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Microstructures and biocorrosion properties of biodegradable Mg–Zn–Y–Ca–xZr alloys

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Published/Copyright: July 4, 2018

Abstract

The influence of Zr microalloying on the microstructures and corrosion resistance of as-cast Mg-3.0Zn-0.6Y-0.3Ca (wt.%) alloy were investigated by means of optical microscopy, X-ray diffraction analysis, transmission electron microscopy, scanning electron microscopy, immersion testing and electrochemical measurements. The results indicated that Zr induced the formation of a strip-like eutectic phase at the grain boundaries, and discouraged the formation of isolated particles. With the Zr addition, the microstructure was refined and the corrosion resistance was enhanced. The alloy with a Zr content of 0.5 wt.% has an optimal corrosion resistance, which can be attributed to the fine and continuously distributed strip-like I-phase and fine grain structure.


*Correspondence address, Prof. Dr. Chunxiang Xu, School of Materials Science and Engineering, Taiyuan University of Technology, Yingze West Street, Taiyuan 030024, P.R. China, Tel.: +86-13734035026, Fax: +86-351-6010022, E-mail:

References

[1] Y.Unigovski, A.Eliezer, E.Abramov, Y.Snir, E.M.Gutman: Mater. Sci. Eng. A360 (2003) 132. 10.1016/S0921-5093(03)00409-XSearch in Google Scholar

[2] G.L.Song, A.Atrens: Adv. Eng. Mater.5 (2003) 837. 10.1002/adem.200310405Search in Google Scholar

[3] W.L.Cheng, S.C.Ma, Y.Bai, Z.Q.Cui, H.X.Wang: J. Alloys Compd.731 (2018) 945. 10.1016/j.jallcom.2017.10.073Search in Google Scholar

[4] C.Liu, H.Z.Yang, P.Wan, K.H.Wang, L.L.Tan, K.Yang: Mater. Sci. Eng. C35 (2014) 1. 10.1016/j.msec.2013.10.020Search in Google Scholar PubMed

[5] L.wang, J.B.Li, K.B.Nie, J.S.Zhang, C.W.Yang, P.W.Yan, Y.P.Liu, C.X.Xu: Mater. Sci. Technol.33 (2017) 9. 10.1080/02670836.2016.1152348Search in Google Scholar

[6] K.D.Ralston, D.Fabijanic, N.Birbilis: Electrochim. Acta56 (2011) 1729. 10.1016/j.electacta.2010.09.023Search in Google Scholar

[7] Y.C.Li, C.E.Wen, D.Mushahary, R.Sravanthi, N.Harishankar, G.Pande, P.Hodgson: Acta Biomater.8 (2012) 3177. 10.1016/j.actbio.2012.04.028Search in Google Scholar PubMed

[8] Y.Lu, A.R.Bradshaw, Y.L.Chiu, I.P.Jones: Mater. Sci. Eng.C48 (2015) 480. PMid:25579949; 10.1016/j.msec2014.12.049Search in Google Scholar

[9] Y.Zhang, J.X.Li, J.Y.Li: J. Alloys Compd.728 (2017) 37. 10.1016/j.jallcom.2017.08.264Search in Google Scholar

[10] Y.Zhang, J.X.Li, J.Y.Li: J. Alloys Compd.730 (2018) 458. 10.1016/j.jallcom.2017.09.325Search in Google Scholar

[11] H.R.Bakhsheshi-Rad, M.R.Abdul-Kadir, M.H.Idris, S.Farahany: Corros. Sci.64 (2012) 184. 10.1016/j.corsci.2012.07.015Search in Google Scholar

[12] D.K.Xu, E.H.Han: Prog. Mater. Sci.22 (2012) 364. 10.1016/j.pnsc.2012.09.005Search in Google Scholar

[13] E.L.Zhang, W.W.He, H.Du, K.Yang: Mater. Sci. Eng. A488 (2008) 102. 10.1016/j.msea.2007.10.056Search in Google Scholar

[14] J.Z.Ilich, J.E.Kerstetter: J. Am. Coll. Nutr.19 (2000) 715. PMid:11194525; 10.1080/07315724.2000.10718070Search in Google Scholar PubMed

[15] Q.Wen, K.K.Deng, J.Y.Shi, B.P.Zhang, W.Liang: Mater. Sci. Eng. A609 (2014) 1. 10.1016/j.msea.2014.04.093Search in Google Scholar

[16] Z.Li, M.F.Chen, W.Li, H.R.Zheng, C.You, D.B.Liu, F.Jin: J. Alloys Compd.702 (2017) 290. 10.1016/j.jallcom.2017.01.178Search in Google Scholar

