Determination of natural uranium, thorium and radium isotopes in water and soil samples by alpha spectroscopy
-
Le Cong Hao
, Chau Van Tao , Nguyen Van Dong , Luong Van Thong und Duong Mong Linh
Abstract
In this study, a simple procedure for the determination of natural uranium, thorium and radium isotopes in water and soil samples by alpha spectroscopy is described. This procedure allows a sequential extraction polonium, uranium, thorium and radium radionuclides from the same sample in two to three days. It was tested and validated with the analysis of certified reference materials from the IAEA.
Kurzfassung
In dieser Untersuchung wird ein einfaches Verfahren zur Bestimmung natürlicher Uran, Thorium- und Radiumisotope in Wasser- und Bodenproben mit Hilfe der Alphaspektrometrie vorgestellt. Dieses Verfahren erlaubt eine sequentielle Extraktion von Polonium-, Uran-, Thorium- and Radiumisotopen aus der gleichen Probe in zwei bis drei Tagen. Es wurde geprüft und validiert durch eine Analyse zertifizierter IAEA Referenzmaterialien.
References
1 Aggarwal, S. K.; Chourasiya, G.; Duggal, R. K.; Singh, C. P.; Eawat, A. S.; Jain, H. C.: Nucl. Instrum. Methods Phys. Res. A238 (1985)10.1016/0168-9002(85)90485-1Suche in Google Scholar
2 Al-Masri, M. S. and Blackburn, R.: Radiat. Phys. Chem.47 (1996) 17110.1016/0969-806X(95)00030-2Suche in Google Scholar
3 Alvarado, J.; Orlandini, K. A.; Erickson, M. D.: J. Radioanal. Nucl. Chem.194 (1995) 13310.1007/BF02037623Suche in Google Scholar
4 Benedik, L.; Vasile, M.; Spasova, U.; Watjen, U.: Appl. Radiat. Isot.67 (2009) 770–77510.1016/j.apradiso.2009.01.033Suche in Google Scholar
5 Blanco Rodríguez, P.; Vera Tome, F.; Lozato, J. C.: Appl. Radiat. Isot.54 (2001) 29–3310.1016/S0969-8043(00)00192-5Suche in Google Scholar
6 Carswell, D.; Milsted, J. J.: Nucl. Energy4 (1957) 51Suche in Google Scholar
7 Doretti, L.; Ferrara, D.; Barison, G.: Radioanal. Nucl. Chem.134 (1989) 34310.1007/BF02278272Suche in Google Scholar
8 Doretti, L.; Ferrara, D.; Barison, G.: Radioanal. Chem. Vol. 141 (1990) 20310.1007/BF02060199Suche in Google Scholar
9 Flores-Mendoza, J.; Iturbe, J. L.; Jimenez-Reyes, M.: J. Radioanal. Nucl. Chem. Articles. 162 (1992) 131–13810.1007/BF02039933Suche in Google Scholar
10 Flynn, U. U.: Analytical. Chimica Acta43 (1968) 221–22710.1016/S0003-2670(00)89210-7Suche in Google Scholar
11 Glover, K. M.; Borell, P.: J. Nucl. Energy1 (1955) 214Suche in Google Scholar
12 Glover, S. E.; Filby, R. H.; Clark, S. B.; Crytdal, S. P.: J. Radioanal. Chem.234 (1998) 21310.1007/BF02389774Suche in Google Scholar
13 Gruner, W.; Beutmann, A.; Lorenz, S.: Isotopenpraxis17 (1980) 385Suche in Google Scholar
14 Guyon, J. C.; Madison, B. L.: Mikrochimica Acta [Wien]I (1975) 13310.1007/BF01271530Suche in Google Scholar
15 Hallstadius, L.: Nucl. Instrum. Methods Phys. Res.223 (1984) 26610.1016/0167-5087(84)90659-8Suche in Google Scholar
16 Hao, L. C.; Tao, C. V.; Dong, N. V.; Nghi, H. N.; Thong, L.V.: Kerntechnik75 (2010) 381–38510.3139/124.110101Suche in Google Scholar
17 Heyn, A. H.; Soman, Y. D.: J. Inorg. Nucl. Chem26 (1964) 287–29510.1016/0022-1902(64)80072-5Suche in Google Scholar
18 IAEA/ AQ/ 18, 2010 (http://www-pub.iaea.org/MTCD/publications/PDF/IAEA-AQ-18_web.pdf).Suche in Google Scholar
19 Karamanis, D.; Ioannides, K. G.; Stamoulis, K.: Anal. Chim. Acta573–574 (2006) 319–32710.1016/j.aca.2006.03.024Suche in Google Scholar
20 Morvan, K.; Andres, Y.; Mokili, B.; Abbe, J.-C.: Analytical Chemistry73 (2001) 4218–422410.1021/ac0015220Suche in Google Scholar
21 Kehagia, K.; Potiriadis, D.; Bratakos, S.; Koukouliou, V.; Drikos, G.: Radiation Protection Dosimetry127 (2007) 293–29610.1093/rpd/ncm404Suche in Google Scholar
22 Kiliari, T.; Pashalidis, I.: Radiation Measurements. 45 (2010) 966–96810.1016/j.radmeas.2010.06.024Suche in Google Scholar
23 Kingston, H. M.; Haswell, S. J.: Chemistry. American Chemical Society, Washington DC, 1997Suche in Google Scholar
24 Lally, A.: In Uranium-Series Disequilibrium: Application to Earth, Marine, and Evironmental Science. 2nd edn.Clarendon Press, Oxford, 1992Suche in Google Scholar
25 Lee, M. H.; Lee, C. W.: Nucl. Instrum. Methods A447 (2000) 59310.1016/S0168-9002(99)01190-0Suche in Google Scholar
26 Maxmann, S. H.: Nucl. Instrum. Methods50 (1967)Suche in Google Scholar
