Continuous dehydrochlorination of 1,3-dichloropropan-2-ol to epichlorohydrin: process parameters and by-products formation
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Anna Krzyżanowska
und
Eugeniusz Milchert
Abstract
The influence of pre-reactor and reactor temperatures on the conversion of 1,3-dichloropropan-2-ol and the selectivity of its transformation to epichlorohydrin in continuous dehydrochlorination for two modes of the reaction product collection was studied. The dehydrochlorination process and mechanism of diglycidyl ether formation are described.
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© 2012 Institute of Chemistry, Slovak Academy of Sciences
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Artikel in diesem Heft
- Evaluation of waste products in the synthesis of surfactants by yeasts
- Investigation of CO2 and ethylethanolamine reaction kinetics in aqueous solutions using the stopped-flow technique
- Alkali pre-treatment of Sorghum Moench for biogas production
- Modelling of kinetics of microbial degradation of simulated leachate from tobacco dust waste
- Model predictive control-based robust stabilization of a chemical reactor
- Decomposition of meta- and para-phenylphenol during ozonation process
- Treatment of effluents from a membrane bioreactor by nanofiltration using tubular membranes
- Zeolite and potting soil sorption of CO2 and NH3 evolved during co-composting of grape and tobacco waste
- Liquid-solid equilibrium for the NaCl-NaHCO3-Na2CO3-H2O system at 45°C. Validation of mixed solvent electrolyte model
- Investigation of turbulent flow field in a Kenics static mixer by Laser Doppler Anemometry
- Effect of flow-rate on ethanol separation in membrane distillation process
- Preparation of aluminium ammonium calcium phosphates using microwave radiation
- Continuous dehydrochlorination of 1,3-dichloropropan-2-ol to epichlorohydrin: process parameters and by-products formation
- Preparation of sterically stabilized gold nanoparticles for plasmonic applications
- Synthesis and spectroscopic characterisation of (E)-2-(2-(9-(4-(1H-1,2,4-triazol-1-yl)butyl)-9H-carbazol-3-yl)vinyl)-3-ethylbenzo[d]thiazol-3-ium, a new ligand and potential DNA intercalator
- Microwave-assisted oxidation of alcohols by hydrogen peroxide catalysed by tetrabutylammonium decatungstate
- Dynamic shape and wall correction factors of cylindrical particles falling vertically in a Newtonian liquid
- Selective oxidation of metallic single-walled carbon nanotubes
