Synthesis of graphene oxide with superhydrophilicity and well-defined sheet size distribution
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Xuebing Hu
Abstract
Graphene oxide exhibits many unique physicochemical properties and has been investigated widely in many areas. For the present contribution, graphene oxide, using flake graphite as a graphite precursor has been prepared by means of the modified Hummers method. By adjusting the oxidation processes, different graphene oxide products have been obtained. By characterizing the structure and performance of these graphene oxide products, it was discovered that graphene oxide prepared with a greater oxidant content and over a longer reaction time has a well-defined sheet size distribution and exhibits superhydrophilicity. The present work provides a simple method to control the sheet size distribution and the hydrophilicity of graphene oxide by simply adjusting the oxidation process.
References
1 D. R.Dreyer, A. D.Todd, C. W.Bielawski: Harnessing the chemistry of graphene oxide, Chemical Society Reviews43 (2014), No. 15, pp. 5288–530110.1039/C4CS00060ASearch in Google Scholar PubMed
2 X.Hu, Y.Yu, Z.Chen, X.Zhang, Y.Wang, J.Zhou: Efficient reduction of graphene oxide film by low temperature heat treatment and its effect on electrical conductivity, Materials Testing60 (2018), No. 1, pp. 102–10610.3139/120.111123Search in Google Scholar
3 F.Fan, B.Zhang, Y.Cao, X.Yang, J.Gu, Y.Chen: Conjugated polymer covalently modified graphene oxide quantum dots for ternary electronic memory devices, Nanoscale30 (2017), No. 9, pp. 10610–1061810.1039/C7NR02809ASearch in Google Scholar
4 F.Mindivan: Effect of various initial concentrations of CTAB on the noncovalent modified graphene oxide (MGNO) structure and thermal stability, Materials Testing59 (2017), No. 9, pp. 729–73410.3139/120.111063Search in Google Scholar
5 J.Abraham, K. S.Vasu, C. D.Williams, K.Gopinadhan, Y.Su, C. T.Cherian, J.Dix, E.Prestat, S. J.Haigh, I. V.Grigorieva, P.Carbone, A. K.Geim, R. R.Nair: Tunable sieving of ions using graphene oxide membranes, Nature Nanotechnology12 (2017), No. 6, pp. 546–55010.1038/nnano.2017.21Search in Google Scholar PubMed
6 M.Aleksandrzak, W.Kukulka, E.Mijowska: Graphitic carbon nitride/graphene oxide/reduced graphene oxide nanocomposites for photoluminescence and photocatalysis, Applied Surface Science398 (2017), pp. 56–6210.1016/j.apsusc.2016.12.023Search in Google Scholar
7 J.Feng, H.Dong, L.Yu, L.Dong: The optical and electronic properties of graphene quantum dots with oxygen-containing groups: a density functional theory study, Journal of Materials Chemistry C24 (2017), No. 5, pp. 5984–599310.1039/C7TC00631DSearch in Google Scholar
8 K.Hatakeyama, K.Awaya, M.Koinuma, Y.Shimizu, Y.Hakutaa, Y.Matsumoto: Production of water-dispersible reduced graphene oxide without stabilizers using liquid-phase photoreduction, Soft matter45 (2017), No. 13, pp. 8353–835610.1039/C7SM01386HSearch in Google Scholar
9 W.Du, M.Wu, M.Zhang, G.Xu, T.Gao, L.Qian, X.Yu, F.Chi, C.Li, G.Shi: Organic dispersions of graphene oxide with arbitrary concentrations and improved chemical stability, Chemical Communications80 (2017), No. 53, pp. 11005–1100710.1039/C7CC04584KSearch in Google Scholar
10 X.Hu, Y.Yu, W.Hou, J.Zhou, L.Song: Effects of particle size and pH value on the hydrophilicity of graphene oxide, Applied Surface Science273 (2013), pp. 118–12110.1016/j.apsusc.2013.01.201Search in Google Scholar
11 O. C.Compton, B.Jain, D. A.Dikin, A. l.Abouimrane, K.Amine, S. T.Nguyen: Chemically active reduced graphene oxide with tunable C/O ratios, Acs Nano5 (2011), No. 6, pp. 4380–439110.1021/nn1030725Search in Google Scholar PubMed
12 C. A.Amadei, P.Arribas, C. D.Vecitis: Graphene oxide standardization and classification: Methods to support the leap from lab to industry, Carbon133 (2018), pp. 398–40910.1016/j.apsusc.2013.01.201Search in Google Scholar
13 Y.Li, D. X.Luong, J.Zhang, Y. R.Tarkunde, C.Kittrell, F.Sargunaraj, Y.Ji, C. J.Arnusch, J. M.Tour: Laser-Induced Graphene in Controlled Atmospheres: From Superhydrophilic to Superhydrophobic Surfaces, New Carbon Materials28 (2017), No. 27, pp. 170049610.1002/adma.201700496Search in Google Scholar PubMed
14 Y.He, C.Tong, L.Geng, L.Liu, C.Lü: Enhanced performance of the sulfonated polyimide proton exchange membranes by graphene oxide: Size effect of graphene oxide, Journal of Membrane Science458 (2014), pp. 36–4610.1016/j.memsci.2014.01.017Search in Google Scholar
15 S.Türk, I.Altınsoy, G. Ç.Efe, M.Ipek, M.Özacar, C.Bindal: The effect of reduction of graphene oxide on the formation of hydroxyapatite and tricalcium phosphate, Vacuum148 (2018), pp. 1–1010.1016/j.vacuum.2017.10.037Search in Google Scholar
16 X.Hu, Y.Yu, J.Zhou, L.Song: Effect of graphite precursor on oxidation degree, hydrophilicity and microstructure of graphene oxide, Nano9 (2014), No. 3, pp. 1–810.1142/S1793292014500374Search in Google Scholar
17 K.Erickson, R.Erni, Z.Lee, N.Alem: Determination of the local chemical structure of graphene oxide and reduced graphene oxide, Advanced Materials40 (2010), No. 22, pp. 4467–447210.1002/adma.201000732Search in Google Scholar PubMed
