Reactive distillation — experimental data for propyl propionate synthesis
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Marcel Kotora
,
Carsten Buchaly
Abstract
A set of experimental data for heterogeneously catalysed esterification of propan-1-ol and propionic acid to propyl propionate in a pilot scale reactive distillation column is presented. The catalytic section of the column was equipped with the structured packing Katapak SP-11. Both, rectifying and stripping, sections consisted of the non-reactive structured Sulzer BX packing. As catalyst, the strongly acidic ion-exchange resin Amberlyst 46 was used. The experimental results show concentration as well as temperature profiles along the column height and therefore exhibit reliable data for model validation purposes.
[1] Bravo, J. L., Pyhalahti, A., & Järvelin, H. (1993). Investigations in a catalytic distillation pilot plant. Vapor/liquid equilibrium kinetics, and mass-transfer issues. Industrial and Engineering Chemistry Research, 32, 2220–2225. DOI: 10.1021/ie00022a004. http://dx.doi.org/10.1021/ie00022a00410.1021/ie00022a004Suche in Google Scholar
[2] Bravo, J. L., Rocha, J. A., & Fair, J. R. (1985). Mass Transfer in Gauze Packings. Hydrocarbon Processing, 64(1), 91–95. Suche in Google Scholar
[3] Buchaly, C., Kreis, P., & Górak, A. (2006). Experimental investigation of reactive distillation in combination with membrane separation. In Proceedings of the Distillation and Absorption Conference, September 4–6, 2006, 152, 373–383. Rugby: Institution of Chemical Engineers. Suche in Google Scholar
[4] Buchaly, C., Kreis, P., & Górak, A. (2007). Hybrid separation processes-Combination of reactive distillation with membrane separation. Chemical Engineering and Processing, 46, 790–799. DOI: 10.1016/j.cep.2007.05.023. http://dx.doi.org/10.1016/j.cep.2007.05.02310.1016/j.cep.2007.05.023Suche in Google Scholar
[5] Carrà, S., Morbidelli, M., Santacesaria, E., & Buzzi G. (1979). Synthesis of propylene oxide from propylene chlorohydrins—II: Modeling of the distillation with chemical reaction unit. Chemical Engineering Science, 34, 1133–1140. DOI: 10.1016/0009-2509(79)85019-8. http://dx.doi.org/10.1016/0009-2509(79)85019-810.1016/0009-2509(79)85019-8Suche in Google Scholar
[6] Duarte, C., Buchaly, C., Kreis, P., & Loureiro, J. M. (2006). Esterification of propionic acid with n-propanol catalytic and noncatalytic kinetic study. Inzynieria Chemiczna i Procesowa, 27, 273–286. Suche in Google Scholar
[7] Górak, A., & Hoffmann, A. (2001). Catalytic distillation in structured packings: Methyl acetate synthesis. AIChE Journal, 47, 1067–1076. DOI: 10.1002/aic.690470513. http://dx.doi.org/10.1002/aic.69047051310.1002/aic.690470513Suche in Google Scholar
[8] Hanika, J., Kolena, J., & Smejkal, Q. (1999). Butylacetate via reactive distillation — modelling and experiment. Chemical Engineering and Science, 54, 5205–5209. DOI: 10.1016/S0009-2509(99)00241-9. http://dx.doi.org/10.1016/S0009-2509(99)00241-910.1016/S0009-2509(99)00241-9Suche in Google Scholar
[9] Hoffmann, A., Noeres, Ch., & Górak, A. (2004). Scale-up of reactive distillation columns with catalytic packings, Chemical Engineering and Processing, 43, 383–395. DOI: 10.1016/S0255-2701(03)00121-1. http://dx.doi.org/10.1016/S0255-2701(03)00121-110.1016/S0255-2701(03)00121-1Suche in Google Scholar
[10] Podrebarac G., Ng, F. T. T., & Rempel G. L. (1998). The production of diacetone alcohol with catalytic distillation: Part I: Catalytic distillation experiments. Chemical Engineering Science, 53, 1067–1075. DOI: 10.1016/S0009-2509(97)00427-2. http://dx.doi.org/10.1016/S0009-2509(97)00427-210.1016/S0009-2509(97)00427-2Suche in Google Scholar
[11] Rocha, J. A., Bravo, J. L., & Fair, J. R. (1996). Distillation columns containing structured packings: A comprehensive model for their performance. 2. Mass-transfer model. Industrial and Engineering Chemistry Research, 35, 1660–1667. DOI: 10.1021/ie940406i. http://dx.doi.org/10.1021/ie940406i10.1021/ie940406iSuche in Google Scholar
[12] Saha, B., Chopade, S. P., & Mahajani, S. M. (2000). Recovery of dilute acetic acid through esterification in a reactive distillation column. Catalysis Today, 60, 147–157. DOI: 10.1016/S0920-5861(00)00326-6. http://dx.doi.org/10.1016/S0920-5861(00)00326-610.1016/S0920-5861(00)00326-6Suche in Google Scholar
[13] Taylor, R., & Krishna, R. (2000). Modelling reactive distillation. Chemical Engineering Science, 55, 5183–5229. DOI: 10.1016/S0009-2509(00)00120-2. http://dx.doi.org/10.1016/S0009-2509(00)00120-210.1016/S0009-2509(00)00120-2Suche in Google Scholar
© 2008 Institute of Chemistry, Slovak Academy of Sciences
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Artikel in diesem Heft
- Photocatalytic reduction of CO2 over TiO2 based catalysts
- Modeling of enzymatic reaction in an airlift reactor using an axial dispersion model
- Hydrolysis of titanium sulphate compounds
- Mathematical modelling of selected characterisation procedures for oil fractions
- High gravity batch and continuous processes for beer production: Evaluation of fermentation performance and beer quality
- Liquid-liquid equilibria of butyric acid for solvents containing a phosphonium ionic liquid
- HAZOP study of a fixed bed reactor for MTBE synthesis using a dynamic approach
- Influence of the reactive distillation column configuration on its performance: A computational study
- Reactive distillation — experimental data for propyl propionate synthesis
- Mixing time of a non-Newtonian liquid in an unbaffled agitated vessel with an eccentric propeller
- Heat transfer coefficient and pressure drop during refrigerant R-134a condensation in a plate heat exchanger
- Pore structure of pyrolyzed scrap tires
- Distribution of local heat transfer coefficient values in the wall region of an agitated vessel
- Chemical pretreatment of feed water for membrane distillation
- Selective methane oxidation to formaldehyde using polymorphic T-, M-, and H-forms of niobium(V) oxide as catalysts
- Validation of the Tessier scheme for speciation of metals in soil using the Bland and Altman test
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