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Electrical Properties of PANI/Chalcogenide Junctions Doped with Ionic Liquids Anions

  • Abdelkader Benabdellah , El-Habib Belarbi , Hocine Ilikti , Mustapha Hatti and Bekhaled Fettouhi
Published/Copyright: March 1, 2013
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Tenside Surfactants Detergents
From the journal Tenside Surfactants Detergents Volume 49 Issue 3

Abstract

Ionic liquids like 1-butyl-3-methylimidazolium chloride ([BMIM] Cl, 1-butyl-3-methyl-imidazolium hexafluorophosphate [BMIM] PF6, 1-butyl-3-methyl-imidazolium tetrafluorobrate [BMIM] BF4, 1-butyl-3-methyl-imidazolium bis (trifluoromethylsulfonyl) imide [BMIM] NTf2) were used as doping elements in polyaniline. Pure polyaniline (EB) and polyaniline doped with different anions of ionic liquids (ESs) were chemically synthesized using ammonium peroxydisulphate (APS) and ionic liquids as oxidants. Junctions have been prepared by evaporating chalcogenide materials (ZnSe, CdSe) on conducting polyaniline (EB & ESs) pellets using a vacuum evaporation technique. I-V characteristics of junctions have been studied at room temperature using the Keithley electrometer 6517A. I-V measurements show the rectification effect. A junction of ES [BF4−] anion may be preferred over the other junctions due to its low ideality factor and maximum rectification ratio.

Kurzfassung

Ionische Flüssigkeiten wie 1-Butyl-3-methylimidazoliumchlorid ([BMIM] Cl, 1-Butyl-3-methylimidazoliumhexafluorophosphat [BMIM] PF6, 1-Butyl-3-methylimidazolium tetrafluorobrat [BMIM] BF4, und 1-Butyl-3-methylimidazolium-bis-(trifluoromethylsulfonyl) imid [BMIM] NTf2 wurden eingesetzt, um Polyanilin zu dotieren. Reines Polyanilin (EB) und Polyanilin, das mit verschiedenen Anionen ionischer Flüssigkeiten dotiert wurde, wurden mit Ammoniumperoxidisulfat (APS) und ionischen Flüssigkeiten synthetisiert. Die Übergänge wurden erzeugt, indem Chalkogenide (ZnSe, CdSe) auf leitende Polyanilinpelltes (EB uns ESs-Pellets) mit der Vakuumverdampfung aufgedampft wurden. Die Charakteristika der I-V-Übergänge wurden bei Raumtemperatur mit einem Keithlyelektrometer 6517A untersucht. Die I-V-Messungen zeigten einen Rektifikationseffekt. Ein Übergang von ES [BF4−]-Anionen scheint wegen des geringen Idealitätsfaktors und der maximalen Rektifikationsgeschwindigkeit gegenüber andern Übergängen bevorzugt zu sein.

Key words:: Emeraldine base (EB); emeraldine salt (ESs); ionic liquids; chalcogenide material; p-n junction; PANI
Stichwörter:: Emeraldinebase (EB); Emeraldinesalz (ES); ionische Flüssigkeiten; Chalkogenide; p-n-Übergang; PANI
4 Dr. A. Benabdellah, Synthesis and Catalysis Laboratory, Ibn Khaldoun University of Tiaret, 14000 Tiaret, Algeria. E-mail:

Dr. Abdelkader Benabdellah was born in juin 1979. He completed his Post Graduation in 2003 after completing his Magister 2006 and Doctorate in 2011 from University of Sciences and Technology Oran (Algeria). At present he is working as a research professor at Ibn Khaldun University of Tiaret (Algeria). His area of research is “electrical systems based on conducting polymers and ionic liquids”.

Dr. El-Habib Belarbi was born in 1965. He completed his Post Graduation in 1990. After completing his Ph.D. in 1997 from Montpellier II University France, he worked as Associate Professor in the Department of physics of Ibn Khaldoun University. At present he is working as full Professor and Dean of college of science and technology and materials science, Ibn Khaldoun University, Tiaret, (Algeria). His area of research is “electrical systems based on conducting polymers and ionic liquids”.

Dr. Hocine Ilikti was born in July 1958. He completed his Post Graduation in 1985. After completing his Magister 1992 and Doctorat in 2004 from University of sciences and technology Oran Algeria and University of Claude BERNARD, Lyon, France, He is at present working as Professor in University of sciences and technology Oran Algeria. His area of research is “electrocatalytic hydrogenation of electrodes modifying by conductor polymers”.

Dr. Mustapha Hatti was born in November 1960. He completed his Post Graduation in 1988 after completing his Magister 2006 and Doctorat in 2010 from University of sciences and technology Oran (Algeria). At present he is working as Head of Division at Solar Equipment Development Unit, Bou Ismail, Tipaza, (Algeria). His area of research is “control and management of hybrid energy systems and fuel cells”.

Dr. Bekhaled Fettouhi was born in February 1976. He completed his Post Graduation in 2001. He obtained his Magister in 2005 from Ibn Khaldun University of Tiaret. (Algeria). At present he is working as a research professor at the Ibn Khaldun University of Tiaret (Algeria). He is preparing his PhD thesis at the University of Paul Verlaine of Metz (France). His area of research is “extraction of heavy metals in ionic liquids”.

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Received: 2011-07-03
Revised: 2012-01-22
Published Online: 2013-03-01
Published in Print: 2012-05-01

© 2012, Carl Hanser Publisher, Munich

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https://doi.org/10.3139/113.110188
Keywords for this article
Emeraldine base (EB); emeraldine salt (ESs); ionic liquids; chalcogenide material; p-n junction; PANI

Articles in the same Issue

  1. Contents/Inhalt
  2. Contents
  3. Abstracts
  4. Abstracts
  5. 7th European Detergents Conference (EDC)
  6. Biosurfactants as Antimicrobial Ingredients for Cleaning Products and Cosmetics
  7. Scientific Results and Economic Effects from the Centre for Surfactants Based on Natural Products (SNAP)
  8. Application
  9. Preparation and Performance of Catanionic Surfactants
  10. Environmental Chemistry
  11. Acrylic Acid-Allylpolyethoxy Carboxylate Copolymer Dispersant for Calcium Carbonate and Iron(III) Hydroxide Scales in Cooling Water Systems
  12. Novel Surfactants
  13. Lyotropic Liquid Crystals Formed in Brij35/Copolymer/Water System
  14. Physical Chemistry
  15. Micellization of Alkyl Trimethyl Ammonium Bromides in Aqueous Solutions–Part 1: Critical Micelle Concentration (CMC) and Ionization Degree
  16. Review
  17. Electrical Properties of PANI/Chalcogenide Junctions Doped with Ionic Liquids Anions
  18. Synthesis
  19. Synthesis of Quaternary Derivatives of Ortho-Coco Di-Amido Toluene and Investigation of these Compounds as Cationic Bitumen Emulsifier
  20. Synthesis and Surface Activity of Guerbet Betaine Surfactants with Ethylene Oxide Groups
  21. Research Group Portrait
  22. Investigations in the Stranski-Laboratorium of the TU Berlin – Physical Chemistry of Colloidal Systems – Going Towards Complexity and Functionality
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