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Properties of Cationic Choline-Derived Surfactant with Photolabile Cinnamate Counterion

  • Shili Song , Yabing Han , Wenli Hao , Jingwen Lu und Yuhua Qian
Veröffentlicht/Copyright: 6. Januar 2017
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Tenside Surfactants Detergents
Aus der Zeitschrift Tenside Surfactants Detergents Band 54 Heft 1

Abstract

A cationic choline-derived surfactant with photolabile cinnamate counterion (tetradecyl-(2-hydroxyethyl)-dimethylammoniumcinnamate, C14HDACin) was synthesized. The properties of C14HDACin aqueous solutions for pre- or post-UV irradiation were investigated by employing tensiometry, conductance, transmission electron microscopy (TEM) and rheometry. The effect of UV irradiation time on photoisomerization of C14HDACin solutions was evaluated, which showed that the photoisomerization efficiency decreases with an increase of C14HDACin concentration. After UV irradiation, the fraction of counterion binding (β) of the C14HDACin micelle decreases. However, the value of CMC increases. Rheometry coupled with TEM studies confirmed that the aggregation of C14HDACin could transform from wormlike to spherical micelles upon UV irradiation.

Kurzfassung

Es wurde ein kationisches Cholin-Derivat-Tensid einem fotolabilen Zimtsäureester-Gegenion (Tetradecyl-(2-hydroxyethyl)-dimethylammoniumcinnamat, C14HDACin) synthetisiert. Die Eigenschaften von wässrigen C14HDACin-Lösungen vor und nach der UV-Bestrahlung wurden tensiometrisch, über die Leitfähigkeit, mit der Transmissionselektronenmikroskopie (TEM) und der Rheometrie bestimmt. Der Einfluss der UV-Strahlungsdauer auf die Fotoisomerisation von C14HDACin-Lösungen wurde bewertet, wobei sich zeigte, dass die Wirksamkeit der Fotoisomerisation bei steigender C14HDACin-Konzentration abnimmt. Nach der UV-Bestrahlung ist der Anteil der Gegenionbindung (β) der C14HDACin-Mizellen gefallen. Jedoch, die CMC nimmt ebenfalls ab. Rheometrische Messungen in Verbindung mit den TEM-Untersuchungen bestätigen, dass durch die UV-Strahlung die wurmartigen C14HDACin-Mizellen sich zu Kugelmizellen umwandeln können.

Key words: Choline; cinnamate; viscoelasticity; photoisomerization
Stichwörter: Cholin; Zimtsäureester; Viskoelastizität; Fotoisomerisation
*Correspondence address, Prof. Dr. Shili Song, School of Chemistry and Chemical Engineering, Henan Normal University, 46# East of Construction Road, 453007 Xinxiang, P.R. China, Tel.: +863733326335, Fax: +863733326336, E-Mail:

Prof. Dr. Shili Song, associate Head of Applied Chemistry at Henan Normal University, is being engaged in teaching and scientific research work. His research interest encompasses both surface chemistry and biocatalysis, especially focused on novel surfactants synthesis and characterization.

Yabing Han is a master's candidate of Applied Chemistry at Henan Normal University.

Wenli Hao is a master's candidate of Applied Chemistry at Henan Normal University.

Jingwen Lu is a master's candidate of Applied Chemistry at Henan Normal University.

Yuhua Qian works as researcher and teaching assistant at the Department of chemical engineering and technology at Henan Normal University.

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Received: 2016-05-12
Accepted: 2016-09-13
Published Online: 2017-01-06
Published in Print: 2017-01-20

© 2017, Carl Hanser Publisher, Munich

Artikel in diesem Heft

  1. Contents/Inhalt
  2. Contents
  3. Editorial
  4. Review of the Year 2016
  5. Review
  6. Reaction Principle of Alcohol Ether Sulfonates by Sulfonated Alkylation Method – A Review
  7. Biosurfactants/Novel Surfactants
  8. Distribution Coefficients of Lipopeptide Biosurfactant in Different Solvents and its Separation from a Surfactant/Polymer Mixture in Aqueous Solutions
  9. Synthesis and Surface Properties of Anionic Vinylguaiacol Based Surfactants
  10. Novel Mesoporous ZSM-5 Zeolite with Disparate Morphologies Synthesized by a Double Long-alkyl-chain Organosilane Template
  11. Environmental Chemistry
  12. Preparation and Characterization of Glauber's Salt Microcapsules for Thermal Energy Storage
  13. Physical Chemistry
  14. Preparation and Characterization of a Humate Surfactant with Hydroxymethylation and Esterification Modification of Lignite
  15. Properties of Cationic Choline-Derived Surfactant with Photolabile Cinnamate Counterion
  16. Micellar Catalysis
  17. Solvent-Free Acetalization of Glycerol with n-Octanal using Combined Brønsted Acid-Surfactant Catalyst
  18. Synthesis
  19. Purification, Analysis and Surfactant Synthesis of Waste Cooking Oil
  20. Application
  21. Preparation and Properties of Novel Asymmetric Gemini Alkyl Polyglycosides
  22. Synthesis and Properties of Esterquats as Antibacterial Agent and Fabric Softener
https://doi.org/10.3139/113.110479
Schlagwörter für diesen Artikel
Choline; cinnamate; viscoelasticity; photoisomerization

Artikel in diesem Heft

  1. Contents/Inhalt
  2. Contents
  3. Editorial
  4. Review of the Year 2016
  5. Review
  6. Reaction Principle of Alcohol Ether Sulfonates by Sulfonated Alkylation Method – A Review
  7. Biosurfactants/Novel Surfactants
  8. Distribution Coefficients of Lipopeptide Biosurfactant in Different Solvents and its Separation from a Surfactant/Polymer Mixture in Aqueous Solutions
  9. Synthesis and Surface Properties of Anionic Vinylguaiacol Based Surfactants
  10. Novel Mesoporous ZSM-5 Zeolite with Disparate Morphologies Synthesized by a Double Long-alkyl-chain Organosilane Template
  11. Environmental Chemistry
  12. Preparation and Characterization of Glauber's Salt Microcapsules for Thermal Energy Storage
  13. Physical Chemistry
  14. Preparation and Characterization of a Humate Surfactant with Hydroxymethylation and Esterification Modification of Lignite
  15. Properties of Cationic Choline-Derived Surfactant with Photolabile Cinnamate Counterion
  16. Micellar Catalysis
  17. Solvent-Free Acetalization of Glycerol with n-Octanal using Combined Brønsted Acid-Surfactant Catalyst
  18. Synthesis
  19. Purification, Analysis and Surfactant Synthesis of Waste Cooking Oil
  20. Application
  21. Preparation and Properties of Novel Asymmetric Gemini Alkyl Polyglycosides
  22. Synthesis and Properties of Esterquats as Antibacterial Agent and Fabric Softener
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