Mild Pfitzner—Moffat oxidation of the (1→3)-β-D-glucan from Saccharomyces cerevisiae
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D. Zeković
,
M. Radulović
Abstract
The structure of the cell wall glucan isolated from the industrial strain of Saccharomyces cerevisiae was characterized as to be composed of a linear (1→3)-β-D-glucan chain with single β-D-glucopyranosyl residues attached to every ninth backbone unit by (1→6)-glycosidic linkages. Mild oxidation of this β-D-glucan with a dimethyl sulfoxide—acetic anhydride reagent yielded an “oxidized” glucan with aldehyde groups introduced at C-6 and carbonyl oxygens located at C-2 and C-4 of the glucopyranosyl rings. The conversion of the oxidized glucan into the polyoxime was used to study the progress of oxidation and to establish the carbonyl groups distribution in this new reactive polysaccharide derived from baker’s yeast cell wall.
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© 2006 Institute of Chemistry, Slovak Academy of Sciences
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Artikel in diesem Heft
- Calibrationless determination of electroactive species using chronoamperograms at collector segment of interdigitated microelectrode array
- The β-carotene dilemma: ESR study with coordinated peroxyl radicals
- Determination of 5-hydroxymethylfurfural after Winkler and by the HPLC method for authentication of honey
- A simple linear sweep voltammetric method for the determination of double-stranded DNA with malachite green
- Spectral and electrochemical study of coordination molecules Cu4OX6L4: 3-Pyridylmethanol and 4-pyridylmethanol Cu4OBrnCl(6−n)(pm)4 complexes
- Magnetic, spectral, and thermal behaviour of 2-chloro-4-nitrobenzoates of Co(II), Ni(II), and Cu(II)
- Synthesis, characterization, and biological activities of some transition metal(II) complexes with the thiosemicarbazone derived from 4-[1-(4-methylphenylsulfonyl)-1H-indol-3-yl]but-3-en-2-one
- Crystal structure and thermal chemical properties of 2-(2,4-dimethylanilino)-3-methyl-6-diethylaminofluorane
- Etherification of glycerol with tert-butyl alcohol catalysed by ion-exchange resins
- Synthesis and reactions of 2-and 4-substituted furo[3,2-c]pyridines
- Synthetic approaches towards bisspiro[naphthalene-2(1H),3′-(3H)pyrazol]-1-one-containing compounds
- Mild Pfitzner—Moffat oxidation of the (1→3)-β-D-glucan from Saccharomyces cerevisiae
- Limited sample recovery in coupled methods of high-performance liquid chromatography of synthetic polymers
