Home Thermal and Tensile Behavior of HD-PE Films Containing Iron (III) Acetylacetonate after UV Irradiation
Article
Licensed
Unlicensed Requires Authentication

Thermal and Tensile Behavior of HD-PE Films Containing Iron (III) Acetylacetonate after UV Irradiation

  • D. Kiryakova , S. Mihaleva , A. Atanassov and M. Tavlieva
Published/Copyright: November 4, 2014
Become an author with De Gruyter Brill

Abstract

The thermal, tensile and other properties of high density polyethylene films containing iron (III) acetylacetonate as pro-oxidant additive have been studied after exposure to UV irradiation for up to 300 h. The effect of photooxidation on polyethylene films with and without pro-oxidant was estimated by Fourier transform infrared spectroscopy, X-ray diffraction analysis, Differential scanning calorimeter measurements and the tensile properties. It was observed that UV irradiation had almost no effect on the melting temperature of the different samples. After exposure, the degree of crystallinity increased from 69% to 72% for the initial polyethylene samples without pro-oxidant additive and by 3% for the samples containing iron (III) acetylacetonate. It was found that the increase in the carbonyl index of initial HDPE was not significant even after 60 h exposure to UV irradiation while samples with pro-oxidant suffered substantial degradation still for 35 h. It was observed that the decrease of the tensile strength is more pronounced for the samples with pro-oxidant under irradiation for 60 to 70 h. The films containing pro-oxidant lose ∼90% of its initial elongation at break after 35 h exposure.


* Mail address: Dimitrina Kiryakova, Department of Materials Science, Assen Zlatarov University, Y. Yakimov Str. 1, Burgas 8010, Bulgaria. E-mail:

References

Arkatkar, A., Arutchelvi, J., Sudhakar, M., Bhaduri, S., Uppara, P. V. and Doble, M., “Approaches to Enhance the Biodegradation of Polyolefins”, Open Environ. Eng. J., 2, 6880 (2009)10.2174/1874829500902010068Search in Google Scholar

Butler, M. F., Donald, A. M., Bras, W., Mant, G. R., Derbyshire, G. E., and Ryan, A. J., “A Real-Time Simultaneous Small- and Wide-Angle X-ray Scattering Study of In-Situ Deformation of Isotropic Polyethylene”, Macromolecules, 28, 63836393 (1995)10.1021/ma00123a001Search in Google Scholar

Chiellini, E., Corti, A., D'Antone, S. and Baciu, R., “Oxo-Biodegradable Carbon Backbone Polymers – Oxidative Degradation of Polyethylene under Accelerated Test Conditions”, Polym. Degrad. Stab., 91, 27392747 (2006)10.1016/j.polymdegradstab.2006.03.022Search in Google Scholar

Chrissafis, K., Paraskevopoulos, K. M., Pavlidou, E. and Bikiaris, D., “Thermal Degradation Mechanism of HDPE Nanocomposites Containing Fumed Silica Nanoparticles”, Thermochim. Acta, 485, 6571 (2009)10.1016/j.tca.2008.12.011Search in Google Scholar

Encinar, J. M., Gonzalez, J. F., “Pyrolysis of Synthetic Polymers and Plastic Wastes. Kinetic Study”, Fuel Process. Technol., 89, 678686 (2008)10.1016/j.fuproc.2007.12.011Search in Google Scholar

Fabiyi, J. S., McDonald, A. G., Wolcott, M. P. and Griffiths, P. R., “Wood Plastic Composites Weathering: Visual Appearance and Chemical Changes”, Polym. Degrad. Stab., 93, 14051414 (2008)10.1016/j.polymdegradstab.2008.05.024Search in Google Scholar

Grigoriadou, I., Paraskevopoulos, K., Chrissafis, K., Pavlidou, E., Stamkopoulos, T. G. and Bikiaris, D., “Effect of Different Nanoparticles on HDPE UV Stability”, Polym. Degrad. Stab., 96, 151163 (2011)10.1016/j.polymdegradstab.2010.10.001Search in Google Scholar

Gulmine, J. V., Janissek, P. R., Heise, H. M. and Akcelrud, L., “Polyethylene Characterization by FTIR”, Polym. Test., 21, 557563 (2002)10.1016/S0142-9418(01)00124-6Search in Google Scholar

Hinsken, H., Moss, S., Pauquet, J.-R., Zweifel, H., “Degradation of Polymers during Melt Processing”, Polym. Degrad. Stab., 34, 279293 (1991)10.1016/0141-3910(91)90123-9Search in Google Scholar

Inci, B., Wagener, K. B., “Decreasing the Alkyl Branch Frequency in Precision Polyethylene: Pushing the Limits toward Longer Run Lengths”, J. Am. Chem. Soc., 133, 1187211875 (2011)10.1021/ja2040046Search in Google Scholar PubMed

Kayacan, I., Dogan, O. M., “Pyrolysis of Low and High Density Polyethylene. Part I: Non-isothermal Pyrolysis Kinetics”, Energ. Sources Part A, 30, 385391 (2008)10.1080/15567030701457079Search in Google Scholar

Kulich, D. M., Wolkowicz, M. D., “Chapter 15 Stabilizer Partitioning in Rubber-Modified Systems”, in Rubber-Toughened Plastics, Riew, C. K. (Ed.), American Chemical Society, Washington DC, p. 329341 (1989)10.1021/ba-1989-0222.ch015Search in Google Scholar

