Article
Licensed
Unlicensed Requires Authentication

Mixed Micellization and Surface Properties of Ionic Liquids/Triton X-100 Mixture System in Aqueous Media

  • , , and
Published/Copyright: August 16, 2013
Become an author with De Gruyter Brill
Submit Manuscript Author Information
Tenside Surfactants Detergents
From the journal Tenside Surfactants Detergents Volume 50 Issue 3

Abstract

Two binary systems of nonionic surfactant Triton X-100 and imidazolium ionic liquid surfactants with different carbon chain: C12mimBr (1-dodecyl-3-methylimidazolium bromide) and C14mimBr (1-tetradecyl-3-methylimidazoliumbromide) have been studied in this paper. The micellization and surface properties of the binary systems were determined by surface tension and conductivity methods, respectively. The critical micelle concentration (CMC), the maximum surface excess (Γmax), minimum area per molecule (Amin) and surface pressure at the CMC (ΠCMC) of single and mixed systems were obtained. Rubingh's theory was used to calculate the composition of the mixtures, and the molecular interaction parameter β. Negative value of β indicates synergism in mixed micelle formation. The order of absolute value of β and average β: C12mimBr/Triton X-100 > C14mimBr/Triton X-100. The values of ΔG0m and ΔG0ads have also been calculated, and both of them were found to be negative in all pure and mixed surfactants, indicating the spontaneity of micellization and adsorption of the surfactants.

Kurzfassung

In dieser Arbeit wurden zwei binäre Systeme aus dem nichtionischen Tensid Triton X-100 und ionischen Flüssigkeiten mit unterschiedlicher Kohenstoffkettenlänge (C12mimBr [1-Dodecyl-3-methylimidazoliumbromid] und C14mimBr [1-Tetradecyl-3-methylimidazoliumbromid]) untersucht. Die Mizellenbildung und die Oberflächeneigenschaften der binären Systeme wurden mit Hilfe von Oberflächenspannungs- und Leitfähigektismethoden bestimmt. Die kritische Miszellenbildungskonzentration (CMC), der maximale Oberflächenüberschuss (Γmax), der minimale Platzbedarf eines Moleküls (Amin) und der Oberflächendruck an der CMC (ΠCMC) des Mischsystems sowie der Einzelsystem wurden gemessen. Mit der Rubingh-Theorie wurden die Zusammensetzungen der Mischungen und der molekulare Wechselwirkungsparameter β berechnet. Negative β-Werte weisen auf Synergismen bei der Mischmizellenbildung hin. Die Reihenfolge der absoluten β- und der durchschnittlichen β-Werte ist: C12mimBr/Triton X-100 > C14mimBr/Triton X-100. Die Energien ΔG0m und ΔG0ads wurden ebenfalls berechnet. Beide waren für alle reinen und gemischten Tenside negativ, was auf eine spontane Mizellenbildung und Adsorption der Tenside hinweist.

Key words:: Nonionic surfactant; ionic liquids; critical micelle concentration; surface properties; synergism effect
Schlüsselwörter:: Nichtionisches Tensid; ionische Flüssigkeit; kritische Mizellbildungskonzentration; Oberflächeneigenschaften; synergistischer Effekt
* Correspondence address, Genxiang Luo, Department of Chemistry, School of Chemistry and Materials Science, Liaoning Shihua University, 113001, P. R. China, Tel.: +86-24-56 86 05 48, Fax: +86-24-56 86 05 48, E-Mail:

Lei Sun is a postgraduate student of analytical chemistry at Liaoning Shihua University. Her current research involves synthesis and surface properties of the ionic liquid surfactants.

Chunyu Han studied analytical chemistry at Liaoning Shihua University where he received his master's degree in 2008. He then joined the group of Prof. Genxiang Luo. He is currently working as an associate professor in the chemistry department at Liaoning Shihua University. His research involves the synthesis and characterization of surfactants.

Chunsheng Liu is an associate professor at the Liaoning Shihua University. His areas of interest are the synthesis and application of surfactants.

Genxiang Luo is a Professor at Liaoning Shihua University. His primary research field is colloid and surfactants. His current research involves the synthesis and surface properties of the ionic liquid surfactants.

