An Advanced Method for the Preparation of Erucyl Dimethyl Amidopropyl Betaine and Acid Solution Properties

Hongsheng Lu; Xuan Zhang; Hongping Quan; Shanshan Dai; Tailiang Zhang; Zhiyu Huang

doi:10.3139/113.110215

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An Advanced Method for the Preparation of Erucyl Dimethyl Amidopropyl Betaine and Acid Solution Properties

Hongsheng Lu , Xuan Zhang , Hongping Quan , Shanshan Dai , Tailiang Zhang und Zhiyu Huang

Veröffentlicht/Copyright: 5. April 2013

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Aus der Zeitschrift Tenside Surfactants Detergents Band 49 Heft 6

Abstract

In this paper, an improved method for the preparation of erucyl dimethyl amidopropyl betaine (EDAB) was provided. The synthesis conditions were investigated. N,N-dimethyl-N′-erucyl-1,3-propylenediamine was synthesized by the reaction of erucic acid with N,N-dimethyl-1,3-propylenediamine at 170°C for 7 h, and then the intermediate was reacted with sodium chloroacetate in the mixture of methanol and water (3:7 v/v) at 60°C. The product was obtained after 6 h. The compounds were confirmed by IR and ¹H-NMR. The properties of EDAB acid solution were also studied. The results indicated that viscosity of acid solution increased with decreasing hydrochloric acid concentration and was mainly controlled by surfactant concentration and temperature. The viscosity of an acid solution was maximum when the concentration of hydrochloric acid was at 15 wt%.

Kurzfassung

In diesem Manuskript wird eine verbesserte Methode zur Herstellung von Erucyldimethylamidopropylbetain (EDAB) vorgestellt. Die Synthesebedingungen wurden untersucht. N,N-Dimethyl-N′-erucyl-1,3-propylenediamin wurde erzeugt, in dem man Erucasäure mit N,N-Dimethyl-1,3-propylenediamin 7 Stunden bei 170°C reagieren ließ. Das Zwischenprodukt wurde dann bei 60°C mit Natriumchloracetat in einer Lösemittelmischung aus Methanol und Wasser (3:7, v/v) umgesetzt. Nach 6 Stunden erhielt man das Endprodukt. Die Verbindungen wurden mittels IR und ¹H-NMR bestätigt. Die Eigenschaften der sauren EDAB-Lösung wurden auch untersucht. Die Ergebnisse zeigten, dass die Viskosität der sauren Lösung mit abnehmender Salzsäurekonzentration zunahm. Sie wurde hauptsächlich von der Tensidkonzentration und der Temperatur kontrolliert. Bei einer Salzsäurekonzentration von 15 w% trat ein Viskositätsmaximium der sauren Lösung auf.

Key words:: Erucylamidopropyl betaine; synthesis; viscoelastic surfactant

Stichwörter:: Erucyldimethylamidopropylbetain; Synthese; viskoelastisches Tensid

^∗ Mr. Xuan Zhang, School of Chemistry and Chemical Engineering, Southwest Petroleum University, Xindu, Sichuan 610500, P.R. China, E-Mail: zx85917@hotmail.com

Dr Hongsheng Lu is currently a teacher at the College of Chemistry and Chemical Engineering, Southwest Petroleum University. He received his Ph.D. in Chengdu Institute of Organic Chemistry of Chinese Academy of Sciences. His research interests include synthesis and application of oil chemicals.

Mr. Xuan Zhang is currently a M.D. candidate at the College of Chemistry and Chemical Engineering, Southwest Petroleum University. His main research is synthesis of viscoelastic surfactant using in acidizing stimulation.

Dr. Hongping Quan is currently a teacher at the College of Chemistry and Chemical Engineering, Southwest Petroleum University. He received his Ph.D. in Applied Chemistry at the College of Chemistry and Chemical Engineering, Southwest Petroleum University. His research interests include synthesis and application of oil chemicals.

Dr. Shanshan Dai is currently a teacher at the College of Chemistry and Chemical Engineering, Southwest Petroleum University. She received her Ph.D. in the College Polymer Science and Engineering in Sichuan University. Her research interests include synthesis and application of oil chemicals.

Dr. Tailiang Zhang is currently a teacher at the College of Chemistry and Chemical Engineering, Southwest Petroleum University. He received his Ph.D. in Applied Chemistry at the College of Chemistry and Chemical Engineering, Southwest Petroleum University. His research interests include synthesis and application of oil chemicals.

Prof. Zhiyu Huang is currently the director of Graduate School, Southwest Petroleum University. He received his Ph.D. in Applied Chemistry at the College of Chemistry and Chemical Engineering, Southwest Petroleum University. His research interests include synthesis and application of oil chemicals.

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Received: 2012-02-01

Revised: 2012-05-19

Published Online: 2013-04-05

Published in Print: 2012-11-01

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https://doi.org/10.3139/113.110215

Schlagwörter für diesen Artikel

Erucylamidopropyl betaine; synthesis; viscoelastic surfactant