Thermodynamic Assessment of the Nb–W–C System
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Weiming Huang
Abstract
The phase equilibrium and thermodynamic information of the Nb–W–C system was reviewed and assessed by using thermodynamic models for the Gibbs energy of individual phases. The assessment was based on the recent evaluations of the W–C, Nb–W and Nb–C, which was revised in the present work taking ternary information into account. The model parameters were evaluated by fitting the selected experimental data by means of a computer program. A consistent set of parameters was obtained, which satisfactorily describes most of the experimental information.
Literature
1 Kaufman, L.; Bernstein, H.: Computer Calculation of Phase Diagrams, Academic Press, New York (1970).Search in Google Scholar
2 Gustafson, P.: Mater. Sci. Techn. 2 (1986) 653 – 658.10.1179/mst.1986.2.7.653Search in Google Scholar
3 Fernândez-Guillermet, A.; Huang, W.: unpublished work.Search in Google Scholar
4 Huang, W.: Mater. Sci. Techn. 6 (1990) 687 – 694.10.1179/mst.1990.6.8.687Search in Google Scholar
5 Rudy, E.: Technical Report AFML-TR-65-2, Part II, Vol. XVIII, Jan. 1969, Air Force Materials Laboratory, Ohio.Search in Google Scholar
6 Gustafson, P.: Carbon 24 (1986) 169 – 176.10.1016/0008-6223(86)90113-2Search in Google Scholar
7 Dinsdale, A.: CALPHAD 15 (1991) 317 – 425.10.1016/0364-5916(91)90030-NSearch in Google Scholar
8 Gustafson, P.: Int. J. Thermophysics 6 (1985) 395 – 409.10.1007/BF00500270Search in Google Scholar
9 Redlich, O.; Kister, A.T.: Ind. Engn. Chem. 40 (1948) 345 – 348.10.1021/ie50458a036Search in Google Scholar
10 Hillert, M.; Staffansson, L.-I.: Acta Chem. Scand. 24 (1970) 3618 – 3626.10.3891/acta.chem.scand.24-3618Search in Google Scholar
11 Andersson, J.-O.; Fernândez-Guillermet, A.; Hillert, M.; Jansson, B.; Sundman, B.: Acta Metall. 34 (1986) 437 – 445.10.1016/0001-6160(86)90079-9Search in Google Scholar
12 Storms, E.K.; Calkin, B.; Yencha, A.: High Temp. Sci. 1 (1969) 430 – 455.Search in Google Scholar
13 Brizes, W.F.; Brody, H.D.: J. Am. Ceram. Soc. 55 (1972) 277 – 278.10.1111/j.1151-2916.1972.tb11282.xSearch in Google Scholar
14 Rudy, E.; Windisch, St.; Brukl, C.E.: Planseeber. Pulvermetall. 16 (1968) 3 – 33.Search in Google Scholar
15 Storms, E. K.; Krikorian, N.: J. Phys. Chem. 64 (1960) 1471 – 1477.10.1021/j100839a029Search in Google Scholar
16 Kimura, H.; Sasaki, Y.: Trans. Jpn. Inst. Met. 2 (1961) 98 – 104.10.2320/matertrans1960.2.98Search in Google Scholar
17 Nikol’skaya, T.A.; Avarbe, R.G.; Vil’K, Yu.N.: Zh. Fiz. Khim. 42 (1968) 637 – 640.Search in Google Scholar
18 Hong, Y.R.; Kumar, R.V.; Balasubramanian, K.; Kay, D.R.A.:“Some Thermodynamic Properties of NbCy”, Dept. Materials Sci. and Eng., McMaster University, Hamilton, ON (1989).Search in Google Scholar
19 Balasubramanian, K.: PhD Thesis, “Thermodynamics of Microalloyed Austenites and Monostoichiometric Carbides”, McMaster University, Hamilton, ON (1988).Search in Google Scholar
20 Jansson, B.: Trita-Mac 234, The Royal Institute of Technology, Stockholm, Sweden (1984).Search in Google Scholar
21 Huang, W.: Z. Metallkd. 81 (1990) 397 – 404.Search in Google Scholar
