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Adsorption of nucleotides on the rutile (110) surface

  • Sibylle Gemming , Andrey N. Enyashin , Johannes Frenzel and Gotthard Seifert
Published/Copyright: May 31, 2013
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International Journal of Materials Research
From the journal International Journal of Materials Research Volume 101 Issue 6

Abstract

The present study aims at the computer-aided design of suitably functionalized oxide surfaces for the integration of nanotubes into multi-purpose nano-electronic devices. The adsorption of the nucleotide cytidine monophosphate on the rutile (110) surface is investigated by density-functional-based tight-binding calculations. The nucleotide favors anchoring with two oxygen atoms of its phosphate part. Adsorption occurs preferentially at two neighboring five-fold coordinated Ti atoms along the [001] direction, thus opening a pathway to an ordered adsorption of nanotubes along [001]. The electronic densities of state show that the aromatic part of the cytidine residue remains unchanged upon adsorption on rutile. This implies that no significant changes occur in the nanotube binding capacity by -stacking of the aromatic part, hence, nucleotide-functionalized oxide surfaces are ideal substrates for the ordered, stable and electronically and chemically inert immobilization of nanotubes.

Keywords: Nucleic acids; Adsorption; Rutile surface; Nanotubes
* Correspondence address, PD Dr. Sibylle Gemming, Forschungszentrum Dresden-Rossendorf, POB 51 01 19, D-01314 Dresden, Germany, Tel.: +49 351 260 2470, Fax: +49 351 260 3285, E-mail:

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Received: 2008-12-16
Accepted: 2009-11-12
Published Online: 2013-05-31
Published in Print: 2010-06-01

© 2010, Carl Hanser Verlag, München

Articles in the same Issue

  1. Contents
  2. Contents
  3. Editorial
  4. IJMR's most downloaded papers from 2008 to the present: a review
  5. Basic
  6. Effect of temperature and strain rate on strain hardening and deformation mechanisms of high manganese austenitic steels
  7. Size effects resulting from local strain hardening; microstructural evaluation of Fe-3% Si and Cu deformed in tension and deep drawing using orientation gradient mapping (OGM)
  8. Microstructure of super-austenitic steels after long-term annealing
  9. Investigation of tensile–compressive yield asymmetry and the role of deformation twin in extruded pure magnesium
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  11. Investigation of the atomic structure of molten As–Se alloys using X-ray diffraction
  12. A theoretical approach to the elastic behaviour of compact and hollow spherical particles reinforced metal-matrix composites
  13. Applied
  14. Adsorption of nucleotides on the rutile (110) surface
  15. Effect of cyclic heat treatment on the microstructures and mechanical properties of Ti–Si alloys
  16. Deleterious phases resulting from the induction bending of thick-walled super-duplex pipework
  17. Steady state creep in a rotating composite disc of variable thickness
  18. Influence of data conversion methods from torsion tests on the Garofalo equation parameters for a high nitrogen steel
  19. High-alloy ferritic cast irons with different graphite microstructures for exhaust manifolds and turbocharger housings
  20. Microstructure and mechanical properties of friction stir butt welded dissimilar pure copper/brass alloy plates
  21. The heat capacity measurements of CoSb3-based Skutterudite compounds
  22. DGM News
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https://doi.org/10.3139/146.110337
Keywords for this article
Nucleic acids; Adsorption; Rutile surface; Nanotubes

Articles in the same Issue

  1. Contents
  2. Contents
  3. Editorial
  4. IJMR's most downloaded papers from 2008 to the present: a review
  5. Basic
  6. Effect of temperature and strain rate on strain hardening and deformation mechanisms of high manganese austenitic steels
  7. Size effects resulting from local strain hardening; microstructural evaluation of Fe-3% Si and Cu deformed in tension and deep drawing using orientation gradient mapping (OGM)
  8. Microstructure of super-austenitic steels after long-term annealing
  9. Investigation of tensile–compressive yield asymmetry and the role of deformation twin in extruded pure magnesium
  10. Neutron diffraction study on liquid Al–Ni alloys
  11. Investigation of the atomic structure of molten As–Se alloys using X-ray diffraction
  12. A theoretical approach to the elastic behaviour of compact and hollow spherical particles reinforced metal-matrix composites
  13. Applied
  14. Adsorption of nucleotides on the rutile (110) surface
  15. Effect of cyclic heat treatment on the microstructures and mechanical properties of Ti–Si alloys
  16. Deleterious phases resulting from the induction bending of thick-walled super-duplex pipework
  17. Steady state creep in a rotating composite disc of variable thickness
  18. Influence of data conversion methods from torsion tests on the Garofalo equation parameters for a high nitrogen steel
  19. High-alloy ferritic cast irons with different graphite microstructures for exhaust manifolds and turbocharger housings
  20. Microstructure and mechanical properties of friction stir butt welded dissimilar pure copper/brass alloy plates
  21. The heat capacity measurements of CoSb3-based Skutterudite compounds
  22. DGM News
  23. DGM News
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