References

1. Haque, M. E., Das, A. R., Rakshit, A. K. and Moulik, S. P.: Langmuir12 (1996) 4084. 10.1021/la9403587Search in Google Scholar

2. Rosen, M. J.: Prog. Colloid Polym. Sci.95 (1994) 39. 10.1007/BFb0115697Search in Google Scholar

3. Ingram, B. T.: Colloid. Polym. Sci.258 (1980) 191. 10.1007/BF01498280Search in Google Scholar

4. Szymczyk, K., Zdziennicka, A. and Janczuk, B.: Colloids and surf. A264 (2005) 147. 10.1016/j.colsurfa.2005.04.023Search in Google Scholar

5. Joshi, T., Bharatiya, B. and Kuperkar, K.: J. Dispersion Sci. Technol.29 (2008) 351. 10.1080/01932690701716069Search in Google Scholar

6. Singh, K. and Marangoni, D. G.: J. Colloid Interface Sci.315 (2007) 620. 10.1016/j.jcis.2007.06.062Search in Google Scholar PubMed

7. Akbas, H., Iscan, M. and Sidim, T.: J. Surfactants Deterg.3 (2000) 77. 10.1007/s11743-000-0117-0Search in Google Scholar

8. Sehgal, P., Kosaka, O. and Doe, H.: J. Dispersion Sci. Technol.30 (2009) 1050. 10.1080/01932690802598838Search in Google Scholar

9. Dong, B., Zhao, X. Y. and Zheng, L. Q.: Colloids and Surf. A317 (2007) 666. 10.1016/j.colsurfa.2007.12.001Search in Google Scholar

10. Jungnickel, C., Luczak, J. and Ranke, J.: Colloids Surf. A316 (2008) 278. 10.1016/j.colsurfa.2007.09.020Search in Google Scholar

11. Luczak, J., Hupka, J. and Thoming, J.: Colloids Surf. A329 (2008) 125. 10.1016/j.colsurfa.2008.07.012Search in Google Scholar

12. Zhang, H., Li, K. and Liang, H.: Colloids Surf. A329 (2008) 75. 10.1016/j.colsurfa.2008.06.046Search in Google Scholar

13. Hisham, J. Y.: J. Dispersion Sci. Technol.30 (2009) 1277. 10.1080/01932690902735207Search in Google Scholar

14. Inoue, T., Ebina, H. and Dong, B.: J. Colloid Interface Sci.314 (2007) 236. 10.1016/j.jcis.2007.05.052Search in Google Scholar PubMed

15. Vora, S., George, A. and Desai, H.: J. Surfactants Deterg.2 (1999) 213. 10.1007/s11743-999-0076-5Search in Google Scholar

16. Gandhi, H., Modi, S. and Jain, N.: J. Surfactants Deterg.4 (2001) 359. 10.1007/s11743-001-0188-ySearch in Google Scholar

17. Das, C., Chakraborty, T. and Ghosh, S.: Colloid Polym. Sci.286 (2008) 1143. 10.1007/s00396-008-1876-0Search in Google Scholar

18. Mukherjee, S., Mitra, D. and Bhattacharya, S. C.: Colloid J.71 (2009) 667. 10.1134/S1061933X09050147Search in Google Scholar

19. Javadian, S., Gharibi, H. and Bromand, Z.: J. Colloid Interface Sci.318 (2008) 449. 10.1016/j.jcis.2007.11.005Search in Google Scholar PubMed

20. Safavi, A., Abdollahi, H. and Maleki, N.: J. Colloid Interface Sci.322 (2008) 274. 10.1016/j.jcis.2008.01.059Search in Google Scholar PubMed

21. Blesic, M., Marques, M. H. and Plechkova, N. V.: Green Chem.9 (2007) 481. 10.1039/b615406aSearch in Google Scholar

22. Smirnova, N. A., Vanin, A. A. and Safonova, E. A.: J. Colloid Interface Sci.336 (2009) 793. 10.1016/j.jcis.2009.04.004Search in Google Scholar PubMed

23. Mukai, T., Yoshio, M., Kato, T., Yoshizawa, M. and Ohno, H.: Chem. Commun.10 (2005) 1333. 10.1039/b414631jSearch in Google Scholar PubMed

24. Khatua, P.K., Ghosh, S. and Ghosh, S. K.: J. Dispersion Sci. Technol.25 (2004) 741. 10.1081/DIS-200035501Search in Google Scholar

