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On the effect of carbonate on barite growth at elevated temperatures

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Published/Copyright: March 7, 2015
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American Mineralogist
From the journal American Mineralogist Volume 98 Issue 7

Abstract

The effect of carbonate on the growth of barite {001} surfaces from aqueous solutions supersaturated with respect to barite (Ωbarite ~ 12) was studied by hydrothermal atomic force microscopy (HAFM) and Raman spectroscopy at temperatures ranging from 25 to 70 °C. The experiments showed that the effects of carbonate depend on the specific location of growth. For mono-layers growing on pristine barite, the carbonate-additive promotes growth and the spreading rate of two-dimensional islands increases with temperature. However, growth is inhibited in layers growing on surfaces, which grew in carbonate-containing solution. The threshold carbonate concentration necessary to completely inhibit growth is inversely correlated with temperature. Raman spectroscopy revealed the presence of carbonate within crystals, which grew in carbonate-containing solution. Judging by these findings, incorporation of carbonate into the structure of growing barite as a thermally activated process likely is a controlling factor, which inhibits barite growth. Thus the study shows that additives can exert opposing effects on growth not only depending on additive concentration but also depending on the specific growth location. The implication of this work, therefore, is that bimodal effects of additives on crystal growth occur more frequently than generally recognized. The insights into the mechanisms of such bimodal effects of additives can significantly contribute to the understanding and predictability of the kinetics of macro-scale processes such as barite scale formation or the behavior of barium sulfate in CO2-sequestration fluids

Keywords: Barite; hydrothermal atomic force microscopy; impurity; growth inhibition; growth promotion; carbonate; Raman spectroscopy
Received: 2012-11-29
Accepted: 2013-3-3
Published Online: 2015-3-7
Published in Print: 2013-7-1

© 2015 by Walter de Gruyter Berlin/Boston

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https://doi.org/10.2138/am.2013.4420
Keywords for this article
Barite; hydrothermal atomic force microscopy; impurity; growth inhibition; growth promotion; carbonate; Raman spectroscopy

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  1. Highlights and Breakthroughs. A step closer to predicting the bonding geometry of crystals
  2. Minerals in the Human. Body Crystal chemistry of cement-asbestos
  3. Versatile monazite: Resolving geological records and solving challenges in materials science. Microprobe analysis and dating of monazite from the Potsdam Formation, New York: A progressive record of chemical reaction and fluid interaction
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  6. Synchrotron Mössbauer study of Fe-bearing pyrope at high pressures and temperatures
  7. In situ Raman spectroscopic study of transient polyhedral distortions during cesium ion exchange into sitinakite
  8. A micro-reflectance IR spectroscopy method for analyzing volatile species in basaltic, andesitic, phonolitic, and rhyolitic glasses
  9. Fundamental Mössbauer parameters of synthetic Ca-Mg-Fe pyroxenes
  10. Iron oxidation state in phyllosilicate single crystals using Fe-K pre-edge and XANES spectroscopy: Effects of the linear polarization of the synchrotron X-ray beam
  11. Effect of particle size on phase transitions in metastable alumina nanoparticles: A view from high-resolution solid-state 27Al NMR study
  12. Magnesite formation from MgO and CO2 at the pressures and temperatures of Earth’s mantle
  13. Investigation of the hydrozincite structure by infrared and solid-state NMR spectroscopy
  14. Local structure in C2/c clinopyroxenes on the hedenbergite (CaFeSi2O6)-ferrosilite (Fe2Si2O6) join: A new interpretation for the Mössbauer spectra of Ca-rich C2/c clinopyroxenes and implications for pyroxene exsolution
  15. On the effect of carbonate on barite growth at elevated temperatures
  16. The structure of (Ca,Co)CoSi2O6 pyroxenes and the Ca-M2+ substitution in (Ca,M2+)M2+Si2O6 pyroxenes (M2+ = Co, Fe, Mg)
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  30. Leter. Discovery of dmisteinbergite (hexagonal CaAl2Si2O8) in the Allende meteorite: A new member of refractory silicates formed in the solar nebula
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