Home Synthesis and Characterization of a Series of Novel Anionic Fumaric Polymerizable Surfactants
Article
Licensed
Unlicensed Requires Authentication

Synthesis and Characterization of a Series of Novel Anionic Fumaric Polymerizable Surfactants

  • M. Zhu , W. Qiao , Y. Sun , H. Liu and Z. Li
Published/Copyright: March 30, 2013
Become an author with De Gruyter Brill
Author Information
Tenside Surfactants Detergents
From the journal Tenside Surfactants Detergents Volume 44 Issue 4

Abstract

A series of novel anionic fumaric polymerizable surfactants with different lengths of carbon chains (C8–C14) were synthesized. The chemical structure of the surfactants was confirmed by 1H NMR, IR and MS. The values of critical micellar concentration (cmc) and γcmc of the surfactants were determined. The surface properties of this series of designed polymerizable surfactants show their potential application in the emulsion polymerization to improve the stability of the latices and water sensitivity of the films.

Kurzfassung

Eine Reihe von neuartigen anionischen fumarpolymerisierbaren Tensiden mit unterschiedlicher Kohlenstoffkettenlänge (C8–C14) wurde synthetisiert. Die chemische Struktur der Tenside wurde durch 1H NMR, IR und MS bestätigt. Die Werte der kritischen Mizellbildungskonzentration (cmc) und γcmc der Tenside wurden bestimmt. Die Oberflächeneigenschaften dieser Reihe ausgebildeter polymerisierbarer Tenside zeigen ihr Anwendungspotential in der Emulsionspolymerisation zur Verbesserung der Stabilität von Latizes und Wasserempfindlichkeit der Filme.

Key words:: Polymerizable surfactant; synthesis; characterization; cmc
Stichwörter:: Polymerisierbare Tenside; Synthese; Charakterisierung; cmc
∗ Dr. Qiao Weihong, State key Lab. of Fine Chemicals, No. 158 Zhongshan Road, Dalian, China, 116012, Tel.: +86-4 11-88 99 38 79, Fax: +86-4 11-88 99 38 79. E-mail:

Zhu Mingyue was born in 1983. He is now a master student at Dalian University of Technology. His main field of research is synthesis and application of the polymerizable surfactants.

Assoc. Prof. Qiao Weihong was born in 1968. She obtained a MSc from Dalian University of Technology in 1994 and a PhD from the same university in 2000. Since 1994, she has been teaching and working at Dalian University of Technology. Her main field of research is the synthesis and physical chemistry of surfactants.

Sun Yingli was born in 1982. He is now a master student at Dalian University of Technology. His main field of research is synthesis and application of the polymerizable surfactants.

Senior Engineer Liu Hongzhu was born in 1973. He obtained a MSc from Dalian Institute of Light Industry in 1999. Since then he has been working in Dalian Zebon Fluorocarbon Paint Stock Co. Ltd. His main field of research is water-base resin and coating.

Prof. Li Zongshi was born in 1936. He obtained a BD from Dalian University of Technology in 1960. Since then he has been working in the department of fine chemicals at Dalian University of Technology. His focus is on the synthesis of surfactants and dyes.

References

1.Guyot, A.: Advances in reactive surfactants: Adv. Colloid Interface Sci.108–109, (2004)3. 10.1016/j.cis.2003.10.009Search in Google Scholar

2.Asua, J. M. and Schoonbrood, H. A. S.: Reactive surfactants in heterophase polymerization: Acta Polym. 49(12)(1998)671.Search in Google Scholar

3.Yang, S. F., Xiong, P. T., Gong, T., Lu, D. P. and Guan, R.: St–BA copolymer emulsions prepared by using novel cationic maleic dialkyl polymerizable emulsifier: Eur. Polym. J.41(12)(2005)2973. 10.1016/j.eurpolymj.2005.06.017Search in Google Scholar

4.Green, B. W. and Saunders, F. L.: In situ polymerization of surface-active agents on latex particles Π the mechanical stability of styrene/butadiene latexes: J. Colloid Interface Sci.33(3)(1970)393. 10.1016/0021-9797(70)90232-8Search in Google Scholar

5.Unzué, M. J., Schoonbrood, H. A. S., Asua, J. M., Goñi, A. M., Sherrington, D. C., Stähler, K., Goebel, K. G., Tauer, K., Sjöberg, M. and Holmberg, K.: Reactive surfactants in heterophase polymerization. VI. Synthesis and screening of polymerizable surfactants (surfmers) with varying reactivity in high solids styrene – butyl acrylate – acrylic acid emulsion polymerization: J. Appl. Polym. Sci.66(9)(1997)1803. 10.1002/(SICI)1097-4628(19971128)66:9<1803::AID-APP20>3.0.CO;2-USearch in Google Scholar