25. Ray, B.G., Chakraborty, I. and Ghosh, S.: Colloid. Polym. Sci.285 (2007) 457.Search in Google Scholar

26. Wang, S. Q. and Ma, J. P.: J. Dispersion Sci. Technol.30 (2009) 1395. 10.1080/01932690902735587Search in Google Scholar

27. Behera, K., Dahiya, P. and Pandey, S.: J. Colloid Interface Sci.307 (2007) 235. 10.1016/j.jcis.2006.11.009Search in Google Scholar PubMed

28. Kumar, B., Tikariha, D. and Ghosh, K. K.: J. Dispersion Sci. Technol.33 (2012) 265. 10.1080/01932691.2011.561178Search in Google Scholar

29. Rehman, N., Mir, M. A. and Jan, M.: J. Surfactants Deterg.12 (2009) 295. 10.1007/s11743-009-1123-9Search in Google Scholar

30. Jinlong, L., Feng, C. and Minhong, X.: Acta Chim. Sinica69 (2011) 2658.Search in Google Scholar

Received: 2012-10-28
Published Online: 2013-08-16
Published in Print: 2013-05-15

© 2013, Carl Hanser Verlag, Munchen

Articles in the same Issue

  1. Contents/Inhalt
  2. Contents
  3. Abstracts
  4. Abstracts
  5. Review Article
  6. Cost Effective Procedures for Extremely Efficient Synthesis of Environmental Friendly Surfactants
  7. Application
  8. Research the Oil Displacing Performance of Dodecyl Polyoxyethylene Ether Sulfonates at Difficult Conditions
  9. Research on Surfactant Flooding in High-temperature and High-salinity Reservoir for Enhanced Oil Recovery
  10. Environmental Chemistry
  11. Determination of Polyaromatic Hydrocarbons in Domestic, Commercial and Industrial soot samples
  12. Physical Chemistry
  13. Effect of Oil/Water Mass Ratios on the Composition and Solubilization of Microemulsion Systems Containing Tween/Alcohol/Alkane/NaCl Solution
  14. Properties of Binary Surfactant System of Alkyl Polyglycosides and α-Sulphonated Fatty Acid Methyl Ester
  15. Mixed Micellization and Surface Properties of Ionic Liquids/Triton X-100 Mixture System in Aqueous Media
  16. Preparation and Application of Cationic Surfactant Ion-selective Electrode
  17. Novel Surfactants
  18. Synthesis and Properties of Monododecyl Diphenyl Methane Disulfonate
  19. Technical Chemistry
  20. The Wettability Alteration Behavior of Cationic Gemini Surfactants on Oil-aged Mica Mineral Surfaces
https://doi.org/10.3139/113.110249
Keywords for this article
Nonionic surfactant; ionic liquids; critical micelle concentration; surface properties; synergism effect

Articles in the same Issue

  1. Contents/Inhalt
  2. Contents
  3. Abstracts
  4. Abstracts
  5. Review Article
  6. Cost Effective Procedures for Extremely Efficient Synthesis of Environmental Friendly Surfactants
  7. Application
  8. Research the Oil Displacing Performance of Dodecyl Polyoxyethylene Ether Sulfonates at Difficult Conditions
  9. Research on Surfactant Flooding in High-temperature and High-salinity Reservoir for Enhanced Oil Recovery
  10. Environmental Chemistry
  11. Determination of Polyaromatic Hydrocarbons in Domestic, Commercial and Industrial soot samples
  12. Physical Chemistry
  13. Effect of Oil/Water Mass Ratios on the Composition and Solubilization of Microemulsion Systems Containing Tween/Alcohol/Alkane/NaCl Solution
  14. Properties of Binary Surfactant System of Alkyl Polyglycosides and α-Sulphonated Fatty Acid Methyl Ester
  15. Mixed Micellization and Surface Properties of Ionic Liquids/Triton X-100 Mixture System in Aqueous Media
  16. Preparation and Application of Cationic Surfactant Ion-selective Electrode
  17. Novel Surfactants
  18. Synthesis and Properties of Monododecyl Diphenyl Methane Disulfonate
  19. Technical Chemistry
  20. The Wettability Alteration Behavior of Cationic Gemini Surfactants on Oil-aged Mica Mineral Surfaces
Downloaded on 9.4.2026 from https://www.degruyterbrill.com/document/doi/10.3139/113.110249/html
Scroll to top button