Home Carbon Black Reinforced Thermoplastic Vulcanizates Based on High Impact Polystyrene/Styrene-Butadiene-Styrene Block Copolymer/Styrene-Butadiene Rubber Blends
Article
Licensed
Unlicensed Requires Authentication

Carbon Black Reinforced Thermoplastic Vulcanizates Based on High Impact Polystyrene/Styrene-Butadiene-Styrene Block Copolymer/Styrene-Butadiene Rubber Blends

  • S. Li , D.-Y. Wei , J. Zhao and Z.-B. Wang
Published/Copyright: November 4, 2014
Become an author with De Gruyter Brill

Abstract

Thermoplastic vulcanizates (TPVs) based on high impact polystyrene (HIPS)/styrene-butadiene-styrene block copolymer (SBS)/styrene-butadiene rubber (SBR) blends were prepared by dynamic vulcanization, with the TPVs being reinforced by carbon black (CB). Experimental results indicated that mechanical properties of dynamically vulcanized HIPS/SBS/SBR blends were enhanced remarkably by the incorporation of CB. The fracture surface morphology of the reinforced HIPS/SBS/SBR/CB TPVs was relatively flat. The Mullins effect could be observed in the stress-strain curves of HIPS/SBS/SBR TPVs and HIPS/SBS/SBR/CB TPVs during the uniaxial loading-unloading cycles. Compared with HIPS/SBS/SBR TPVs, CB-reinforced HIPS/SBS/SBR TPVs had the relatively higher stress, residual strain and internal friction loss.


* Mail address: Zhaobo Wang, College of Material Science & Engineering, Qingdao University of Science & Technology, No. 53, Zhengzhou Road, Qingdao, Postal Code 266042, PRC. E-mail: ;

References

Abou-Kandil, A. I., Gaafar, M. S., “Effect of Different Types of Carbon Black on the Mechanical and Acoustic Properties of Ethylene-Propylene-Diene Rubber”, J. Appl. Polym. Sci., 117, 15021508 (2010)Search in Google Scholar

Coran, A. Y., Patel, R. P., “Rubber-Thermoplastic Compositions. Part I EPDM-Polypropylene Thermoplastic Vulcanizates”, Rubber Chem. Technol., 53, 141150 (1980)10.5254/1.3535023Search in Google Scholar

Coran, A. Y., Patel, R. P. and Williams, D., “Rubber-Thermoplastic Compositions. Part V. Selecting Polymers for Thermoplastic Vulcanizates”, Rubber Chem. Technol., 55, 116136 (1982)10.5254/1.3535861Search in Google Scholar

Datta, S., Naskar, K., Jelenic, J. and Noordermeer, J. W. M., “Dynamically Vulcanized PP/EPDM Blends by Multifunctional Peroxides: Characterization withith Various Analytical Techniques”, J. Appl. Polym. Sci., 98, 13931403 (2005)10.1002/app.22312Search in Google Scholar

Diani, J., Fayolle, B. and Gilormini, P., “A Review on the Mullins Effect”. Eur. Polym. J., 45, 601612 (2009)10.1016/j.eurpolymj.2008.11.017Search in Google Scholar

Dorfmann, A., Ogden, R. W., “A Constitutive Model for the Mullins Effect with Permanent Set in Particle-Reinforced Rubber”, Int. J. Solids Struct., 41, 18551878 (2004)10.1016/j.ijsolstr.2003.11.014Search in Google Scholar

Drozdov, A. D., “Mullins' Effect in Thermoplastic Elastomers: Experiments and Modeling”, Mech. Res. Commun., 36, 437443 (2009)10.1016/j.mechrescom.2008.12.007Search in Google Scholar

Fisher, K., U.S. Patent 3 758 643 (1973)Search in Google Scholar

Gessler, A. M., Haslett, W. H., U.S. Patent 3 037 954 (1962)Search in Google Scholar

Ikeda, T., Yamada, B., “A Study of Carbon Black Distribution and Properties in BR/NBR Blends: Roles of Commercial Homogenizer and Slipping Agent”. Polym. Plast. Technol., 40, 577592 (2001)10.1081/PPT-100002077Search in Google Scholar

Ismail, H., Ramly, A. F. and Othman, N., “The Effect of Carbon Black/Multiwall Carbon Nanotube Hybrid Fillers on the Properties of Natural Rubber Nanocomposites”, Polym-Plast. Technol., 50, 660666 (2011).10.1080/03602559.2010.551380Search in Google Scholar

Jayasree, T. K., Predeep, P., “Effect of Fillers on Mechanical Properties of Dynamically Crosslinked Styrene Butadiene Rubber/High Density Polyethylene Blends”, J. Elastom. Plast., 40, 127146 (2008)10.1177/0095244307083865Search in Google Scholar