27 Mirashi, N. N.; Mathur, J. N.; Satya, P.; Ramaniah, M. V.: Appl. Radiat. Isot.37 (1986) 35810.1016/0883-2889(86)90127-9Suche in Google Scholar
28 Murray, A. S.; Maten, R.; Johnston, A.; Martin, P.: J. Radioanal. Nucl. Chem. Articles115 (1987) 265Suche in Google Scholar
29 Roman, D. J.: Int. J. Appl. Radiat. Isot.35 (1984) 990–99210.1016/0020-708X(84)90221-7Suche in Google Scholar
30 Rose, W. J.; White, J. C.: USAEC Report ORNL-2627, 1958Suche in Google Scholar
31 Rose, W. J.; White, J. C.: Analyt. Chemistry. 31 (1959) 184710.1021/ac60155a050Suche in Google Scholar
32 Shabana, E. I.; Al-Hobaib, A. S.: Radiochim. Acta.87 (1999) 41–4510.1524/ract.1999.87.12.41Suche in Google Scholar
33 Sorret, C.; Tauveron, N.: Report CEA-R-4297, 1972Suche in Google Scholar
34 Singh, S. K.; Tripathi, S. C.; Singh, D. K.: Separation Science and Technology45 (2010) 824–83110.1080/01496391003607498Suche in Google Scholar
35 Surbeck, H.: Sci Total Environ.1 (1995) 173–174Suche in Google Scholar
36 Surbeck, H.: Applied Radiation and Isotopes53 (2000) 97–10010.1016/S0969-8043(00)00119-6Suche in Google Scholar
37 Talvitie, N.: Ana. Chem.44 (1972) 28010.1021/ac60310a013Suche in Google Scholar
38 Vdoenko, V. M; Dubasov, Yu. V.: Analytical Chemistry of Radium. Wiley, New York, 1975Suche in Google Scholar
39 Vera Tomé, F.; Martin Sánchez, A.: Appl. Radiat. Isot.42 (1991) 135–14010.1016/0883-2889(91)90062-6Suche in Google Scholar
40 Vesterbackca, P.; Ikaheimonen, T. K.: Anal. Chim. Acta.545 (2005) 252–26110.1016/j.aca.2005.04.074Suche in Google Scholar
41 Walsh, R. L.; Senior, I. F.: AAEC/E512, 1981Suche in Google Scholar
© 2011, Carl Hanser Verlag, München
Artikel in diesem Heft
- Contents/Inhalt
- Contents
- Summaries/Kurzfassungen
- Summaries
- Technical Contributions/Fachbeiträge
- Stress analyses for reactor pressure vessels by the example of a product line '69 Boiling Water Reactor
- Multiple condensation induced water hammer events, experiments and theoretical investigations
- Simulation of load following mode of operation for a natural circulation pressure tube type BWR
- CANDU fuel elements behaviour in the load following tests
- Local heat transfer coefficient near the spacer grids
- Best estimate analysis of PHEBUS FPT1 experiment bundle phase using ASTEC code ICARE module
- Investigations of bi-directional flow behaviour in presence of a large vertical opening in a fire compartment
- CANDU reactors with reactor grade plutonium/thorium carbide fuel
- Novel method to produce 109Cd via proton irradiation of electroplated silver on a gold-coated copper backing
- Technical Notes/Technische Mitteilungen
- Atmospheric dispersion of accidental release of radioactive gases from high enriched and low enriched fuel of Miniature Neutron Source Reactors (MNSR)
- Fuel burnup of modified fuel assembly configurations for a small medical reactor
- Determination of natural uranium, thorium and radium isotopes in water and soil samples by alpha spectroscopy
Artikel in diesem Heft
- Contents/Inhalt
- Contents
- Summaries/Kurzfassungen
- Summaries
- Technical Contributions/Fachbeiträge
- Stress analyses for reactor pressure vessels by the example of a product line '69 Boiling Water Reactor
- Multiple condensation induced water hammer events, experiments and theoretical investigations
- Simulation of load following mode of operation for a natural circulation pressure tube type BWR
- CANDU fuel elements behaviour in the load following tests
- Local heat transfer coefficient near the spacer grids
- Best estimate analysis of PHEBUS FPT1 experiment bundle phase using ASTEC code ICARE module
- Investigations of bi-directional flow behaviour in presence of a large vertical opening in a fire compartment
- CANDU reactors with reactor grade plutonium/thorium carbide fuel
- Novel method to produce 109Cd via proton irradiation of electroplated silver on a gold-coated copper backing
- Technical Notes/Technische Mitteilungen
- Atmospheric dispersion of accidental release of radioactive gases from high enriched and low enriched fuel of Miniature Neutron Source Reactors (MNSR)
- Fuel burnup of modified fuel assembly configurations for a small medical reactor
- Determination of natural uranium, thorium and radium isotopes in water and soil samples by alpha spectroscopy