Reverse Phase HPLC Analysis of Commercial Surfactants used as Melt Additives
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V. M. Datla
, K. Beck , E. Shim and B. Pourdeyhimi
Abstract
Reverse phase HPLC (High Performance Liquid Chromatography) was used to analyze the length distribution of polyoxyethylene (POE) chains in commercial surfactants that can be used as melt additives for hydrophilic polypropylene surface modification. Ten nonionic surfactants including ethoxylated alcohols, nonyl phenols and amines, PEG esters, and mono glycerides were investigated. HPLC methods described herein are capable of analyzing ethoxylated nonionic surfactants and offer the advantage of separating the components in surfactants according to both the hydrophobe and hydrophile chain length. Moreover, the method is rapid and gradient elution allows for good baseline separation of the several components in the additives.
Kurzfassung
Zur Analyse der Kettenlängenverteilung von Polyoxyethylengruppen (PEO) in kommerziellen Tensiden, die als Schmelzadditive zur Modifikation der hydrophilen Polypropylenoberflächen eingesetzt werden, wurde die Umkehrphasenhochleistungschromatographie (RP-HPLC) verwendet. Zehn nichtionische Tenside, einschließlich ethoxilierter Alkohole, Nonylphenole und Amine, PEG-Ester und Monoglyceride, wurden untersucht. Die hier beschriebenen HPLC-Methoden sind für die Analyse ethoxylierter nichtionischer Tenside geeignet und bieten den Vorteil, dass eine Trennung der hydrophoben und hydrophilen Anteile der Tenside möglich ist. Darüber hinaus handelt es sich um eine schnelle Methode. Die Graduentenelution erlaubt aufgrund der guten Basislinie eine Auftrennung verschiedener Komponenten in den Additiven.
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© 2010, Carl Hanser Publisher, Munich
Articles in the same Issue
- Contents/Inhalt
- 10.3139/113.100302
- Abstracts
- 10.3139/113.100304
- Analysis
- Reverse Phase HPLC Analysis of Commercial Surfactants used as Melt Additives
- Application
- Branched Alkyl Alcohol Propoxylated Sulfate Surfactants for Improved Oil Recovery
- Novel Surfactants
- Micellization of Gemini Surfactants in Polymer Solutions
- Physical Chemistry
- Properties of Microemulsions with Mixed Nonionic Surfactants and Mint Oil
- Adsorption and Desorption of Ionic Surfactants
- Sizes and Anisometricity of Micelles in Lyotropic Liquid Crystalline Mesophases: Sodium Lauryl Sulphate/Water/Decanol Lyotropic System
- Studies on Acoustic and Thermodynamic Behaviour of Terbium Laurate and Myristate in Mixed Organic Solvents
- Overview
- Nonionic Surfactants: An Overview
Articles in the same Issue
- Contents/Inhalt
- 10.3139/113.100302
- Abstracts
- 10.3139/113.100304
- Analysis
- Reverse Phase HPLC Analysis of Commercial Surfactants used as Melt Additives
- Application
- Branched Alkyl Alcohol Propoxylated Sulfate Surfactants for Improved Oil Recovery
- Novel Surfactants
- Micellization of Gemini Surfactants in Polymer Solutions
- Physical Chemistry
- Properties of Microemulsions with Mixed Nonionic Surfactants and Mint Oil
- Adsorption and Desorption of Ionic Surfactants
- Sizes and Anisometricity of Micelles in Lyotropic Liquid Crystalline Mesophases: Sodium Lauryl Sulphate/Water/Decanol Lyotropic System
- Studies on Acoustic and Thermodynamic Behaviour of Terbium Laurate and Myristate in Mixed Organic Solvents
- Overview
- Nonionic Surfactants: An Overview