Startseite Preparation and Surface Activities of Novel Sodium Sulfated Aryl Oleic Acid Alkanolamides
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Preparation and Surface Activities of Novel Sodium Sulfated Aryl Oleic Acid Alkanolamides

  • Xu Zhigang , Yuan Bing , Yan Jie , Li Zongshi , Qiao Weihong und Lubo Cheng
Veröffentlicht/Copyright: 8. Mai 2013
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Abstract

Novel sodium sulfated aryl oleic acid alkanolamide surfactants (SSAOAA) with different hydrophobic groups are prepared. An aromatic ring introduced to a long alkyl chain has a significant effect on the effectiveness in reducing water surface tension. The critical micelle concentration (c.m.c.) of one product and the surface tension (γc.m.c.) at the c.m.c. are investigated. Surface active properties of sodium sulfated aryl oleic acid alkanolamides are compared to those of conventional sulfated fatty acid alkanolamides. Results show that the c.m.c. decreases with increasing the sizes of alkyl chains.

Kurzfassung

Neuartige Tenside aus natriumsulfatierten Aryl-Ölsäure-Alkanolamiden mit verschiedenen hydrophoben Gruppen wurden dargestellt. Die Einfügung eines aromatischen Ringes an eine lange Alkylkette hat einen signifikanten Einfluss auf die Effektivität der Verringerung der Wasseroberflächenspannung. Die kritische Mizellbildungskonzentration (c.m.c.) eines Produktes und die Oberflächenspannung (γc.m.c.) bei der c.m.c. wurden untersucht. Die Oberflächenaktivität von natriumsulfatiertem Aryl-Ölsäure-Alkanolamid wurde mit herkömmlichen sulfatierten Fettsäure-Alkanolamiden verglichen. Die Ergebnisse zeigen, dass mit Erhöhung der Alkylkettegröße die c.m.c. abnimmt.


3Dr. Xu Zhigang, State Key Laboratory of Fine Chemicals, Dalian University of Technology, 158 Zhongshan Road, Dalian 116012, PR China, E-mail:

Xu Zhigang was born in 1977. Now he is a PhD candidate at Dalian University of Technology. His main field of research is the synthesis and physical chemistry of surfactants.

Yuan Bing was born in 1977. Now he is a PhD candidate at Dalian University of Technology. His main field of research is about catalysts with little pollution, the synthesis and physical chemistry of surfactants

Yan Jie was born in 1964. He obtained an MSc from Dalian University of Technology in 1995. Since then he has been working in the department of chemistry at Sichuan University of Sciences and Engineering. His main field of research is the organic synthesis.

Prof. Li Zongshi was born in 1936. He obtained a BS degree from Dalian University of Technology in 1960. Since then he has been working in the department of fine chemicals at Dalian University of Technology. His focus is on synthesis of surfactants and their applications.

Associate Prof. Qiao Weihong was born in 1968. She obtained an MSc from Dalian University of Technology in 1994 and a PhD from the same university in 2000. Since 1994, she has been teaching and working in Dalian University of Technology. Her main field of research is the synthesis and physicial chemistry of surfactants.

Prof. Cheng Lubo was born in 1933. He obtained a BS from Dalian University of Technology in 1955. Since then he has been working in the department of fine chemicals at Dalian University of Technology. His focus is on synthesis of surfactants, dyes and their applications.


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Received: 2005-3-1
Published Online: 2013-05-08
Published in Print: 2005-09-01

© 2005, Carl Hanser Publisher, Munich

Heruntergeladen am 16.11.2025 von https://www.degruyterbrill.com/document/doi/10.3139/113.100265/pdf
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