characterized by various spectroscopic techniques. Among the novel compounds described, the remarkable example of a deeply colored water-soluble rhenium carbonyl derivative is presented. The crystal structures of this family of BIAN compounds are also reported, which confirm the position of the chloro ligand at the tricarbonyl rhenium(I) center. In the case of BIAN ligands carrying bulky substituents in the ortho-position of the arylimino subunits, evidence has been found for an exchange of the halide ligand in solution, which is considered to be of major relevance for catalytic applications. Implications of our results for the fields of photocatalytic CO2 reduction and the controlled release of the gasotransmitter CO in aqueous solution are briefly discussed.
Graphical Abstract
Synthesis and Characterization of Novel Re(BIAN)(CO)3Cl Derivatives Including the First Example of a Water-soluble Tricarbonyl Rhenium(I) Complex with Bis(imino)acenaphthene Ligands
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Articles in the same Issue
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- Strukturen von polaren Magnesiumorganylen: Synthese und Struktur von Basen-Addukten des Bis(pentamethylcyclopentadienyl)magnesiums
- The Mixed-valent Mercury(I/II) Compounds Hg3(HAsO4)2 and Hg6As2O10
- New Intermetallic Zinc Compounds with Ordering Variants of the KHg2 and LT-SrZn5 Type
- Effects of Metal Ions and N-Donor Ligands with Different Coordination Characters on the Construction of d10 Metal-organic Complexes with Selective Photocatalytic Activities
- Synthesis and Characterization of Novel Re(BIAN)(CO)3Cl Derivatives Including the First Example of a Water-soluble Tricarbonyl Rhenium(I) Complex with Bis(imino)acenaphthene Ligands
- Hydrothermal Synthesis and Crystal Structure of a One-dimensional Cobalt (II) Coordination Polymer with Two Organic Ligands
- Vinylsilylferrocenes and Ethynyl(vinyl)silylferrocenes. Synthesis, Multinuclear Magnetic Resonance Study and DFT Calculations
- One-pot Multi-component Synthesis of Mono- and Bis-indolylimidazole Derivatives Using Zn2+@KSF and Their Antibacterial Activity
- Catalyst-free, Solvent-promoted and Scalable Multicomponent Synthesis of 3-Aminoalkylated Indoles via a Mannich-type Reaction
- Synthesis and Reactions of New Chiral Linear Dipeptide Candidates Using Nalidixic Acid as Starting Material
- Synthesis and Characterization of Ammonium Acesulfamate
- Two Rare Hydroazulene-type Sesquiterpenes from the Roots of Aristolochia yunnanensis
- Spiroalkaloids and Coumarins from the Stem Bark of Pauridiantha callicarpoides
Articles in the same Issue
- Synthesis and Crystal Structure of a “High-temperature” Phase of Li[H2NC(O)NH], the Missing Alkali-Metal Ureate
- Strukturen von polaren Magnesiumorganylen: Synthese und Struktur von Basen-Addukten des Bis(pentamethylcyclopentadienyl)magnesiums
- The Mixed-valent Mercury(I/II) Compounds Hg3(HAsO4)2 and Hg6As2O10
- New Intermetallic Zinc Compounds with Ordering Variants of the KHg2 and LT-SrZn5 Type
- Effects of Metal Ions and N-Donor Ligands with Different Coordination Characters on the Construction of d10 Metal-organic Complexes with Selective Photocatalytic Activities
- Synthesis and Characterization of Novel Re(BIAN)(CO)3Cl Derivatives Including the First Example of a Water-soluble Tricarbonyl Rhenium(I) Complex with Bis(imino)acenaphthene Ligands
- Hydrothermal Synthesis and Crystal Structure of a One-dimensional Cobalt (II) Coordination Polymer with Two Organic Ligands
- Vinylsilylferrocenes and Ethynyl(vinyl)silylferrocenes. Synthesis, Multinuclear Magnetic Resonance Study and DFT Calculations
- One-pot Multi-component Synthesis of Mono- and Bis-indolylimidazole Derivatives Using Zn2+@KSF and Their Antibacterial Activity
- Catalyst-free, Solvent-promoted and Scalable Multicomponent Synthesis of 3-Aminoalkylated Indoles via a Mannich-type Reaction
- Synthesis and Reactions of New Chiral Linear Dipeptide Candidates Using Nalidixic Acid as Starting Material
- Synthesis and Characterization of Ammonium Acesulfamate
- Two Rare Hydroazulene-type Sesquiterpenes from the Roots of Aristolochia yunnanensis
- Spiroalkaloids and Coumarins from the Stem Bark of Pauridiantha callicarpoides
