Startseite Carbon dioxide production in the oscillating Belousov—Zhabotinsky reaction with oxalic acid
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Carbon dioxide production in the oscillating Belousov—Zhabotinsky reaction with oxalic acid

  • P. Ševčík EMAIL logo , D. Mišicák und L’. Adamčíková
Veröffentlicht/Copyright: 1. Februar 2006
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Abstract

A new volumetric method for monitoring the oscillating Belousov—Zhabotinsky reaction with oxalic acid is described. While an oscillatory behavior in the potential of the Pt redox electrode at slow stirring without inert gas bubbling can be observed, a monotonous, nonoscillatory course was found both at the slow and rapid stirring rates for the carbon dioxide evolution. Possible reasons for such observations are discussed.

[1] Epstein, I. R. and Pojman, J. A., An Introduction to Nonlinear Chemical Dynamics. Oxford University Press, New York, 1998. 10.1093/oso/9780195096705.001.0001Suche in Google Scholar

[2] Field, R. J. and Burger, M., Oscillations and Traveling Waves in Chemical Systems. Wiley and Sons, New York, 1985. Suche in Google Scholar

[3] Noszticzius, Z. and Bódiss, J., J. Am. Chem. Soc. 101, 3177 (1979). http://dx.doi.org/10.1021/ja00506a00710.1021/ja00506a007Suche in Google Scholar

[4] Ševčík, P. and Adamčíková, L’., Collect. Czech. Chem. Commun. 47, 891 (1982). Suche in Google Scholar

[5] Rastogi, R. P., Yadav, K. D. S., and Rastogi, P., Indian J. Chem. 15A, 338 (1977). Suche in Google Scholar

[6] Wittmann, M., Stirling, P., and Bódiss, J., Chem. Phys. Lett. 141, 241 (1987). http://dx.doi.org/10.1016/0009-2614(87)85017-010.1016/0009-2614(87)85017-0Suche in Google Scholar

[7] Guedes, M. C. and Faria, R. B. J., J. Phys. Chem., A 102, 1973 (1998). http://dx.doi.org/10.1021/jp973078j10.1021/jp973078jSuche in Google Scholar

[8] Rastogi, R. P., Prem Chand, Pandey, M. K., and Das, M., J. Phys. Chem., A 109, 4562 (2005). http://dx.doi.org/10.1021/jp058052410.1021/jp0580524Suche in Google Scholar

[9] Rastogi, R. P. and Prem Chand, Chem. Phys. Lett. 369, 434 (2003). http://dx.doi.org/10.1016/S0009-2614(02)01980-210.1016/S0009-2614(02)01980-2Suche in Google Scholar

[10] Ševčík, P. and Adamčíková, L’., Collect. Czech. Chem. Commun. 50, 799 (1985). http://dx.doi.org/10.1135/cccc1985079910.1135/cccc19850799Suche in Google Scholar

[11] Gaspar, V. and Galambosi, P., J. Phys. Chem. 90, 2222 (1986). http://dx.doi.org/10.1021/j100401a04510.1021/j100401a045Suche in Google Scholar

[12] Ševčík, P. and Adamčíková, L’., J. Chem. Phys. 91, 1012 (1989). http://dx.doi.org/10.1063/1.45722510.1063/1.457225Suche in Google Scholar

[13] Pelle, K., Wittmann, M., Lovrics, K., Noszticzius, Z., Turco-Liveri, M. L., and Lombardo, R., J. Phys. Chem., A 108, 5377 (2004). http://dx.doi.org/10.1021/jp048817s10.1021/jp048817sSuche in Google Scholar

[14] Pelle, K., Wittmann, M., Noszticzius, Z., Lombardo, R., Sbriziolo, C., and Turco-Liveri, M. L., J. Phys. Chem., A 107, 2039 (2003). http://dx.doi.org/10.1021/jp026713g10.1021/jp026713gSuche in Google Scholar

[15] Ševčík, P., Kissimonová, K., and Adamčíková, L’., J. Phys. Chem., A 104, 3958 (2000). http://dx.doi.org/10.1021/jp993156y10.1021/jp993156ySuche in Google Scholar

[16] Ševčík, P., Kissimonová, K., and Adamčíková, L’., J. Phys. Chem., A 107, 1290 (2003). http://dx.doi.org/10.1021/jp021301t10.1021/jp021301tSuche in Google Scholar

[17] Bowers, P. G., Bar-Eli, K., and Noyes, R. M., J. Chem. Soc., Faraday Trans. 92, 2843 (1996). http://dx.doi.org/10.1039/ft996920284310.1039/ft9969202843Suche in Google Scholar

Published Online: 2006-2-1
Published in Print: 2006-2-1

© 2006 Institute of Chemistry, Slovak Academy of Sciences

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