6.Soula, O., Guyot, A., Williams, N., Grade, J. and Blease, T.: Styrenic surfmer in emulsion copolymerization of acrylic monomers. II. Copolymerization and film properties: J. Polym. Sci. Part A: Polym. Chem.37(22)(1999)4205. 10.1002/(SICI)1099-0518(19991115)37:22<4205::AID-POLA21>3.0.CO;2-BSearch in Google Scholar

7.Sindt, O., Gauthier, C., Hamaide, T. and Guyot, A.: Reactive surfactants in heterophase polymerization. XVI. Emulsion copolymerization of styrene-butyl acrylate-acrylic acid in the presence of simple maleate reactive surfactants: J. Appl. Polym. Sci.77(12)(2000)2768. 10.1002/1097-4628(20000919)77:12<2768::AID-APP250>3.0.CO;2-4Search in Google Scholar

8.Abele, S., Gauthier, C., GraillatC. and Guyot, A.: Films from styrene-butyl acrylate lattices using maleic or succinic surfactants: mechanical properties, water rebound and grafting of the surfactants: Polymer41(3)(2000)1147. 10.1016/S0032-3861(99)00233-5Search in Google Scholar

9.Amalvy, J. I., Unzue, M. J., Schoonbrood, H. A. S. and Asua, J. M.: Reactive surfactants in heterophase polymerization: Colloidal properties, film-water absorption, and surfactant exudation: J. Polym. Sci. Part A: Polym. Chem.40(17)(2002)2994. 10.1002/pola.10385Search in Google Scholar

10.Aramendia, E., Barandiaran, M. J., Grade, J., Blease, T. and Asua, J. M.: Improving Water Sensitivity in Acrylic Films Using Surfmers: Langmuir 21(4) (2005) 1428.Search in Google Scholar

11.Schoonbrood, H. A. S., Asua, J. M.: Reactive Surfactants in Heterophase Polymerization. 9. Optimum Surfmer Behavior in Emulsion Polymerization: Macromolecules30(12)(1997)6034. 10.1021/ma9701494Search in Google Scholar

12.Hamaide, T., Monnet, C. and Guyot, A.: Polym. Bull.33(1994)133. 10.1007/BF00297347Search in Google Scholar

13.Abele, S., Graillat, C., Zicmanis, A. and Guyot, A.: Hemiesters and Hemiamides of Maleic and Succinic Acid: Synthesis and Application of surfactants in Emulsion polymerization with styrene and Butyl Acrylate: Polym. Adv. Technol.10(1999)301.10.1002/(SICI)1099-1581(199906)10:6<301::AID-PAT879>3.0.CO;2-SSearch in Google Scholar

14.Dymicky, M.: Org. Prep. Proced. Int.15(4)(1983)233. 10.1080/00304948309356647Search in Google Scholar

Received: 2007-03-14
Published Online: 2013-03-30
Published in Print: 2007-08-01

© 2007, Carl Hanser Publisher, Munich

Articles in the same Issue

  1. Contents/Inhalt
  2. Contents
  3. Abstracts
  4. Abstracts
  5. Application
  6. Influence of Polymer Architecture on the Stabilization of Iron and Manganese Ions in Aqueous Systems
  7. The Long-term Stability of Sodium Percarbonate in Presence of Zeolite as Measured by Heat Flow Calorimetry
  8. A Novel Method for the Synthesis of Mesoporous TiO2 at Ambient Temperature
  9. Sanitary Ware with Easy Cleaning and/or Antibacterial Properties
  10. Novel Surfactants
  11. Synthesis and Characterization of a Series of Novel Anionic Fumaric Polymerizable Surfactants
  12. Physical Chemistry
  13. Interfacial Tensions, Partition Coefficients, and Interfacial Elasticities: Measures for Emulsion Stability?
https://doi.org/10.3139/113.100343
Keywords for this article
Polymerizable surfactant; synthesis; characterization; cmc

Articles in the same Issue

  1. Contents/Inhalt
  2. Contents
  3. Abstracts
  4. Abstracts
  5. Application
  6. Influence of Polymer Architecture on the Stabilization of Iron and Manganese Ions in Aqueous Systems
  7. The Long-term Stability of Sodium Percarbonate in Presence of Zeolite as Measured by Heat Flow Calorimetry
  8. A Novel Method for the Synthesis of Mesoporous TiO2 at Ambient Temperature
  9. Sanitary Ware with Easy Cleaning and/or Antibacterial Properties
  10. Novel Surfactants
  11. Synthesis and Characterization of a Series of Novel Anionic Fumaric Polymerizable Surfactants
  12. Physical Chemistry
  13. Interfacial Tensions, Partition Coefficients, and Interfacial Elasticities: Measures for Emulsion Stability?
Sign up now to receive a 20% welcome discount
Institutional Access
How does access work?
Have an idea on how to improve our website?
Please write us.
© 2025 De Gruyter Brill
Downloaded on 26.10.2025 from https://www.degruyterbrill.com/document/doi/10.3139/113.100343/html
Scroll to top button