18 X.Hu, Y.Yu, Y.Wang, J.Zhou, L.Song: Separating nano graphene oxide from the residual strong-acid filtrate of the modified Hummers method with alkaline solution, Applied Surface Science329 (2015), pp. 83–8610.1016/j.apsusc.2014.12.110Search in Google Scholar
19 S.Wang, Y.Dong, C.He, Y.Gao, N.Jia, Z.Chen, W.Song: The role of sp2/sp3 hybrid carbon regulation in the nonlinear optical properties of graphene oxide materials, RSC Advances84 (2017), No. 7, pp. 53643–5365210.1039/C7RA10505CSearch in Google Scholar
20 A.Sedrpoushan, M.Heidari, O.Akhavan: Nanoscale graphene oxide sheets as highly efficient carbocatalysts in green oxidation of benzylic alcohols and aromatic aldehydes, Chinese Journal of Catalysis38 (2017), No. 4, pp. 745–75710.1016/S1872-2067(17)62776-1Search in Google Scholar
21 D.Papkov, A.Goponenko, O. C.Compton, Z.An, A.Moravsky, X. Z.Li, S. T.Nguyen, Y. A.Dzenis: Improved Graphitic Structure of Continuous Carbon Nanofibers via Graphene Oxide Templating, Advanced Functional Materials46 (2013), No. 23, pp. 5763–577010.1002/adfm.201300653Search in Google Scholar
22 L.Zhang, J.Liang, Y.Huang, Y.Ma, Y.Wang, Y.Chen: Size-controlled synthesis of graphene oxide sheets on a large scale using chemical exfoliation, Carbon47(2009), No. 14, pp. 3365–336810.1016/j.carbon.2009.07.045Search in Google Scholar
23 Z.Li, W.Zhang, Y.Luo, J.Yang, J. G.Hou: How graphene is cut upon oxidation?Journal of the American Chemical Society131 (2009), No. 18, pp. 6320–632110.1021/ja8094729Search in Google Scholar PubMed
24 C. W.Lee, B. J.Min, S. I.Kim, H. K.Jeong: Stacking of water molecules in hydrophilic graphene oxides characterized by Kelvin probe force microscopy, Carbon54 (2013), pp. 353–35810.1016/j.carbon.2012.11.047Search in Google Scholar
25 T.Bharathidasan, S. V.Kumar, M. S.Bobji, R. P. S.Chakradhar, B. J.Basu: Effect of wettability and surface roughness on ice-adhesion strength of hydrophilic, hydrophobic and superhydrophobic surfaces, Applied Surface Science314 (2014), pp. 241–25010.1016/j.apsusc.2014.06.101Search in Google Scholar
© 2019, Carl Hanser Verlag, München
Articles in the same Issue
- Inhalt/Contents
- Contents
- Fachbeiträge/Technical Contributions
- Improved stress concentration factors for circular shafts for uniaxial and combined loading
- Constitutive modeling for high temperature compressive deformation of non-oriented electrical steel
- Microstructure and mechanical properties of a rotary friction welded tungsten heavy alloy
- Laser speckle photometry – Optical sensor systems for condition and process monitoring
- Bending behavior of sandwich structures with different fiber facing types and extremely low-density foam cores
- Effects of specimen dimensions and impact energy on energy absorption and damage of glass/epoxy composite plates
- Wear behavior of sansevieria cylindrica and E-glass reinforced polyester composites
- Synergistic effects of chemical finishing processes on comfort characteristics of micro-modal and lyocell knitted fabrics
- Inspection of defects in CFRP by improved magnetic induction tomography
- Effects of the drill flute number on drilling of a casted AZ91 magnesium alloy
- Limit load evaluation of inlet pigtail pipe bends with ovality under in-plane bending
- Synthesis of graphene oxide with superhydrophilicity and well-defined sheet size distribution
- Effects of induction hardened surface depth on the dynamic behavior of rotating shaft systems
- Tool condition monitoring in the milling process with vegetable based cutting fluids using vibration signatures
Articles in the same Issue
- Inhalt/Contents
- Contents
- Fachbeiträge/Technical Contributions
- Improved stress concentration factors for circular shafts for uniaxial and combined loading
- Constitutive modeling for high temperature compressive deformation of non-oriented electrical steel
- Microstructure and mechanical properties of a rotary friction welded tungsten heavy alloy
- Laser speckle photometry – Optical sensor systems for condition and process monitoring
- Bending behavior of sandwich structures with different fiber facing types and extremely low-density foam cores
- Effects of specimen dimensions and impact energy on energy absorption and damage of glass/epoxy composite plates
- Wear behavior of sansevieria cylindrica and E-glass reinforced polyester composites
- Synergistic effects of chemical finishing processes on comfort characteristics of micro-modal and lyocell knitted fabrics
- Inspection of defects in CFRP by improved magnetic induction tomography
- Effects of the drill flute number on drilling of a casted AZ91 magnesium alloy
- Limit load evaluation of inlet pigtail pipe bends with ovality under in-plane bending
- Synthesis of graphene oxide with superhydrophilicity and well-defined sheet size distribution
- Effects of induction hardened surface depth on the dynamic behavior of rotating shaft systems
- Tool condition monitoring in the milling process with vegetable based cutting fluids using vibration signatures