Abstract
After the synthesis and isolation of methylated bismuth cysteine, its initial identification by IR-spectroscopy was performed, whereas for definitive identification, high resolution mass spectrometry (ESI-TOF-MS and LTQ Orbitrap) was carried out.
[1] Boertz, J., Hartmann, L. M., Sulkowski, M., Hippler, J., Mosel, F., Diaz-Bone, R. A., Michalke, K., Rettenmeier, A. W., & Hirner, A. V. (2009). Determination of trimethylbismuth in the human body following ingestion of colloidal bismuth subcitrate. Drug Metabolism and Disposition, 37, 352–358. DOI: 10.1124/dmd.107.020313. http://dx.doi.org/10.1124/dmd.107.02031310.1124/dmd.107.020313Search in Google Scholar PubMed
[2] Briand, G. G., Burford, N., Eelman, M. D., Aumeerally, N., Chen, L., Cameron, T. S., & Robertson, K. N. (2004). Identification, isolation, and characterization of cysteinate and thiolactate complexes of bismuth. Inorganic Chemistry, 43, 6495–6500. DOI: 10.1021/ic049594n. http://dx.doi.org/10.1021/ic049594n10.1021/ic049594nSearch in Google Scholar PubMed
[3] Buchmann, W., Spezia, R., Tournois, G., Cartailler, T., & Tortajada, J. (2007). Structures and fragmentations of cobalt(II)-cysteine complexes in the gas phase. Journal of Mass Spectrometry, 42, 517–526. DOI: 10.1002/jms.1183. http://dx.doi.org/10.1002/jms.118310.1002/jms.1183Search in Google Scholar PubMed
[4] Burford, N., Eelman, M. D., Mahony, D. E., & Morash, M. (2003). Definitive identification of cysteine and glutathione complexes of bismuth by mass spectrometry: assessing the biochemical fate of bismuth pharmaceutical agents. Chemical Communications, 1, 146–147. DOI: 10.1039/b210570e. http://dx.doi.org/10.1039/b210570e10.1039/b210570eSearch in Google Scholar PubMed
[5] Krupp, E. M., Milne, B. F., Mestrot, A., Meharg, A. A., & Feldmann, J. (2008). Investigation into mercury bound to biothiols: structural identification using ESI-ion-trap MS and introduction of a method for their HPLC separation with simultaneous detection by ICP-MS and ESI-MS. Analytical and Bioanalytical Chemistry, 390, 1753–1764. DOI: 10.1007/s00216-008-1927-x. http://dx.doi.org/10.1007/s00216-008-1927-x10.1007/s00216-008-1927-xSearch in Google Scholar PubMed PubMed Central
[6] Michalke, K., Meyer, J., Hirner, A. V., & Hensel, R. (2002). Biomethylation of bismuth by the methanogen Methanobacterium formicicum. Applied Organometallic Chemistry, 16, 221–227. DOI: 10.1002/aoc.288. http://dx.doi.org/10.1002/aoc.28810.1002/aoc.288Search in Google Scholar
[7] Sun, H., Zhang, L., & Szeto, K.-Y. (2004). Bismuth in medicine. In A. Sigel & H. Sigel (Eds.), Metal ions in biological systems: Volume 41: Metal ions and their complexes in medication (Chapter 11, pp. 333–378). New York: Marcel Dekker. Search in Google Scholar
© 2009 Institute of Chemistry, Slovak Academy of Sciences
Articles in the same Issue
- Utilization of solid phase spectrophotometry for the determination of trace amounts of copper using 5-(2-benzothiazolylazo)-8-hydroxyquinoline
- Analysis of spectinomycin in fermentation broth by reversed-phase chromatography
- An amperometric sensor for uric acid based on ordered mesoporous carbon-modified pyrolytic graphite electrode
- Utility of π-acceptor reagents for spectrophotometric determination of sulphonamide drugs via charge-transfer complex formation
- A graph theoretical approach to the effect of mutation on the flexibility of the DNA binding domain of p53 protein
- Aquaculture by-product: a source of proteolytic enzymes for detergent additives
- Effect of anthraquinone on brightness value and crystalline structure of pulp during soda processes
- Selection of a method for determination of activity of pectinolytic enzymes in berry fruit materials
- Study on polymeric micelles of poly(γ-benzyl l-glutamate)-graft-poly(ethylene glycol) copolymer and its mixtures with poly(γ-benzyl l-glutamate) homopolymer in ethanol
- Synthesis and characterization of mesoporous molecular sieves
- Growth mechanism and characterization of ZnO nano-tubes synthesized using the hydrothermal-etching method
- Novel use of silicon nanocrystals and nanodiamonds in biology
- Fluoride anion sensing using colorimetric reagents containing binaphthyl moiety and urea binding site
- Spectrophotometric methods for sertraline hydrochloride and/or clidinium bromide determination in bulk and pharmaceutical preparations
- Study of physicochemical properties-antitubercular activity relationship of naphthalene-1,4-dione analogs: A QSAR approach
- Spectroscopic study of protonation of oligonucleotides containing adenine and cytosine
- Rheological properties of doughs with buckwheat and quinoa additives
- Synthesis and isolation of methyl bismuth cysteine and its definitive identification by high resolution mass spectrometry
Articles in the same Issue
- Utilization of solid phase spectrophotometry for the determination of trace amounts of copper using 5-(2-benzothiazolylazo)-8-hydroxyquinoline
- Analysis of spectinomycin in fermentation broth by reversed-phase chromatography
- An amperometric sensor for uric acid based on ordered mesoporous carbon-modified pyrolytic graphite electrode
- Utility of π-acceptor reagents for spectrophotometric determination of sulphonamide drugs via charge-transfer complex formation
- A graph theoretical approach to the effect of mutation on the flexibility of the DNA binding domain of p53 protein
- Aquaculture by-product: a source of proteolytic enzymes for detergent additives
- Effect of anthraquinone on brightness value and crystalline structure of pulp during soda processes
- Selection of a method for determination of activity of pectinolytic enzymes in berry fruit materials
- Study on polymeric micelles of poly(γ-benzyl l-glutamate)-graft-poly(ethylene glycol) copolymer and its mixtures with poly(γ-benzyl l-glutamate) homopolymer in ethanol
- Synthesis and characterization of mesoporous molecular sieves
- Growth mechanism and characterization of ZnO nano-tubes synthesized using the hydrothermal-etching method
- Novel use of silicon nanocrystals and nanodiamonds in biology
- Fluoride anion sensing using colorimetric reagents containing binaphthyl moiety and urea binding site
- Spectrophotometric methods for sertraline hydrochloride and/or clidinium bromide determination in bulk and pharmaceutical preparations
- Study of physicochemical properties-antitubercular activity relationship of naphthalene-1,4-dione analogs: A QSAR approach
- Spectroscopic study of protonation of oligonucleotides containing adenine and cytosine
- Rheological properties of doughs with buckwheat and quinoa additives
- Synthesis and isolation of methyl bismuth cysteine and its definitive identification by high resolution mass spectrometry