Decomposition of the Interstitial Solid Solution Pd(B)
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Markus Beck
Abstract
The decomposition at 628 K of a Pd(B) solid solution containing 6 at.% boron was analyzed by use of, primarily, X-ray diffraction. A structure model was used to simulate the X-ray diffraction-line profiles. The decomposition is described as the precipitation of a boron-poor face-centered cubic (fcc) phase in the parent fcc phase gradually enriching in boron. The experimentally determined width of the miscibility gap is different from previous experimental results, but agrees with theoretical data obtained on the basis of the quasi-chemical approximation. Further, the micro-strain in the decomposed state was measured and compared with that of the initial, quenched supersaturated solid solution; good agreement is observed between results obtained from X-ray diffractometry and transmission electron microscopy.
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PV(2θ) = I0[L(2θ)2 + G(2θ)] with Lorentzian component L(2θ) = η/[1 + CL(2θ – 2θ0)2], where
References
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© 2001 Carl Hanser Verlag, München
Artikel in diesem Heft
- Frontmatter
- Preisverleihung
- Werner-Köster-Preis 2000
- Aufsätze/Articles
- Decomposition of the Interstitial Solid Solution Pd(B)
- Texture Development in Al–Mg Alloys During High Temperature Annealing
- A Method for Determining the Weld Pool after Laser Beam Welding
- Composition–Pressure–Temperature Phase Diagram of the Silver–Germanium System
- Theoretical Study of P-Containing Transformation-Induced Plasticity Steel – Part 1: Determination of the Phosphorus Concentration
- Theoretical Study of P-Containing Transformation-Induced Plasticity Steel – Part 2: Analysis of the Potential TRIP Effect
- Influence of Microstructure on the Low and High Cycle Fatigue Behaviour of a Medium Carbon Microalloyed Steel
- Temperature Dependence of the Viscosity of Al–Sr Alloy Melts
- Preparation of an Al–Sr Master Alloy by Molten Salts Electrolysis
- Phase Decomposition of Cast Alloy ZnAl11Cu3
- Crystallographic Investigations on the Serrated Grain Boundaries in an AISI 316 Stainless Steel
- Bruch der Antriebswelle eines Sessellifts
- Mitteilungen/Notifications
- Personen
- Bücher/Books
- Tagungen/Conferences
Artikel in diesem Heft
- Frontmatter
- Preisverleihung
- Werner-Köster-Preis 2000
- Aufsätze/Articles
- Decomposition of the Interstitial Solid Solution Pd(B)
- Texture Development in Al–Mg Alloys During High Temperature Annealing
- A Method for Determining the Weld Pool after Laser Beam Welding
- Composition–Pressure–Temperature Phase Diagram of the Silver–Germanium System
- Theoretical Study of P-Containing Transformation-Induced Plasticity Steel – Part 1: Determination of the Phosphorus Concentration
- Theoretical Study of P-Containing Transformation-Induced Plasticity Steel – Part 2: Analysis of the Potential TRIP Effect
- Influence of Microstructure on the Low and High Cycle Fatigue Behaviour of a Medium Carbon Microalloyed Steel
- Temperature Dependence of the Viscosity of Al–Sr Alloy Melts
- Preparation of an Al–Sr Master Alloy by Molten Salts Electrolysis
- Phase Decomposition of Cast Alloy ZnAl11Cu3
- Crystallographic Investigations on the Serrated Grain Boundaries in an AISI 316 Stainless Steel
- Bruch der Antriebswelle eines Sessellifts
- Mitteilungen/Notifications
- Personen
- Bücher/Books
- Tagungen/Conferences
