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Reactive Blending in a Twin Screw Extruder
Experimental and Theoretical Approaches
-
A. De Loor
Published/Copyright:
May 28, 2013
Abstract
We studied the morphology of a reactive blend, constituted by an EVA/EMA phase dispersed in a polypropylene matrix. The dispersed phase was crosslinked in-situ during the extrusion through a transesterification reaction, catalysed by dibutyltin oxide. Rheological studies allowed to define the changes in rheological behaviour during the crosslinking reaction. Using a flow model developed for twin screw extruders, we computed the reaction extent along the screws and the corresponding blend morphology using a very simple approach. Theoretical results underestimate the extent of the reaction, but explain qualitatively the general tendencies when varying operating parameters.
Received: 1995-7-18
Accepted: 1995-11-3
Published Online: 2013-05-28
Published in Print: 1996-05-01
© 1996, Carl Hanser Verlag, Munich
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Articles in the same Issue
- Contents
- Contents
- Editorial
- Eighteenth in a Series: Toshiba Machine
- Screw Extrusion
- Theoretical and Experimental Investigations of the Melting of Pellets in Co-Rotating Twin-Screw Extruders
- An Improved Flow Simulation Model for a Tangential Counter-Rotating Twin Screw Extruder
- Modeling and Experimental Study of the Flow in a Simplified Cavity Transfer Mixer
- An Analytical Model of the Conveying Behaviour of Closely Intermeshing Co-rotating Twin Screw Extruders
- Reactive Processing
- Simulation of Continuous Polymerization in a Modular Intermeshing Co-rotating Twin Screw Extruder
- Reactive Blending in a Twin Screw Extruder
- Die Extrusion
- Viscoelastic Simulations of Stratified Bicomponent Extrusion through Slit Dies
- Fibers
- Spinnability of Polymer Melts – a Complex Problem in Basic Research1)
- Molding
- Structure and Properties of Inflation Films of β-Phase Nucleating Agent-Added Polypropylene
- Inverse Modeling of Injection Molding Thermal Stresses to Optimize Temperature and Pressure History
- An Assessment of Thermal Stresses in Injection Moulded ABS Copolymer
- Rapid Communications
- Experimental Study on the Injection Compression Molding of Parts with Precision Contours
Articles in the same Issue
- Contents
- Contents
- Editorial
- Eighteenth in a Series: Toshiba Machine
- Screw Extrusion
- Theoretical and Experimental Investigations of the Melting of Pellets in Co-Rotating Twin-Screw Extruders
- An Improved Flow Simulation Model for a Tangential Counter-Rotating Twin Screw Extruder
- Modeling and Experimental Study of the Flow in a Simplified Cavity Transfer Mixer
- An Analytical Model of the Conveying Behaviour of Closely Intermeshing Co-rotating Twin Screw Extruders
- Reactive Processing
- Simulation of Continuous Polymerization in a Modular Intermeshing Co-rotating Twin Screw Extruder
- Reactive Blending in a Twin Screw Extruder
- Die Extrusion
- Viscoelastic Simulations of Stratified Bicomponent Extrusion through Slit Dies
- Fibers
- Spinnability of Polymer Melts – a Complex Problem in Basic Research1)
- Molding
- Structure and Properties of Inflation Films of β-Phase Nucleating Agent-Added Polypropylene
- Inverse Modeling of Injection Molding Thermal Stresses to Optimize Temperature and Pressure History
- An Assessment of Thermal Stresses in Injection Moulded ABS Copolymer
- Rapid Communications
- Experimental Study on the Injection Compression Molding of Parts with Precision Contours