Jankovic, B., Marinovic-Cincovic, M., JovanovicV., Samarzija-Jovanovic, S. and Markovic, G., “Kinetic Analysis of Nonisothermal Degradation of Acrylonitrile-Butadiene/Ethylene-Propylene-Diene Rubber Blends Reinforced with Carbon Black Filler”, Polym. Composite., 53, 802808 (2004)Search in Google Scholar

Kuriakose, B., De, S. K., “Studies on the Melt Flow Behavior of Thermoplastic Elastomers From Polypropylene-Natural Rubber Blends”, Polym. Eng. Sci., 25, 630634 (1985)10.1002/pen.760251009Search in Google Scholar

Le, H. L., Osazuwa, O., Kolesov, I., Ilisch, S. and Radusch, H. J., “Influence of Carbon Black Properties on the Joule Heating Stimulated Shape-Memory Behavior of Filled Ethylene-1-Octene Copolymer”, Polym. Eng. Sci., 51, 500508 (2011)10.1002/pen.21818Search in Google Scholar

Li, J., Mayau, D. and Lagarrigue, V., “A Constitutive Model Dealing with Damage Due to Cavity Growth and the Mullins Effect in Rubber-Like Materials under Triaxial Loading”, J. Mech. Phys. Solids., 56, 953973 (2008)10.1016/j.jmps.2007.06.009Search in Google Scholar

Mullins, L., “Effect of Stretching on the Properties of Rubber”, J. Rubber Res., 16, 275289 (1947)Search in Google Scholar

Mullins, L., Tobin, N. R., “Theoretical Model for the Elastic Behavior of Filler-Reinforced Vulcanized Rubbers”, Rubber Chem. Technol., 30, 555571 (1957)10.5254/1.3542705Search in Google Scholar

Wang, Z. B., ZhaoH. L., Zhao, J. and WangX., “Rheological, Mechanical and Morphological Properties of Thermoplastic Vulcanizates Based on High Impact Polystyrene and Styrene-Butadiene Rubber”, J. Appl. Polym. Sci., 117, 25232529 (2010)Search in Google Scholar

Wu, P., Chen, J. and Wu, C. F., “Crystallization Behavior and Mechanical Properties of Polypropylene/Modified Carbon Black Composites”, Polym. Composite., 30, 391398 (2009)10.1002/pc.20566Search in Google Scholar

Zhao, X. B., Zhang, Q. Y., Gu, J. W., Yin, D. Z. and Yin, C. J., “Effects of Carbon Black on the Properties of HNBR Reinforced by in-Situ Prepared ZDMA”, Polym. Plast. Technol., 50, 15071510 (2011)10.1080/03602559.2011.593086Search in Google Scholar

Received: 2013-11-26
Accepted: 2014-07-01
Published Online: 2014-11-04
Published in Print: 2014-11-30

© 2014, Carl Hanser Verlag, Munich

Articles in the same Issue

  1. Contents
  2. Contents
  3. Regular Contributed Articles
  4. Converging-Diverging Flow in a Novel Extruder and its Application in Film Blowing
  5. Modeling of Plasticating Injection Molding – Experimental Assessment
  6. Viscosity Analysis of a Polymer-Based Drug Delivery System Using Open-Source CFD Methods and High-Pressure Capillary Rheometry
  7. Thermal Properties and Morphology Characteristics of a PP Mono-Filament and its Foam
  8. Thermal and Tensile Behavior of HD-PE Films Containing Iron (III) Acetylacetonate after UV Irradiation
  9. Carbon Black Reinforced Thermoplastic Vulcanizates Based on High Impact Polystyrene/Styrene-Butadiene-Styrene Block Copolymer/Styrene-Butadiene Rubber Blends
  10. A Study of the Bubbles in UV Micro Roll-to-Roll Imprinting
  11. An Annular Rotating-Die Technique in Extrusion Process: Effect of Mandrel Rotating Speed on Extrudate Swell Behavior of HDPE Parison
  12. Investigation of the Structural Robustness of Deep Depth Injection Mold with Cavity Pressure and Mold Design
  13. Verifying the Melting Behavior in Single-Screw Plasticization Units Using a Novel Simulation Model and Experimental Method
  14. Processing of Polyetherimide/Cloisite 30B Nanocomposite by Vibration Casting Method
  15. Comparison between 1D and 3D Approaches for Twin-Screw Extrusion Simulation
  16. Study on the Polymer Melt Flow in a Closely Intermeshing Counter-Rotating Twin Screw Extruder
  17. The Influence of Moisture and Laminate Setup on the De-Consolidation Behavior of PA6/GF Thermoplastic Matrix Composites
  18. PPS News
  19. PPS News
  20. Seikei Kakou Abstracts
  21. Seikei Kakou Abstracts
Downloaded on 23.9.2025 from https://www.degruyterbrill.com/document/doi/10.3139/217.2917/html
Scroll to top button