High-speed Melt Spinning of PET
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T. Kikutani
Abstract
The high-speed spinning process of poly(ethylene terephthalate) (PET) was modified by introducing a liquid isothermal bath (LIB) which was kept at a temperature of 155°C and placed at a distance of 150 cm or 200 cm below the spinneret. The structure and mechanical properties of the as-spun fibers thus produced in the take-up speed range of 1 to 7 km/min were characterized. The results showed that the introduction of the LIB significantly influences the structural development of the as-spun fibers. The fibers produced using the LIB in the spinline showed significantly higher birefringence and crystallinity compared to the fibers produced using a standard high-speed spinning process. A semi-quantitative numerical simulation was performed with the incorporation of the LIB in the spinline to understand the mechanism of fiber structure formation during the modified high-speed spinning process of PET. The results showed that the solidification stress is considerably high when the solidification was assumed to occur at a position close to the exit of the LIB. The enhancement of molecular orientation was attributed to the increased frictional stress induced by the liquid layer whereas the spinline crystallization was found to be influenced strongly by the temperature of the liquid.
© 1996, Carl Hanser Verlag, Munich
Artikel in diesem Heft
- Contents
- Contents
- Editorial
- Seventeenth in a Series: Reifenhäuser – From Blacksmiths to Master Integrated Screw Extrusion System Manufacturers
- Invited Paper
- 35 Years of Studies of Mixing of Rubber and Viscoelasticity
- Mixing
- Melt Strength and Elastic Behaviour of LLDPE/LDPE Blends
- Screw Extrusion
- Melting and Blending in a Modular Co-Rotating/Counter-Rotating Twin Screw Extruder
- A Physico-Mathematical Model for Solids Conveying in Co-Rotating Twin Screw Extruders
- Fibers and Films
- High-speed Melt Spinning of PET
- Die Extrusion
- Evaluation of the FAN Technique for Profile Die Design
- Molding
- Analysis of the Mold Filling Process with Phase Change Considering the Non-steady Effect
- Analysis of the Local Volume Flow Rate of Polymers During Injection Molding
- Surface Defect Formation in the Injection Molding of Acrylonitrile-Styrene-Acrylate Polymers
- Injection Molding of Microcomposites Based on Polypropylene and Thermotropic Liquid Crystalline Polymers
Artikel in diesem Heft
- Contents
- Contents
- Editorial
- Seventeenth in a Series: Reifenhäuser – From Blacksmiths to Master Integrated Screw Extrusion System Manufacturers
- Invited Paper
- 35 Years of Studies of Mixing of Rubber and Viscoelasticity
- Mixing
- Melt Strength and Elastic Behaviour of LLDPE/LDPE Blends
- Screw Extrusion
- Melting and Blending in a Modular Co-Rotating/Counter-Rotating Twin Screw Extruder
- A Physico-Mathematical Model for Solids Conveying in Co-Rotating Twin Screw Extruders
- Fibers and Films
- High-speed Melt Spinning of PET
- Die Extrusion
- Evaluation of the FAN Technique for Profile Die Design
- Molding
- Analysis of the Mold Filling Process with Phase Change Considering the Non-steady Effect
- Analysis of the Local Volume Flow Rate of Polymers During Injection Molding
- Surface Defect Formation in the Injection Molding of Acrylonitrile-Styrene-Acrylate Polymers
- Injection Molding of Microcomposites Based on Polypropylene and Thermotropic Liquid Crystalline Polymers
