Viscometric Studies of Cu(II) Surfactants Derived from Mustard Oil in Benzene at 303.15 K

Pragya Tank; Rashmi Sharma; Arun Kumar Sharma

doi:10.3139/113.110601

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Viscometric Studies of Cu(II) Surfactants Derived from Mustard Oil in Benzene at 303.15 K

Pragya Tank , Rashmi Sharma und Arun Kumar Sharma

Veröffentlicht/Copyright: 7. März 2019

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Aus der Zeitschrift Tenside Surfactants Detergents Band 56 Heft 2

Abstract

The viscosity, specific viscosity, and fluidity of Cu(II) surfactant complexes derived from mustard oil with urea/thiourea/2-amino-6-chloro benzothiazole in a non-aqueous solvent has been determined at a constant temperature of 303.15 K. The results were used to determine the critical micelle concentration (CMC), soap complex-solvent interactions and the effect of chain length of the surfactant molecule on various parameters. The conclusions with regard to solute-solute and solute-solvent interaction have been discussed in terms of well-known Moulik and Jones-Dole equations. The effect of surfactant concentration on the viscosity of the solution in non-polar solvent has been discussed. The observations suggested that the structure breaking effect by the solute on the solvent molecules is more prominent above CMC as compared to below CMC after the formation of the micelles. This information plays a role in various industrial and biological applications.

Kurzfassung

Die Viskosität, die spezifische Viskosität und die Fließfähigkeit von Cu(II)-Tensidkomplexen, wurden bei einer konstanten Temperatur von 303,15 K gemessen. Die Cu(II)-Tensidkomplexe wurden aus Senföl mit Harnstoff/Thioharnstoff/2-Amino-6-chlorbenzothiazol in einem nichtwässrigen Lösungsmittel erzeugt. Mit den Messergebnissen wurden die kritische Mizellenbildungskonzentration (CMC), die Wechselwirkungen zwischen dem Seifenkomplex und dem Lösungsmittel sowie die Wirkung der Kettenlänge des Tensidmoleküls auf verschiedene Parameter bestimmt. Die Schlussfolgerungen bezüglich der Wechselwirkungen von Gelöstem-Gelöstem und Gelöstem-Lösungsmittel wurden mit Hilfe der bekannten Gleichungen von Moulik und Jones-Dole diskutiert. Der Einfluss der Tensidkonzentration auf die Viskosität der Lösung in einem unpolaren Lösungsmittel wurde diskutiert. Die Beobachtungen legten nahe, dass der Strukturbruch des gelösten Stoffes an den Lösungsmittelmolekülen oberhalb von CMC im Vergleich zu unterhalb von CMC nach der Bildung der Mizellen stärker hervortritt. Diese Informationen spielen eine Rolle in verschiedenen industriellen und biologischen Anwendungen.

Key words: Cu(II) surfactant; mustard oils; benzothiazole; soap-solvent interaction; CMC; viscosity

Stichwörter: Cu(II)-Tensid; Senföle; Benzothiazol; Seifenlösungsmittelwechselwirkung; CMC; Viskosität

∗Correspondence address, Dr. Rashmi Sharma, Shastri Nagar, Ajmer-305001, Rajasthan, India, E-Mail: avinash_1965@yahoo.co.in

Dr. Pragya Tank, Associate Prof, in Department of Chemistry, S.P.C. Govt. College Ajmer-305001 (Rajasthan). She is M. Sc. Ph.D (Chemistry). Her Research interest is Physical chemistry, Surface chemistry, Colloidal chemistry, synthesis of surfactants. She published 10 papers in International and National journals. Her teaching and research experience is 10 years.

Dr. Rashmi Sharma, Associate Prof, in Department of Chemistry, S.P.C. Govt. College Ajmer-305001 (Rajasthan) India. She was born in 1969. She is M. Sc. Ph. D.(Chemistry). Her Research interest is Physical chemistry, Surface chemistry, Colloidal chemistry, synthesis of surfactants and their degradation by thermal and photochemical methods. She published 70 papers in International and National journals. Her teaching and research experience is 20 years. About 7 students awarded Ph. D degree in her supervision.

Dr. Arun Kumar Sharma, Guest Faculty, in Department of Pure and Applied chemistry, M.D.S. University Ajmer-305001 Raj. India. He was born in 1985. He is M. Sc. M.Phil. Ph. D.(Chemistry).P.G. Diploma in textile Chemistry, P.G. Diploma in Analytical Chemistry, CSIR SRF, CSIR-UGC NET (AIR-08/898), GATE-2013 (AIR-1395/11768). His Research interest is Physical chemistry, Surface chemistry, Colloidal chemistry, synthesis of surfactants, chemical kinetics, environmental chemistry etc. He published 60 papers in International and National journals. His research experience is 08 years. He presented his research work in 40 national and international conferences. He published 15 books in lambert Academic Publishing Germany and one chapter in Book by Intech publisher Croatia, two chapters in books by discovery publishers New Delhi India. He is awarded Prof. V. S. Tripathi Young Scientist Award by Indian Chemical Society Kolkata, in 47^th Annual convention of Chemists – 2010 & International conference on Recent Advances in Chemical Sciences at Pt. R.S. University, Raipur – (Chhattisgarh) India, Awarded international travel grant by CSIR, New Delhi to attend 2nd (ICBEC-2011) at Dubai, UAE in 2011 Best Performer Award by BARC-BRNS-AEACI-DAE in SAC-7 (7^th School on analytical chemistry) at Heavy Water Plant Manuguru A.P. India in 2013, Awarded Young Scientist award in National conference in frontiers of chemical sciences by PAHER University Udaipur associated by Indian Chemical Society Kolkata, India in 2016, awarded best association in kinetics award by ICS Kolkata in 54^th Annual convention of Chemists – 2017 at UTU Bardoli Surat Gujrat, India. He is life member of APCBEE, ISCA, AEACI.

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Received: 2017-08-10

Accepted: 2018-01-11

Published Online: 2019-03-07

Published in Print: 2019-03-15

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https://doi.org/10.3139/113.110601

Schlagwörter für diesen Artikel

Cu(II) surfactant; mustard oils; benzothiazole; soap-solvent interaction; CMC; viscosity