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Foaming Behavior of Dialdehyde Starch Schiff-base Derivatives

  • Xiaojuan Wang , Shufen Zhang and Benzhi Ju
Published/Copyright: September 9, 2013
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Tenside Surfactants Detergents
From the journal Tenside Surfactants Detergents Volume 50 Issue 4

Abstract

A foamable dialdehyde starch-aniline Schiff-base (DAS-AN) was synthesized by the reaction of dialdehyde starch (DAS) and oil-soluble aniline in a homogeneous dimethyl sulfoxide system under N2 atmosphere. The DAS-ANs were characterized by gel permeation chromatography (GPC), Fourier-transform infrared spectroscopy (FT-IR) and NMR spectroscopy. Their foaming behavior and surface tension were investigated. Foaming power and stability tests were performed for solutions of DAS-ANs with different degrees of substitutions with aniline (DSAN) and concentrations. The maximum foaming power was 2.6 times the initial solution volume of the foam test in 450 mg · L–1 CaCO3 aqueous solution. The most stable foams only decreased by 6% in volume in deionized water after 20 min.

Kurzfassung

Eine verschäumbare Schiff’sche Base aus Dialdehydstärke und Anilin (DAS-AN) wurde durch Reaktion von Dial dehydstärke (DAS) mit öllöslichem Anilin im homogenen Dimethylsulfoxidsystem unter N2-Atmonsphäre erhalten. Die DAS-ANs wurde mit Hilfe von Gelpermeationschromatographie (GPC), Fourier-Transfom-IR-Spektroskopie (FT-IR) und der Kernspinresonanzspektroskopie (NMR) charakterisiert. Ihr Schaumverhalten und ihre Oberflächenspannung wurden untersucht. Tests zum Schaumvermögen und zur Stabilität wurde mit Lösungen durchgeführt, die DAS-AN mit verschiedenen Anilin-Substitutionsgraden (DSAN) und Konzentrationen enthielten. Das maximale Schaumvermögen betrug das 2,6-fache des ursprünglichen wässrigen Lösungsvolumens mit 450 mg L–1 CaCO3 im Schaumtest. Das Volumen der stabilsten Schäume in deionisiertem Wasser nahm nach 20 Minuten um nur 6% ab.

Key words: Dialdehyde starch-aniline Schiff-base; foaming behavior; surface activity
Stichwörter: Schiff’sche Base aus Dialdehydstärke und Anilin (DAS-AN); Schaumverhalten; Oberflächenaktivität
1 Prof. Benzhi Ju, State Key Lab of Fine Chemicals, Dalian University of Technology, Dalian 116024P.R. China, E-Mail:

Xiaojuan Wang was born in January 1983. She is a Ph.D student at Dalian University of Technology (China). Her main field of research is synthesis and physical chemistry of starch-based surfactants.

Shufen Zhang was born in April 1960. She is a Professor and is the director of the department of fine chemicals of Dalian University of Technology (China). Her focus is on the synthesis of surfactants and dyes, as well as their application.

Benzhi Ju, Professor, is teaching and working at Dalian University of Technology (China). His main field of research is the synthesis and application of starch-based surfactants and intelligent materials.

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Received: 2012-12-4
Revised: 2013-1-7
Published Online: 2013-09-09
Published in Print: 2013-07-15

© 2013, Carl Hanser Publisher, Munich

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https://doi.org/10.3139/113.110259
Keywords for this article
Dialdehyde starch-aniline Schiff-base; foaming behavior; surface activity

Articles in the same Issue

  1. Contents/Inhalt
  2. Contents
  3. Abstracts
  4. Abstracts
  5. Application
  6. Surface and Interfacial Performance of Unsaturated Octadecyl Carboxybetaine
  7. Synthesis of Thermoresponsive SiO2 Composite Modified by Nonionic Organosilicone Surfactant
  8. Combination of Best Promoter and Micellar Catalyst for Chromic Acid Oxidation of D-Mannitol to Mannose in Aqueous Media
  9. Antimicrobial Efficacy of Hygiene Rinsers under Consumer-Related Conditions
  10. Environmental Chemistry
  11. How Effective are Alternative Ways of Laundry Washing?
  12. Novel Surfactants
  13. Foaming Behavior of Dialdehyde Starch Schiff-base Derivatives
  14. Novel Diphenyl Methane Based Quaternary Ammonium Surfactants: Synthesis, Surface Properties and Antimicrobial Activity
  15. Physical Chemistry
  16. Interaction of Cationic CTAB Surfactant with Curcumin, an Anticarcinogenic Drug: Spectroscopic Investigation
  17. Parametric Optimization and Thermo-dynamic Studies on the Influence of Electrolytes on Sodium Salicylate in Aqueous Solution
  18. Effect of Cationic Surfactant on the Oxidation of Galactose by N-Bromophthalimide in the Presence of Acidic Medium: A Kinetic and Mechanistic Study
  19. News
  20. Retirement of Professor Ulrich Buller
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