Melt Creep Recovery of Polyamide 6 and Polypropylene Nanocomposites Blended with Layered Silicate
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G.-G. Lin
Abstract
Nanocomposites of polyamide six (PA6) reinforced with organoclay were prepared in this study through melt mixing. The blended montmorillonite clay was organically modified with octadecylamine. The loadings of the clay were 1 wt%, 5 wt%, and 9 wt%. The obtained nanocomposites exhibited exfoliation (1 wt%) and intercalation (other compositions) structures. By contrast, if they were mixed with unmodified clay, the PA6 molecules could not enter the silicate interlayer. For polypropylene (PP), forming nanocomposites with organoclay was difficult but made feasible by incorporating the maleated PP. The results of dynamic rheological tests demonstrated that an end-tethered storage modulus was observed for the PA6/organoclay nanocomposites. However, the PP/organoclay exhibited terminal-zone behavior. In addition, the shear creep recovery was conducted on the molten polymer composites. The results indicated that the molten PA6/organoclay nanocomposite exhibited a higher creep-recovery ratio, a measure of the elastic property, than that of pristine PA6. The time constant in the Voigt-Kelvin constitutive model for the PA6/organoclay melts was lower than that of the pristine PA6 due to the superior elastic moduli, because it is defined as the ratio of viscosity to the modulus. However, the recovery ratios for most of the PP nanocomposites were found to be less than that for the pristine PP, indicating the fair reinforcing effect of the organoclay.
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© 2016, Carl Hanser Verlag, Munich
Articles in the same Issue
- Contents
- Contents
- Regular Contributed Articles
- Influence of Melt-Mixing Process Conditions on Mechanical Performance of Organoclay/Fluoroelastomer Nanocomposites
- Melt Creep Recovery of Polyamide 6 and Polypropylene Nanocomposites Blended with Layered Silicate
- Dielectric Behavior of OPEFB Reinforced Polycaprolactone Composites at X-Band Frequency
- Numerical Modeling of Bubble Growth in Microcellular Polypropylene Produced in a Core-Back Injection Process Using Chemical Blowing Agents
- Numerical Simulation and Experimental Validation of Granite Powder Filled Jute Epoxy Composite for Slurry Jet Erosive Wear
- Rheological Modeling of Polymeric Melts in Extruders upon Two-Dimensional Shear Flow
- Experimental Investigation on Curing Stress in Polymer Composite Using Digital Gradient Sensing Technique
- Experimental and Numerical Investigation of Shrinkage and Warpage of a U-Shaped Injection Molded Part
- Modeling for Starve Fed/Flood Fed Mixing Single-Screw Extruders
- The Comparative Study of Different Mixing Methods for Microcrystalline Cellulose/Polyethylene Composites
- Fabrication of Superhydrophobic Polyethylene Parts by Rotomolding
- Numerical Simulation of Chaotic Mixing in Single Screw Extruders with Different Baffle Heights
- PPS News
- PPS News
- Seikei Kakou Abstracts
- Seikei-Kakou Abstracts
Articles in the same Issue
- Contents
- Contents
- Regular Contributed Articles
- Influence of Melt-Mixing Process Conditions on Mechanical Performance of Organoclay/Fluoroelastomer Nanocomposites
- Melt Creep Recovery of Polyamide 6 and Polypropylene Nanocomposites Blended with Layered Silicate
- Dielectric Behavior of OPEFB Reinforced Polycaprolactone Composites at X-Band Frequency
- Numerical Modeling of Bubble Growth in Microcellular Polypropylene Produced in a Core-Back Injection Process Using Chemical Blowing Agents
- Numerical Simulation and Experimental Validation of Granite Powder Filled Jute Epoxy Composite for Slurry Jet Erosive Wear
- Rheological Modeling of Polymeric Melts in Extruders upon Two-Dimensional Shear Flow
- Experimental Investigation on Curing Stress in Polymer Composite Using Digital Gradient Sensing Technique
- Experimental and Numerical Investigation of Shrinkage and Warpage of a U-Shaped Injection Molded Part
- Modeling for Starve Fed/Flood Fed Mixing Single-Screw Extruders
- The Comparative Study of Different Mixing Methods for Microcrystalline Cellulose/Polyethylene Composites
- Fabrication of Superhydrophobic Polyethylene Parts by Rotomolding
- Numerical Simulation of Chaotic Mixing in Single Screw Extruders with Different Baffle Heights
- PPS News
- PPS News
- Seikei Kakou Abstracts
- Seikei-Kakou Abstracts