[17] T.Li, H.Zhang, Y.He, N.Wen, X.Wang: J. Mater. Sci. Technol.31(2015) 744. 10.1016/j.jmst.2015.02.001Search in Google Scholar

[18] T.Kokubo, H.Takadama: Biomater.27 (2006) 2907. PMid:16448693; 10.1016/j.biomaterials.2006.01.017Search in Google Scholar PubMed

[19] ASTM G31-72, Standard Practice for Laboratory Immersion Corrosion Testing of Metals, American Society for Testing & Materials, West Conshohocken, 2004.Search in Google Scholar

[20] Y.W.Song, D.Y.Shan, R.S.Chen, E.H.Han: Corros. Sci.51 (2009) 1087. 10.1016/j.corsci.2009.03.011Search in Google Scholar

[21] Z.Qiao, Z.Shi, N.Hort, N.I. ZainalAbidin, A.Atrens: Corros. Sci.61 (2012) 185. 10.1016/j.corsci.2012.04.030Search in Google Scholar

[22] A.Atrens, G.L.Song, M.Liu, Z.Shi, F.Cao, M.S.Dargusch: Adv. Eng. Mater.17 (2015) 400. 10.1002/adem.201400434Search in Google Scholar

[23] F.Cao, Z.Shi, G.L.Song, M.Liu, A.Atrens: Corros. Sci.76 (2013) 60. 10.1016/j.corsci.2013.06.030Search in Google Scholar

[24] Y.Ali, D.Qiu, B.Jiang, F.S.Pan, M.X.Zhang: J. Alloys Compd.619 (2015) 639. 10.1016/j.jallcom.2014.09.061Search in Google Scholar

[25] C.Wang, H.Y.Zhang, H.Y.Wang, G.J.Liu, Q.C.Jiang: Scr. Mater.69 (2013) 445. 10.1016/j.scriptamat.2013.05.026Search in Google Scholar

[26] P.M.Jardim, G.Solorzano, J.B. VanderSande: Microsc. Microanal.8 (2002) 487. PMid:12533209; 10.1017/S1431927602010413Search in Google Scholar PubMed

[27] W.F.Ng, K.Y.Chiu, F.T.Cheng: Mater. Sci. Eng. C30 (2010) 898. 10.1016/j.msec.2010.04.003Search in Google Scholar

[28] T.Li, H.Zhang, Y.He, X.Wang: Mater. Corros.66 (2015) 7. 10.1002/maco.201307528Search in Google Scholar

[29] N.I. ZainalAbidin, A.D.Atrens, D.Martin, A.Atrens: Corros. Sci.53 (2011) 3542. 10.1016/j.corsci.2011.06.030Search in Google Scholar

[30] F.Cao, Z.shi, J.Hofstetter, P.J.Uggowitzer, G.L.Song, M.Liu, A.Atrens: Corros. Sci.75 (2013) 78. 10.1016/j.corsci.2013.05.018Search in Google Scholar

[31] K.Nogita, S.Ockert, J.Pierce, M.C.Greaves, C.M.Gourlay, A.K.Dahle: Int. J. Hydrogen Energy34 (2009) 7686. 10.1016/j.ijhydene.2009.07.036Search in Google Scholar

[32] X.M.Zong, J.S.Zhang, W.Liu, J.A.Chen, K.B.Nie, C.X.Xu: Adv. Eng. Mater.19 (2017) 1. 10.1002/adem.201600606Search in Google Scholar

[33] Z.Shi, A.Atrens: Corros. Sci.53 (2011) 226. 10.1016/j.corsci.2010.09.016Search in Google Scholar

[34] G.L.Song, A.Atrens, X.L.Wu, B.Zhang: Corros. Sci.40 (1998) 1769. 10.1016/S0010-938X(98)00078-XSearch in Google Scholar

[35] R.Ambat, N.N.Aung, W.Zhou: Corros. Sci.42 (2000) 1433. 10.1016/S0010-938X(99)00143-2Search in Google Scholar

[36] M.C.Zhao, M.Liu, G.L.Song, A.Atrens: Corros. Sci.50 (2008) 1939. 10.1016/j.corsci.2008.04.010Search in Google Scholar

[37] F.Shi, Y.C.Yu, X.F.Guo, Z.M.Zhang, Y.Y.Li: Trans. Nonferrous Met. Soc. China19 (2009) 1093. 10.1016/S1003-6326(08)60412-4Search in Google Scholar

[38] D.K.Xu, E.H.Han: Scr. Mater.71 (2014) 21. 10.1016/j.scriptamat.2013.09.025Search in Google Scholar

Received: 2017-07-06
Accepted: 2018-02-05
Published Online: 2018-07-04
Published in Print: 2018-07-12

© 2018, Carl Hanser Verlag, München

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