Melt-recrystallization of Talc-filled Polypropylene Injection Moldings
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M. Fujiyama
Abstract
Talc-filled polypropylene injection moldings show a peculiar crystal orientation, in which the plate planes of talc particles are aligned parallel to the molding surface, the c- and a*- axes of polypropylene crystals are bimodally oriented to the flow direction, and the b-axes are oriented to the thickness direction. If they are melt-recrystallized, although the orientation of talc and the b-axis orientation of polypropylene crystals are restored, the c- and a*-axes become unoriented in a plane parallel to the molding surface. This peculiar crystal orientation cannot be explained by any effect of an epitaxy caused by lattice matching between the cleavage plane of talc and (040) plane of polypropylene crystal, a crystallization nucleation effect, a concentration of stress or melt orientation, or their synergisms. From the facts that, even if talc-filled polypropylene injection moldings are melt-recrystallized, the b-axis orientation to the thickness direction is restored and that an injection molding of polypropylene filled with only 0.5 wt.-% talc already shows the peculiar crystal orientation, it is assumed that talc influences a remote interaction on the crystallization of polypropylene so that the (040) planes of polypropylene crystals pile on or the b-axes are oriented perpendicular to the plate planes of talc particles.
© 1992, Carl Hanser Verlag, Munich
Artikel in diesem Heft
- Contents
- Contents
- Continuous Mixing and Compounds
- Starve-fed Flow in Co-Rotating Twin Screw Extruders
- Process for Improvement in Toughness of Unsaturated Polyester with Elastomer
- Mechanical Properties of Thermoplastic Polyurethane Blends and Copolymers of Styrene and Acrylonitrile
- Extrusion
- Mixing on Melting in Single Screw Extrusion
- Numerical Study of Slip at the Walls in the Extruder
- Elimination of Sag in Plastic Pipe Extrusion
- Fibers and Film
- Issues Concerning the Rate of Heat Transfer from a Spinline
- Skew Stretched Polycarbonate Films
- Molding
- Molecular Orientation in Injection-Molded Polypropylene Copolymers with Ethylene
- Melt-recrystallization of Talc-filled Polypropylene Injection Moldings
- Processing Characteristics of Thermoplastic Sheet Composites
- Rapid Communication of Recent Advances
- The Face-relief Strategy for Design of Profile Dies
Artikel in diesem Heft
- Contents
- Contents
- Continuous Mixing and Compounds
- Starve-fed Flow in Co-Rotating Twin Screw Extruders
- Process for Improvement in Toughness of Unsaturated Polyester with Elastomer
- Mechanical Properties of Thermoplastic Polyurethane Blends and Copolymers of Styrene and Acrylonitrile
- Extrusion
- Mixing on Melting in Single Screw Extrusion
- Numerical Study of Slip at the Walls in the Extruder
- Elimination of Sag in Plastic Pipe Extrusion
- Fibers and Film
- Issues Concerning the Rate of Heat Transfer from a Spinline
- Skew Stretched Polycarbonate Films
- Molding
- Molecular Orientation in Injection-Molded Polypropylene Copolymers with Ethylene
- Melt-recrystallization of Talc-filled Polypropylene Injection Moldings
- Processing Characteristics of Thermoplastic Sheet Composites
- Rapid Communication of Recent Advances
- The Face-relief Strategy for Design of Profile Dies
