Swelling Properties and Environmental Responsiveness of a Superabsorbent Composite Microsphere Based on Starch-g-Poly(acrylic acid)/Organo-Mordenite
-
P.-Q. Gao
, Y. Zhang , L. Zhao and Y.-Z. Chen
Abstract
Starch-g-poly(acrylic acid)/organo-mordenite superabsorbent composite microsphere, was prepared by grafting partially neutralized acrylic acid onto starch in the presence of organo-mordenite as an inorganic component. The morphology was characterized with scanning electron microscope (SEM). The swelling properties of the superabsorbent composite microsphere were evaluated in distilled water, various NaCl solutions, solutions with different pH values, and urea solutions. Swelling kinetics of the superabsorbent composite microsphere in above environments were discussed by means of a Schott's second-order model. The results showed that the incorporation of 10 wt% organo-mordenite enhanced the water absorbency by 144% (from 268 to 655 g · g−1) and possessed the maximum swelling absorbency (75 g · g−1) in the 0.9% NaCl solution and (667 g · g−1) in 0.04 mol · l−1 urea solution. Moreover, swelling of starch-g-poly(acrylic acid)/organo-mordenite (with 10 wt% organo-mordenite) in distilled water and in all other environments followed Schott's second order kinetics. Swelling was extremely environmental-responsive to the concentration of the NaCl solution, the pH values, and urea solutions, respectively. The overall results inferred that the novel superabsorbent composite can be exploited for many potential applications.
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Articles in the same Issue
- Contents
- Contents
- Regular Contributed Articles
- Swelling Properties and Environmental Responsiveness of a Superabsorbent Composite Microsphere Based on Starch-g-Poly(acrylic acid)/Organo-Mordenite
- Study on Permeability of Porous Ultra-High Molecular Weight Polyethylene (UHMWPE)
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- Devulcanization of Scrap Tire Rubber with Supercritical CO2: A Study of the Effects of Process Parameters on the Properties of Devulcanized Rubber
- Forming of Thermoplastic Matrix Composites with Gas Pressure – the Influence of Blank Holder and Sheet Temperature on the Forming Pressure and Drawing Ratio
- Time Dependence of Morphology and Mechanical Properties of Injection Molded Recycled PET
- A Generalized 2D Output Model of Polymer Melt Flow in Single-Screw Extrusion
- Flow Behavior of PP-Polymer Nanocomposites in Capillary and Injection Molding Dies
- A Recollection with Respect to Flow Induced Crystallization in Polymer Melt Processing
- Optical Properties of HDPE in Injection Molding and Injection Press Molding for IR System Lenses Part II: Mold Temperature and Surface Roughness Effects on Injection Molding
- Modeling Temperature and Time Dependence of the Wetting of Tool Steel Surfaces by Polymer Melts
- Modification Induced by Gamma Irradiation in Polystyrene/Poly(methyl methacrylate) Blends
- Rapid Communications
- Study on the Influence of Extrusion Temperature and Extrusion Die on the Properties of Self-Reinforced PP Sheets
- PPS News
- PPS News
- Seikei Kakou Abstracts
- Seikei-Kakou Abstracts
Articles in the same Issue
- Contents
- Contents
- Regular Contributed Articles
- Swelling Properties and Environmental Responsiveness of a Superabsorbent Composite Microsphere Based on Starch-g-Poly(acrylic acid)/Organo-Mordenite
- Study on Permeability of Porous Ultra-High Molecular Weight Polyethylene (UHMWPE)
- Precise Fabrication of Fresnel Flash Lens Featured with V-Grooved Microstructures
- Ion Etching Induced Surface Patterns of Blend Polymer (Poly Ethylene Glycol – Poly Methyl Methacrylate) Irradiated with Gamma Rays
- Devulcanization of Scrap Tire Rubber with Supercritical CO2: A Study of the Effects of Process Parameters on the Properties of Devulcanized Rubber
- Forming of Thermoplastic Matrix Composites with Gas Pressure – the Influence of Blank Holder and Sheet Temperature on the Forming Pressure and Drawing Ratio
- Time Dependence of Morphology and Mechanical Properties of Injection Molded Recycled PET
- A Generalized 2D Output Model of Polymer Melt Flow in Single-Screw Extrusion
- Flow Behavior of PP-Polymer Nanocomposites in Capillary and Injection Molding Dies
- A Recollection with Respect to Flow Induced Crystallization in Polymer Melt Processing
- Optical Properties of HDPE in Injection Molding and Injection Press Molding for IR System Lenses Part II: Mold Temperature and Surface Roughness Effects on Injection Molding
- Modeling Temperature and Time Dependence of the Wetting of Tool Steel Surfaces by Polymer Melts
- Modification Induced by Gamma Irradiation in Polystyrene/Poly(methyl methacrylate) Blends
- Rapid Communications
- Study on the Influence of Extrusion Temperature and Extrusion Die on the Properties of Self-Reinforced PP Sheets
- PPS News
- PPS News
- Seikei Kakou Abstracts
- Seikei-Kakou Abstracts