Crystal chemistry of interfaces formed between two different non-metallic, inorganic structures
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David Andeen
Abstract
Epitaxial relations are often described by the mismatch of lattice parameters between the two materials. When the structures forming the epitaxial interface are dissimilar, the lattice mismatch is often less meaningful because of the different geometrical arrangement of atoms in the two structures. In a previous paper, it was shown that two rules of crystal chemistry, widely known as Pauling's rules, namely cation/anion coordination and charge balance, could be applied to understand the epitaxy of (0001) ZnO (wurtzite) on (111) MgAl2O4 (spinel) substrates. It was then shown that the same rules could be applied to predict and confirm the epitaxy of (101) SiO2 (cristobalite) on (0001) Al2O3 (sapphire). Here, the same rules are applied to explain the epitaxy of four other dissimilar structures that have been previously published by others, including SrTiO3 on Ni c(2 × 2) S, TiO2 (anatase) on LaAlO3, TiO2 (rutile) on r-plane Al2O3, and Zr1−x (Yx)O2 on (0001) Al2O3.
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© 2007, Carl Hanser Verlag, München
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Articles in the same Issue
- Contents
- Contents
- Editorial
- Tony Evans 65 years
- Basic
- Do plastic zones form at crack tips in silicate glasses?
- Phase stability of thermal barrier oxides: A comparative study of Y and Yb additions
- Internal stresses and phase stability in multiphase environmental barrier coatings
- Mechanisms of elastodynamic erosion of electron-beam thermal barrier coatings
- Directed assembly of fluidic networks by buckle delamination of films on patterned substrates
- In-situ studies of the TGO growth stresses and the martensitic transformation in the B2 phase in commercial Pt-modified NiAl and NiCoCrAlY bond coat alloys
- Adhesion of the γ-Ni(Al)/α-Al2O3 interface: a first-principles assessment
- Crystal chemistry of interfaces formed between two different non-metallic, inorganic structures
- Applied
- Materials for violin bows
- Wetting of metals and glasses on Mo
- High temperature creep of La-monazite
- Sandwich panels for blast protection in water: simulations
- Thermal-elastic response of marble polycrystals: Influence of grain orientation configuration
- The compressive response of carbon fiber composite pyramidal truss sandwich cores
- Reactions in the sintering of MgAl2O4 spinel doped with LiF
- Crack-tip strain fields in collagen biomaterials for skin tissue engineering
- DGM News
- Personal