Lacoste, J., Carlsson, D. J., “Gamma-, Photo-, and Thermally-Initiated Oxidation of Linear Low Density Polyethylene: A Quantitative Comparison of Oxidation Products”, J. Polym. Sci., 30, 493500 (1992)10.1002/pola.1992.080300316Search in Google Scholar

La Mantia, F. P., Dintcheva, N. T., “Photooxidation and Stabilization of Photooxidized Polyethylene and of its Monopolymer Blends”, J. Appl. Polym. Sci., 91, 22442255 (2004)10.1002/app.13352Search in Google Scholar

Mark, E. J.: Physical Properties of Polymers Handbook, Springer, New York (2007)10.1007/978-0-387-69002-5Search in Google Scholar

Ohtake, Y., Kobayashi, T., Asabe, H. and Murakami, N., “Biodegradation of Low-Density Polyethylene, Polystyrene, Polyvinyl Chloride, and Urea Formaldehyde Resin Buried under Soil for over 32 years”, J. Appl. Polym. Sci., 56, 17891796 (1995)10.1002/app.1995.070561309Search in Google Scholar

Reddy, M. M., Gupta, R. K., Bhattacharya, S. N. and Parthasarathy, R., “Abiotic Oxidation Studies of Oxo-biodegradable Polyethylene”, J. Polym. Environ., 16, 2734 (2008)10.1007/s10924-008-0081-zSearch in Google Scholar

Roy, P. K., Surekha, P., Rajagopal, C., Chatterjee, S. N. and Choudhary, V., “Accelerated Aging of LDPE Films Containing Cobalt Complexes as Prooxidants”, Polym. Degrad. Stab., 91, 17911799 (2006)10.1016/j.polymdegradstab.2005.11.010Search in Google Scholar

Roy, P. K., Surekha, P., Raman, R. and Rajagopal, C., “Thermal Degradation of Star-Shaped Poly(∊-caprolactone)”, Polym. Degrad. Stab., 94, 10331039 (2009)10.1016/j.polymdegradstab.2009.04.025Search in Google Scholar

Sinfronio, F. S. M., Santos, J. C. O., Pereira, L. G., Souza, A. G., Conceicao, M. M., FernandesJr., V. J. and Fonseca, V. M., “Kinetic of Thermal Degradation of Low-density and Highdensity Polyethylene by Non-isothermal Thermogravimetry”, J. Therm. Anal. Cal., 79, 393399 (2005)10.1007/s10973-005-0072-4Search in Google Scholar

Suresh, B., Maruthamuthu, S., Khare, A., Palanisamy, N., Muralidharan, V. S., Ragunathan, R., Kannan, M. and Pandiyaraj, K. N., “Influence of Thermal Oxidation on Surface and Thermo-Mechanical Properties of Polyethylene”, J. Polym. Res., 18, 21752184 (2011)10.1007/s10965-011-9628-0Search in Google Scholar

Valadez-Gonzalez, A., Cervantes-Uc, J. M. and Veleva, L., “Mineral Filler Influence on the Photo-Oxidation of High Density Polyethylene: I. Accelerated UV Chamber Exposure Test”, Polym. Degrad. Stab., 63, 253260 (1999)10.1016/S0141-3910(98)00102-5Search in Google Scholar

Waddon, A., Zheng, L., Farris, R. and Coughlin, E. B., “Nanostructured Polyethylene-POSS Copolymers: Control of Crystallization and Aggregation”, Nano Lett., 2, 11491155 (2002)10.1021/nl020208dSearch in Google Scholar

Received: 2013-11-22
Accepted: 2014-05-15
Published Online: 2014-11-04
Published in Print: 2014-11-30

© 2014, Carl Hanser Verlag, Munich

Articles in the same Issue

  1. Contents
  2. Contents
  3. Regular Contributed Articles
  4. Converging-Diverging Flow in a Novel Extruder and its Application in Film Blowing
  5. Modeling of Plasticating Injection Molding – Experimental Assessment
  6. Viscosity Analysis of a Polymer-Based Drug Delivery System Using Open-Source CFD Methods and High-Pressure Capillary Rheometry
  7. Thermal Properties and Morphology Characteristics of a PP Mono-Filament and its Foam
  8. Thermal and Tensile Behavior of HD-PE Films Containing Iron (III) Acetylacetonate after UV Irradiation
  9. Carbon Black Reinforced Thermoplastic Vulcanizates Based on High Impact Polystyrene/Styrene-Butadiene-Styrene Block Copolymer/Styrene-Butadiene Rubber Blends
  10. A Study of the Bubbles in UV Micro Roll-to-Roll Imprinting
  11. An Annular Rotating-Die Technique in Extrusion Process: Effect of Mandrel Rotating Speed on Extrudate Swell Behavior of HDPE Parison
  12. Investigation of the Structural Robustness of Deep Depth Injection Mold with Cavity Pressure and Mold Design
  13. Verifying the Melting Behavior in Single-Screw Plasticization Units Using a Novel Simulation Model and Experimental Method
  14. Processing of Polyetherimide/Cloisite 30B Nanocomposite by Vibration Casting Method
  15. Comparison between 1D and 3D Approaches for Twin-Screw Extrusion Simulation
  16. Study on the Polymer Melt Flow in a Closely Intermeshing Counter-Rotating Twin Screw Extruder
  17. The Influence of Moisture and Laminate Setup on the De-Consolidation Behavior of PA6/GF Thermoplastic Matrix Composites
  18. PPS News
  19. PPS News
  20. Seikei Kakou Abstracts
  21. Seikei Kakou Abstracts
Downloaded on 22.9.2025 from https://www.degruyterbrill.com/document/doi/10.3139/217.2900/html
Scroll to top button