22 Jonsson, S.: PhD Thesis, “Phase Relations in Quaternary Hard Materials”, The Royal Institute of Technology, Stockholm, Sweden (1993).Search in Google Scholar
23 Fernândez-Guillermet, A.: PhD Thesis, “Thermodynamics of the Co–Fe–Ni–W–C System”, The Royal Institute of Technology, Stockholm, Sweden (1988).Search in Google Scholar
24 Sundman, B.; Jansson, B.; Andersson, J.-O.: CALPHAD 9 (1985) 153 – 190.10.1016/0364-5916(85)90021-5Search in Google Scholar
© 1997 Carl Hanser Verlag München
Articles in the same Issue
- Frontmatter
- Editorial
- Editorial
- Aufsätze
- Systematical Calculation of the Chemical Driving Force for Precipitation Reactions in Binary Alloys
- Thermodynamic and Kinetic Study of Diffusion Paths in the System Cu–Ag –Zn
- Multi-Step Hot Working of Al-5 wt.% Mg
- Young’s Modulus of Cast-Iron as a Function of Volume Content, Shape and Orientation of Graphite Inclusions
- Die Charakterisierung homogener polyedrischer Gefüge mit Hilfe des räumlichen Poisson-Voronoi-Mosaiks und der Vergleich zur DIN 50 601
- A Quasicrystal with Inflation Symmetry and no Forbidden Symmetry Axes in a Rapidly Solidified Mg–Al Alloy
- Internal Oxidation of Rapidly Solidified Cu–Zr Alloys
- Phase Diagram Investigation and Thermodynamic Evaluation of the Thallium–Tellurium System
- Thermodynamic Assessment of the Nb–W–C System
- Thermodynamic Properties of the Nb–W–C–N System
- Thermodynamic Properties of NiAs-Type Fe1+xSb
- Thermodynamic Properties of Alloys of Phosphorus with Calcium, Barium, Chromium, Manganese and Iron
- Phase Equilibria in the γ′-Rich Region of the Ni –Al –Hf System
- Phase Equilibria in the γ′-Rich Region of the Boron-doped Ni –Al –Hf System
- Instructions for Authors
- Zeitschrift für metallkunde
- Mitteilungen der Deutschen Gesellschaft für Materialkunde e.V
- Personen
- Bericht aus dem DGM-Fachausschuß Strangpressen
- Fortbildung
Articles in the same Issue
- Frontmatter
- Editorial
- Editorial
- Aufsätze
- Systematical Calculation of the Chemical Driving Force for Precipitation Reactions in Binary Alloys
- Thermodynamic and Kinetic Study of Diffusion Paths in the System Cu–Ag –Zn
- Multi-Step Hot Working of Al-5 wt.% Mg
- Young’s Modulus of Cast-Iron as a Function of Volume Content, Shape and Orientation of Graphite Inclusions
- Die Charakterisierung homogener polyedrischer Gefüge mit Hilfe des räumlichen Poisson-Voronoi-Mosaiks und der Vergleich zur DIN 50 601
- A Quasicrystal with Inflation Symmetry and no Forbidden Symmetry Axes in a Rapidly Solidified Mg–Al Alloy
- Internal Oxidation of Rapidly Solidified Cu–Zr Alloys
- Phase Diagram Investigation and Thermodynamic Evaluation of the Thallium–Tellurium System
- Thermodynamic Assessment of the Nb–W–C System
- Thermodynamic Properties of the Nb–W–C–N System
- Thermodynamic Properties of NiAs-Type Fe1+xSb
- Thermodynamic Properties of Alloys of Phosphorus with Calcium, Barium, Chromium, Manganese and Iron
- Phase Equilibria in the γ′-Rich Region of the Ni –Al –Hf System
- Phase Equilibria in the γ′-Rich Region of the Boron-doped Ni –Al –Hf System
- Instructions for Authors
- Zeitschrift für metallkunde
- Mitteilungen der Deutschen Gesellschaft für Materialkunde e.V
- Personen
- Bericht aus dem DGM-Fachausschuß Strangpressen
- Fortbildung