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Kinetics for gas–solid reactions involving dual-reaction interfaces

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Published/Copyright: September 10, 2015
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International Journal of Materials Research
From the journal International Journal of Materials Research Volume 106 Issue 9

Abstract

A series of new equations have been developed, based on the pseudo-steady state approximation, to describe the kinetics of gas–solid reactions involving two reaction interfaces. These formulae can be applied to cases where two solid product layers (stoichiometric compounds or solid solution products) are involved, or to one solid product layer and one volatile species (formed by the reaction of solid product with gas). For the latter case, when either the solid product layer is dense, or the diffusion process is the controlling step, the relationship is equivalent to the widely-used Tedmon model.

Keywords: Corrosion; Diffusion; Kinetics; Tedmon model
*Correspondence address, Associate Professor Guo-Hua Zhang, State Key Laboratory of Advanced Metallurgy, University of Science and Technology Beijing, Xue-Yuan Road 30, Hai-Dian District, Beijing 100083, China, Tel.: +86-10-82377750, Fax: +86-10-62332252, E-mail:

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Received: 2014-10-28
Accepted: 2015-04-20
Published Online: 2015-09-10
Published in Print: 2015-09-15

© 2015, Carl Hanser Verlag, München

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https://doi.org/10.3139/146.111260
Keywords for this article
Corrosion; Diffusion; Kinetics; Tedmon model

Articles in the same Issue

  1. Contents
  2. Contents
  3. Original Contributions
  4. Kinetics for gas–solid reactions involving dual-reaction interfaces
  5. Preparation of 6N grade silicon ingot by combined purification processes from waste silicon cutting sludge
  6. Material characterisation to identify the rheological behaviour for powder injection moulding
  7. Isothermal section of Nd–Mn–As phase diagram at 800 °C
  8. Influence of bath temperature and pH on the structure of electrodeposited cobalt nanowires
  9. Influence of combined grain refinement and modification on the microstructure, tensile strength and wear properties of Al-15Si, Al-15Si-4.5Cu alloys
  10. The investigation of mechanical properties of B4C-reinforced AlSi7 foams
  11. The stabilising effect of oxides in foamed aluminium alloy scrap
  12. Physical chemistry of WC-12 %Co coatings deposited by thermal spraying at different standoff distances
  13. Experimental investigation on the tensile behavior of a transparent polyurethane interlayer
  14. Short Communications
  15. Linearized analysis of X-ray stress measurement using the Debye–Scherrer ring
  16. Gas induced semi-solid process effects on microstructure and mechanical properties of 319 aluminum alloy
  17. Ductile fracture behavior of low carbon high strength steel using continuum damage mechanics
  18. Fabrication of β-Si3N4 whiskers by microwave sintering using ZrO2–Y2O3–Al2O3 as liquid phase
  19. People
  20. Berthold Scholtes on the occasion of his 65th birthday
  21. DGM News
  22. DGM News
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