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Skew Stretched Polycarbonate Films

  • J. P. Wu und J. L. White
Veröffentlicht/Copyright: 27. Mai 2013
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Abstract

The formation and characterization of complex chain orientation of polycarbonate skew stretched films is described. The directions of symmetry axes of orientation are represented in the form of refractive index and infrared absorption ellipsoids. The chain orientation is evaluated in terms of White-Spruiell biaxial orientation factors based on the principal axes of orientation. The anisotropic mechanical properties of skew stretched films are correlated with their orientation states. The major symmetry axes of skew stretched polycarbonate films tend to move toward the second stretching direction as increasing second stretching ratio. The chain orientation behavior of these films exhibit increasing uniaxial orientation character at high second stretching ratio. The anisotropic characters of tensile modulus and yield stress of skew stretched films follow a linear relation with the magnitude of chain orientation within our stretching range.


** Mail address: Prof. Dr. James L. White, Institute of Polymer Engineering, University of Akron, Akron, Ohio 44325-0301, U.S.A.

Received: 1991-2
Accepted: 1991-4
Published Online: 2013-05-27
Published in Print: 1992-05-01

© 1992, Carl Hanser Verlag, Munich

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