Simulation of a hybrid fermentation-separation process for production of butyric acid
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Marek Blahušiak
,
Štefan Schlosser
Abstract
Simulation of a hybrid fermentation-separation process for the production of butyric acid (BA) based on published data was done. A unit consisting of a bioreactor with immobilized cells in the fibrous bed and of separation by pertraction through supported liquid membranes (SLM) was considered. Productivities of the unit volume of a fixed bed bioreactor in continuous and fed-batch fermentation at pH 5.5 and 6.0 were used. Concentration of BA in the bioreactor outlet stream was assumed to be in the interval from 0.11 kmol m−3 to 0.45 kmol m−3. Data on the pertraction through SLM with phosphonium ionic liquid (IL) and bulk liquid membrane with trioctylamine (TOA) as carriers were used. A strong increase in the required membrane area was found for both carriers at the pH of pertraction above 4. pH values of fermentation and pertraction should be optimized independently. It is advantageous to have pH of the feed into the pertraction unit of about 4. Dependences of the membrane area on the pertraction efficiency are nearly linear and not very sharp, especially for IL, what enables working at the pertractor efficiency exceeding 90 %. Application of phosphonium IL is promising compared to classical extractant TOA because of lower demand of the membrane area in a large interval of BA concentrations in the pertractor feed.
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© 2009 Institute of Chemistry, Slovak Academy of Sciences
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Artikel in diesem Heft
- Co-digestion of agricultural and industrial wastes
- Comparison of anoxic granulation in USB reactors with various inocula
- A study of selected phytoestrogens retention by reverse osmosis and nanofiltration membranes - the role of fouling and scaling
- Displacement washing of kraft pulp cooked from a blend of hardwoods
- Solid suspension and gas dispersion in gas-solid-liquid agitated systems
- Implementation of marginal quantities in management of cogeneration units operating in liberal market environment
- Kinetic study of wood chips decomposition by TGA
- LES and URANS modelling of turbulent liquid-liquid flow in a static mixer: Turbulent kinetic energy and turbulence dissipation rate
- Steady state and dynamic simulation of a hybrid reactive separation process
- Prediction of liquid-liquid flow in an SMX static mixer using large eddy simulations
- Simulation of a hybrid fermentation-separation process for production of butyric acid
- Simulation of aerobic landfill in laboratory scale lysimeters — effect of aeration rate
- Application of anoxic fixed film and aerobic CSTR bioreactor in treatment of nanofiltration concentrate of real textile wastewater
- Pretreatment of landfill leachate by chemical oxidation processes
- Development of β and α isotactic polypropylene polymorphs in injection molded structural foams
- Effect of time on the metal-support (Fe-MgO) interaction in CVD synthesis of single-walled carbon nanotubes
- Unique role of water content in enzymatic synthesis of ethyl lactate using ionic liquid as solvent
- Autothermal biodrying of municipal solid waste with high moisture content
- Kinetics of nitric oxide oxidation
