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Synthesis and oxidation of Zr3Al3C5 powders

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Published/Copyright: May 23, 2013
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International Journal of Materials Research
From the journal International Journal of Materials Research Volume 98 Issue 1

Abstract

Predominantly single phase Zr3Al3C5 powders were synthesized in an Ar atmosphere using Zr – Al intermetallics and graphite as starting materials. The reaction path of Zr3Al3C5 synthesis was discussed based on differential scanning calorimetry and X-ray diffraction results. Lattice parameters of Zr3Al3C5 determined using the Rietveld method are a = 3.347 Å and c = 27.642 Å. In addition, the oxidation of Zr3Al3C5 powders was tested by using thermogravimetry – differential scanning calorimetry. The starting and complete oxidation temperatures are 400 °C and 1200 °C, respectively. These temperatures are much higher than those for ZrC, suggesting that Zr3Al3C5 has better oxidation resistance than ZrC. On the other hand, the oxidation degree of Zr3Al3C5, defined for the complete carbide – oxide transformation, overshot 100 % during oxidation. This overshooting is attributed to the formation of amorphous carbon. The phase evolution during the oxidation of Zr3Al3C5 was also investigated.

Keywords: Zr3Al3C5; ZrC; Oxidation; XRD; DSC
* Correspondence address, Dr. Yanchun Zhou, Professor and Director of High-performance Ceramic Division, Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang, 110016, P.R. China, Tel.: +86 24 2397 1765, Fax: +86 24 2389 1320, E-mail:

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Received: 2006-3-2
Accepted: 2006-10-14
Published Online: 2013-05-23
Published in Print: 2007-01-01

© 2007, Carl Hanser Verlag, München

Articles in the same Issue

  1. Contents
  2. Contents
  3. Editorial
  4. Editorial
  5. Basic
  6. Synthesis and oxidation of Zr3Al3C5 powders
  7. Standard Gibbs energy of formation of Zn17Y2 and Zn12Y determined by solution calorimetry and measurement of heat capacity from near zero Kelvin
  8. Phase equilibria in the Zn–Fe–S system at 450°C
  9. Formation of δ-Al2O3 hollow nanoparticles via a chemical vapor condensation process
  10. Low-cycle fatigue and damage of an uncoated and coated single crystal nickel-base superalloy SCB
  11. Fluidity of Mg–Al–Ca alloys in the high-pressure die casting process
  12. Applied
  13. Mechanical properties of rope-reinforced aluminium extrusions under quasistatic loading conditions
  14. Influence of interfaces on the mechanical properties of ultrahigh carbon steel multilayer laminates
  15. Thermomechanical processing of AA6061 billets for semi-solid forming
  16. Infrared spectroscopy and X-ray diffraction data of In – Se compounds
  17. Synthesis and characterization of MgAlON–BN composites
  18. Neutron diffraction residual stress analysis of steel engineering components: a study of the elastic and plastic anisotropy
  19. Notifications
  20. DGM News
https://doi.org/10.3139/146.101427
Keywords for this article
Zr3Al3C5; ZrC; Oxidation; XRD; DSC

Articles in the same Issue

  1. Contents
  2. Contents
  3. Editorial
  4. Editorial
  5. Basic
  6. Synthesis and oxidation of Zr3Al3C5 powders
  7. Standard Gibbs energy of formation of Zn17Y2 and Zn12Y determined by solution calorimetry and measurement of heat capacity from near zero Kelvin
  8. Phase equilibria in the Zn–Fe–S system at 450°C
  9. Formation of δ-Al2O3 hollow nanoparticles via a chemical vapor condensation process
  10. Low-cycle fatigue and damage of an uncoated and coated single crystal nickel-base superalloy SCB
  11. Fluidity of Mg–Al–Ca alloys in the high-pressure die casting process
  12. Applied
  13. Mechanical properties of rope-reinforced aluminium extrusions under quasistatic loading conditions
  14. Influence of interfaces on the mechanical properties of ultrahigh carbon steel multilayer laminates
  15. Thermomechanical processing of AA6061 billets for semi-solid forming
  16. Infrared spectroscopy and X-ray diffraction data of In – Se compounds
  17. Synthesis and characterization of MgAlON–BN composites
  18. Neutron diffraction residual stress analysis of steel engineering components: a study of the elastic and plastic anisotropy
  19. Notifications
  20. DGM News
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