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Ferroic materials and anomalous strains

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Published/Copyright: January 27, 2022
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Abstract

Ferroics are materials which become ferroelastic, ferromagnetic, or ferroelectric at lower temperatures on cooling. They usually show a phase transformation which produces an ordered state (low-entropy phase). Their properties are partially due to a domain structure. The strain effects are found either by cycling around the transformation temperature (two-way effect, invar), by mechanical straining plus heating above the transformation temperature (one-way memory) or by cyclic mechanical loading (pseudo- or rubber-elasticity).

Ferromagnetic or ferroelectric materials can be shaped by magnetic or electrical fields instead of mechanical stresses. In combination with a martensitic transformation, considerable strains are obtained in some ferromagnetic alloys, such as Ni2MnGa and other multiferroics.

Polymers can show one-way behaviour like metals, and ferro- and piezo-electrical behaviour like ceramics. The largest amounts of reversible strains are obtained with polymers, the smallest with ceramics. Porous charged polymers show hysteresis curves like ceramic ferroelectrics, but larger amounts of strain: ferro-electrets.

A systematic understanding of this group of materials permits to compare their abilities and limits. This, in turn, provides a basis for the selection of the best material for a certain application.


Prof. em. Dr.-Ing. Dr. h. c. Erhard Hornbogen Ruhr-Universität Bochum Lehrstuhl Werkstoffwissenschaft Institut für Werkstoffe Fakultät für Maschinenbau, Gebäude IA 1/126 44780 Bochum, Germany Tel.: +49 2 34 32 2 30 22 Fax: +49 2 34 32 1 42 35

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Received: 2004-08-02
Accepted: 2005-01-26
Published Online: 2022-01-27

© 2005 Carl Hanser Verlag, München

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