Aramid-HDPE Composites: Influence of Interface Adhesion Measured by T-peel Test on Tensile Properties
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Abstract
In this study, the influence of using compatibilizer as tie-layer between fiber matrix interfaces in continuous aramid fiber reinforced high density polyethylene (HDPE) composites was investigated. Maleic anhydride (MAH) grafted polyethylene and ethylene-methyl acrylate-glycidyl methacrylate (EMA-GMA) terpolymer were used as compatibilizers at varying layer numbers. Adhesion strength was determined by T-peel test, and tensile test was carried out. It was found that higher MFR (Melt Flow Rate) valued matrix and compatibilizer application increased the mechanical performance. The maximum strength values were obtained with EMA-GMA applications. In observations of peeled parts and cross-sectional slices, interface adhesion was investigated and failure patterns were determined. It was seen that the samples with compatibilizer had more wetted portions especially the EMA-GMA tie-layered ones.
Kurzfassung
In der vorliegenden Arbeit wurde der Einfluss von kompatibilitätsverbessernden Zwischenschichten zwischen Fasermatrix-Grenzflächen in Aramid-HDPE-Kompositen (High Density Polyethylen) untersucht. Es wurde hierzu ein mit Maleinsäureanhydrid (MAH) aufpolymerisiertes Polyethylen und Ethylen-methyl acrylat-glycidyl methacrylat (EMA-GMA) Terpolymer in verschiedenen Lagenanzahlen verwendet. Die Adhäsionskraft wurde mittels eines Winkelschälabzugtests untersucht, ebenso ein mechanischer Zugtest. Es konnte gezeigt werden, dass Materialien mit höherem Schmelzfluss Index (MFI) sowie der Einsatz von kompatibilitätsverbessernden Schichten mechanischen Eigenschaften verbessern. Die Maximalwerte wurden erreicht mit der Verwendung von EMA-GMA. Mit Hilfe von Untersuchung der abgeschälten Prüfkörper und Querschnittsproben wurde der Grenzflächenverbund analysiert und Schadensmuster bestimmt. Es konnte gezeigt werden, dass in Proben mit kompatibilitätsverbessernden Zusatzschichten mehr benetzte Anteile vorhanden waren, insbesondere bei den EMA-GMA-haltigen Materialien.
References
1 D. B.Miracle, S. L.Donaldson: ASM Handbook, vol. 21, ASM International, USA (2001), pp. 107–119Search in Google Scholar
2 S. K.Mazumdar: Composites Manufacturing: Materials, Product and Process, CRC Press LLC, USA (2002), p. 610.1201/9781420041989Search in Google Scholar
3 http://www.teijinaramid.com/wp-content/uploads/2012/02/1090308_Twaron-productbrochurefinal_051.pdf (access 2013)Search in Google Scholar
4 D.Rosato, D. V.Rosato: Reinforced plastics handbook, 3rd Ed., Elsevier Science & Technology Books, USA (2004), pp. 68–71Search in Google Scholar
5 M. P.Kruijer, L. L.Warnet, R.Akkerman: Analysis of the mechanical properties of a reinforced thermoplastic pipe (RTP), Composites Part A36 (2005), pp. 291–30010.1016/j.compositesa.2004.06.018Search in Google Scholar
6 http://www.soluforce.net/media/soluforce/Soluforce_Brochure_2012.pdf (access 2013)Search in Google Scholar
7 A. R.Offringa: Thermoplastic composites-rapid processing applications, Composites Part A27 (1996), pp. 329–33610.1016/1359-835X(95)00048-7Search in Google Scholar
8 A.Kelly, C. H.Zweben: Comprehensive composite materials, Pergamon Press, UK (2000), Vol. 2, pp. 979–998Search in Google Scholar
9 A. J.Peacock: Handbook of polyethylene structure, properties, and applications, Marcel Dekkel, Inc., USA (2000), pp. 375–41210.1201/9781482295467Search in Google Scholar
10 L. A.Utracki: Polymer blends handbook, Kluwer Academic Publishers, The Netherlands (2002), Vol. 1, pp. 1021–1035Search in Google Scholar
11 I.Ahmad, P. Y.Wong, I.Abdullah: Effects of fiber composition and graft-copoly (ethylene/maleic anhydride) on thermoplastic natural rubber composites reinforced by aramid fiber, Polym. Compos.27(4) (2006), pp. 395–40110.1002/pc.20225Search in Google Scholar
