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Study on a Ternary Surfactant System of Disodium Hexadecyl Diphenyl Ether Disulfonate, Dodecyldimethyl Hydroxyethyl Ammonium Chloride and Fatty Alcohol Polyoxyethylene Ether

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Published/Copyright: March 9, 2018
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Tenside Surfactants Detergents
From the journal Tenside Surfactants Detergents Volume 55 Issue 2

Abstract

This study was focused on a ternary complex system composed of hexadecyl diphenyl ether disulfonate (C16-MADS), dodecyl dimethyl hydroxyethyl ammonium chloride (K3) and fatty alcohol polyoxyethylene ether (AEO9). The binary mixture C-K consisting of C16-MADS and K3 was investigated and the maximum synergism was obtained when the mole ratio was 0.33:0.67. Subsequently, AEO9 was added to the binary C-K complex system to investigate whether the behavior of the new complex system, in which C-K is thought to be a surfactant, can be explained by the theory of regular solution. The maximum synergism was achieved when the molar ratio of C-K and AEO9 was 7:3. The regular solution theory could well explain the synergism in mixed micelle formation and the synergism in surface tension reduction efficiency, but the synergism in surface tension reduction effectiveness did not match with the experimental data. So, there still exist some deficiencies in the application of the regular solution theory to a complex system of three surfactants.

Kurzfassung

Diese Studie konzentrierte sich auf ein ternäres Komplexsystem aus Hexadecyldiphenyletherdisulfonat (C16-MADS), Dodecyldimethylhydroxyethylammoniumchlorid (K3) und Fettalkoholpolyoxyethylenether (AEO9). Die binäre Mischung C-K aus C16-MADS und K3 wurde untersucht; der synergistische Effekt von C-K war am größten, wenn das Molverhältnis 0,33:0,67 betrug. Anschließend wurde AEO9 zu dem binären komplexen System C-K gegeben, um zu untersuchen, ob das Verhalten des neuen komplexen Systems, in dem C-K als ein Tensid angenommen wird, mit der Theorie der regulären Lösung erklärt werden kann. Der maximale Synergismus trat auf, wenn das Molverhältnis von C-K und AEO9 7:3 war. Die Theorie der regulären Lösung konnte den Synergismus bei der Bildung von Mischmizellen und den Synergismus bei der Verringerung der Oberflächenspannung gut erklären, aber die experimentellen Daten stimmten nicht mit der theoretischen Erklärung zum Synergismus bei der Verringerung der Oberflächenspannung überein. So gibt es noch einige Schwächen in der Anwendung der regulären Lösungstheorie auf ein komplexes System aus drei Tensiden.

Key words: Synergism; interaction; complex system; surface chemical properties; regular solution theory
Stichwörter: Synergismus; Interaktion; komplexes System; chemische Oberflächeneigenschaften; Theorie der regulären Lösung
*Correspondence address, Dr. Hujun Xu, Jiangnan University, School of Chemical and Material Engineering, Lihu Avenue, Wuxi 214122, P.R. China, Tel.: +86-13706180672, E-Mail: ,

Xiaobang Li and Zhenjun Ding are postgraduates at Jiangnan University and are involved in synthesis and analysis of surfactants.

Hujun Xu is an associate professor at Jiangnan University, P.R. China. He received his Ph.D. degree in 2005 from Nanjing University of Science and Technology, P.R. China. He has been involved in surfactants and detergents for over 30 years. He has published over 60 papers in the field of surfactants and detergents.

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Received: 2016-09-29
Accepted: 2017-03-16
Published Online: 2018-03-09
Published in Print: 2018-03-16

© 2018, Carl Hanser Publisher, Munich

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  2. Contents
  3. Short Communication
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  5. Application
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  7. Food-grade Water in Oil Microemulsion as a Potential Approach for Tea Polyphenols Encapsulation
  8. Physical Chemistry
  9. Aldehydes as Additives in AOT-based Microemulsions: Influence on the Electrical Percolation
  10. Study on a Ternary Surfactant System of Disodium Hexadecyl Diphenyl Ether Disulfonate, Dodecyldimethyl Hydroxyethyl Ammonium Chloride and Fatty Alcohol Polyoxyethylene Ether
  11. Synergistic Effect of Saponin and Rhamnolipid Biosurfactants Systems on Foam Behavior
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  15. Synthesis of a Gemini Betaine Surfactant and Its Properties as Foam Drainage Agent
  16. Synthesis and Evaluation of a New Trianionic Surfactant for the Removal of Pb(II) by Flotation Method
  17. Environmental Chemistry
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  19. Detergent Ingredients
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https://doi.org/10.3139/113.110554
Keywords for this article
Synergism; interaction; complex system; surface chemical properties; regular solution theory

Articles in the same Issue

  1. Contents/Inhalt
  2. Contents
  3. Short Communication
  4. Clouding Behaviour of Polysorbate 80: Effect of Additives
  5. Application
  6. Effect of Molecular Weight of Polymers on the Properties of Delicate Facial Foams
  7. Food-grade Water in Oil Microemulsion as a Potential Approach for Tea Polyphenols Encapsulation
  8. Physical Chemistry
  9. Aldehydes as Additives in AOT-based Microemulsions: Influence on the Electrical Percolation
  10. Study on a Ternary Surfactant System of Disodium Hexadecyl Diphenyl Ether Disulfonate, Dodecyldimethyl Hydroxyethyl Ammonium Chloride and Fatty Alcohol Polyoxyethylene Ether
  11. Synergistic Effect of Saponin and Rhamnolipid Biosurfactants Systems on Foam Behavior
  12. Ultrasonic Studies of Cu(II) Soaps Derived from Mustard and Soya Bean Oils
  13. Synthesis
  14. Synthesis, Properties and Application of Novel Ethylenediamine Triacetate Chelating Surfactants
  15. Synthesis of a Gemini Betaine Surfactant and Its Properties as Foam Drainage Agent
  16. Synthesis and Evaluation of a New Trianionic Surfactant for the Removal of Pb(II) by Flotation Method
  17. Environmental Chemistry
  18. Destabilization and Separation of Gas Condensate from Wastewater using Different Surfactant Demulsifiers
  19. Detergent Ingredients
  20. Foaming and Cleaning Performance Comparison of Liquid Detergent Formulations using Mixtures of Anionic and Nonionic Surfactants
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