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Wetting of metals and glasses on Mo

  • Antoni P. Tomsia , Eduardo Saiz , Sonia López-Esteban , Mehdi Benhassine , Joel de Coninck , Nicole Rauch and Manfred Rühle
Published/Copyright: June 11, 2013
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International Journal of Materials Research
From the journal International Journal of Materials Research Volume 98 Issue 12

Abstract

The wetting of low melting point metals and Si – Ca – Al – Ti – O glasses on molybdenum has been investigated. The selected metals (Au, Cu, Ag) form a simple eutectic with Mo. Metal spreading occurs under nonreactive conditions without interdiffusion or ridge formation. The metals exhibit low (non-zero) contact angles on Mo but this requires temperatures higher than 1100 °C in reducing atmospheres in order to eliminate a layer of adsorbed impurities on the molybdenum surface. By controlling the oxygen activity in the furnace, glass spreading can take place under reactive or nonreactive conditions. We have found that in the glass/Mo system the contact angle does not decrease under reactive conditions. In all cases, adsorption from the liquid seems to accelerate the diffusivity on the free molybdenum surface.

Keywords: Wetting; Interface; Glasses; Liquid metals; Interfacial energies
* Correspondence address, Antoni P. Tomsia, Materials Sciences Division, Lawrence Berkeley National Laboratory, MSD Building 62R0203, Berkeley, CA 94720, USA. Tel.: +1 510 486 4918, Fax: +1 510 486 4761, E-mail:

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Received: 2007-6-25
Accepted: 2007-9-12
Published Online: 2013-06-11
Published in Print: 2007-12-01

© 2007, Carl Hanser Verlag, München

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https://doi.org/10.3139/146.101581
Keywords for this article
Wetting; Interface; Glasses; Liquid metals; Interfacial energies

Articles in the same Issue

  1. Contents
  2. Contents
  3. Editorial
  4. Tony Evans 65 years
  5. Basic
  6. Do plastic zones form at crack tips in silicate glasses?
  7. Phase stability of thermal barrier oxides: A comparative study of Y and Yb additions
  8. Internal stresses and phase stability in multiphase environmental barrier coatings
  9. Mechanisms of elastodynamic erosion of electron-beam thermal barrier coatings
  10. Directed assembly of fluidic networks by buckle delamination of films on patterned substrates
  11. In-situ studies of the TGO growth stresses and the martensitic transformation in the B2 phase in commercial Pt-modified NiAl and NiCoCrAlY bond coat alloys
  12. Adhesion of the γ-Ni(Al)/α-Al2O3 interface: a first-principles assessment
  13. Crystal chemistry of interfaces formed between two different non-metallic, inorganic structures
  14. Applied
  15. Materials for violin bows
  16. Wetting of metals and glasses on Mo
  17. High temperature creep of La-monazite
  18. Sandwich panels for blast protection in water: simulations
  19. Thermal-elastic response of marble polycrystals: Influence of grain orientation configuration
  20. The compressive response of carbon fiber composite pyramidal truss sandwich cores
  21. Reactions in the sintering of MgAl2O4 spinel doped with LiF
  22. Crack-tip strain fields in collagen biomaterials for skin tissue engineering
  23. DGM News
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