12 S. M.Lai, F. C.Yeh, Y.Wang, H. C.Chan, H. F.Shen: Comparative study of maleated polyolefins as compatibilizers for polyethylene/wood flour composites, J. Appl. Polym. Sci.87 (2003), pp. 487–49610.1002/app.11419Search in Google Scholar
13 S. N.Patankar, A.Das, Y. A.Kranova: Interface engineering via compatibilization in HDPE composite reinforced with sodium borosilicate hollow glass microspheres, Composites Part A40 (2009), pp. 897–90310.1016/j.compositesa.2009.04.016Search in Google Scholar
14 http://site2012.eurofibers.com/wp-content/uploads/2012/02/PDS-Twaron%C2%AE-2300.pdf (access 2013)Search in Google Scholar
15 https://www.daelimchem.co.kr/upload/e_LH4100.pdf (access 2013)Search in Google Scholar
16 http://www.arpc.ir/Portals/0/Pdf/Products/Ploymers/HDPE/I4.pdf (access 2013)Search in Google Scholar
17 http://www.admer.eu (access 2013)Search in Google Scholar
18 http://www.lotader.com/pdf/EN/products/technical_polymers/lotader/tds_lotader_ax8900_2010.pdf (access 2013)Search in Google Scholar
19 International Organization for Standardization: Adhesives – T-peel test for flexible-to-flexible bonded assemblies, ISO 11339, ISO, Geneva (2010)Search in Google Scholar
20 International Organization for Standardization: Plastics – Determination of tensile properties – Part 5: Test conditions for unidirectional fiber-reinforced plastic composites, ISO 527-5, ISO, Geneva (2009)Search in Google Scholar
21 International Organization for Standardization: Adhesives – Designation of main failure patterns, ISO 10365, ISO, Geneva (1992)Search in Google Scholar
22 C.Martin-Barrera, P. J.Gonzalez-Chi: Scaling effects on the mechanical performance of symmetrical and balanced thermoplastic laminates, Polym. Test.31 (2012), pp. 1053–106110.1016/j.polymertesting.2012.07.013Search in Google Scholar
23 R.Ou, H.Zhao, S.Sui, Y.Song, Q.Wang: Reinforcing effects of Kevlar fiber on the mechanical properties of wood-flour-/high-density-polyethylene composites, Composites Part A41 (2010), pp. 1272–127810.1016/j.compositesa.2010.05.011Search in Google Scholar
24 T.Amornsakchai, B.Sinpatanapan, S.Bualek-Limcharoen, W.Meesiri: Composite of aramid fiber (poly-m-phenyleneisophthalamide)-thermoplastic elastomers (SEBS): Enhancement of tensile properties by maleated SEBS compatibilizer, Polymer40 (1999), pp. 2993–299910.1016/S0032-3861(98)00524-2Search in Google Scholar
25 M.Arroyo, R.Zitzumbo, F.Avalos: Composite based on PP/EPDM blends and aramid short fibers: Morphology/behaviour relationship, Polymer41 (2000), pp. 6351–635910.1016/S0032-3861(99)00821-6Search in Google Scholar
© 2014, Carl Hanser Verlag, München
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Articles in the same Issue
- Inhalt/Contents
- Inhalt
- Fachbeiträge/Technical Contributions
- Environmental Effects on Mechanical Properties of Glass-Epoxy Composites
- The Effect of Borax on the Friction Performance of an Automotive Brake Lining
- Aramid-HDPE Composites: Influence of Interface Adhesion Measured by T-peel Test on Tensile Properties
- Prediction of Surface Roughness in Longitudinal Turning Process by a Genetic Learning Algorithm
- Effect of Rotation Speed on the Quality of Friction Welded AA 6061/AA 7075 Joints
- Detection of defects in metallic specimens supported by ultrasound propagation simulations
- Wear Properties of Fe-Cr-C and B4C Powder Coating on AISI 316 Stainless Steel Analyzed by the Taguchi Method
- Combustion Behaviour of Solid Propellants for Micro-Thruster
- Structure Optimization of the 2D Angular Rotation of a Micro/Nano Table Using the Interface between Matlab and ANSYS
- Indium Recovery by Selective Removal of Copper and Tin from ITO Etching Waste Solution by Cementation with Cobalt and Subsequent Electro-Winning: A Validation Experiment*
- Effectiveness of Coatings on the Corrosion Resistance of the External Surface of Concrete Structures
- Vorschau/Preview
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